• 한국자기공명학회논문지
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• 제24권4호
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• pp.96-103
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• 2020

A new NMR method to monitor solvent-localized NMR signals in the two-phase liquid system is suggested. This method based on intermolecular single-quantum coherence (iSQC). Here, we exploited the feature of the local action of distant dipolar field (DDF) effect in order to filter out specific NMR signals dissolved in different solvents. This solvent specific iSQC spectroscopy was carried out on a model two-phase liquid system (D-glucose in water/palmitic acid in chloroform), and showed solvent-localized NMR signals. We believe our approaches might be useful in metabolic analysis such as two-phase liquid extraction scheme for labile chemical species.

• 한국자기공명학회논문지
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• 제25권1호
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• pp.1-7
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• 2021

Employing of 13C stable-isotopes in NMR metabolomics can give unique splitting patterns and coupling constants information originated from 13C-13C coupling interaction that provide an important structural information regarding the cellular metabolic process. But it has been known that an undesirable signal distortion in 2D heteronuclear correlation study, due to 13C-13C interaction, hampers an analysis of the coupling information. Recently, we proposed J-scaled distortion-free heteronuclear single-quantum coherence (HSQC) sequence which provides a distortion-free 13C-13C coupling information with a selective resolution enhancement of JCC splitting. In this paper, we dicuss theoretical aspect and practical feature of J-scaled HSQC pulse sequence. The conceptual explanation of orgin of the signal distortion by 13C-13C coupling interaction and design of J-scaled HSQC through exemplified results are provided in brief.

• 한국자기공명학회논문지
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• 제25권4호
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• pp.45-50
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• 2021

A calix[4]pyrrole (1) bearing a quaternary ammonium pendant via its meso phenoxy linker has been synthesized as the bromide salt form. It was revealed by ¹H NMR spectroscopic analyses performed in DMSO-d₆ that receptor 1 binds F^- with high affinity and selectivity over other halide anions. The binding of receptor 1•Br^- with F^- and Cltakes place by anion metathesis with the anions including F^- and Cl^-.

• 한국소음진동공학회논문집
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• 제19권12호
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• pp.1356-1363
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• 2009

The aim of this research is to construct eigenfrequency optimization codes for plates with Arbitrary Rank Microstructures. From among noise factors, resonance sound is main reason for floor's solid noise. But, Resonance-elusion design codes are not fixed so far. Besides, The prediction of composite material's capability and an resonance elusion by controlling natural frequency of plate depend on designer's experiences. In this paper, First, using computer program with arbitrary rank microstructure, variation on composite material properties is studied, and then natural frequency control is performed by plate topology optimization method. The results of this study are as followed. 1) Programs that calculate material properties along it's microstructure composition and control natural frequency on composite material plate are coded by Homogenization and Topology Optimization method. and it is examined by example problem. 2) Equivalent material properties, calculated by program, are examined for natural frequency. In this paper, Suggested programs are coded using $Matlab^{TM}$, Feapmax and Feap Library with Homogenization and Topology Optimization method. and Adequacy of them is reviewed by performing the maximization or minimization of natural frequency for plates with isotropic or anisotropic materials. Since the programs has been designed for widely use. If the mechanism between composite material and other structural member is identified, extension application may be possible in field of structure maintenance, reinforcement etc. through application of composite material.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2012년도 춘계학술대회 논문집
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• pp.150-154
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• 2012

A flow induced mechanical vibration and acoustic resonance should be considered at design stage because they are mainly occurred in the tube bank of boiler. Acoustic resonance is occurred when the vortex shedding frequency of tube bank coincides with the acoustic natural frequency of the cavity. Effective solution to avoid acoustic resonance is installing acoustic baffles in the tube banks parallelly inside of the flow cavity. Thus, location and number of acoustic baffles should be exactly calculated to eliminate the acoustic resonance. This paper presents case study of acoustic resonance due to inappropriate number and location of acoustic baffles. Measured frequency and mode in the study is verified by FEM acoustic modal analysis. The number and location of acoustic baffles to avoid acoustic resonance are calculated by using FEM acoustic modal analysis.

• International Journal of Fluid Machinery and Systems
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• 제1권1호
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• pp.169-180
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• 2008

As a major component of a power plant, a turbine generator must have sufficient reliability. Longer blades have lower natural frequency, thereby requiring that the design of the shaft and blade takes into account the coupling of the blade vibration mode, nodal diameter k=0 and k=1 with vibration of the shaft. The present work analyzes the coupling of the translation motion of the shaft with in-plane vibration of the blades with k=1 modes. At a rotational speed ${\Omega}_1=|{\omega}_s-{\omega}_b|$, the resonance of the blades has a relatively large amplitude. A violent coupled resonance was observed at a rotational speed ${\Omega}_2=|{\omega}_s+{\omega}_b|$. Resonance in blade vibration at ${\Omega}_1=|{\omega}_s-{\omega}_b|$ was experimentally confirmed.

• 한국방사선학회논문지
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• 제7권3호
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• pp.245-249
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• 2013

천연 탄탈의 중성자포획에 의한 공명에너지를 측정하기 위하여 교토대학의 원자로연구소의 46-MeV 전자선형가속기의 광핵반응에서 발생하는 중성자를 이용하였다. 중성자포획에서 발생되는 즉발감마선을 BGO($Bi_4Ge_3O_{12}$)섬광검출장치로 측정하였다. 검출장치는 탄탈 시료에서 발생되는 즉발감마선을 기하학적으로 모두 측정하도록 만들어져 있으며 측정되어진 전기적 신호를 탄탈의 중성자 공명에너지 동정하는 스펙트럼구성에 사용하였다. 연구에서 사용되어진 중성자의 에너지는 1 ~ 200 eV 영역에 대하여 각각의 공명에너지를 분석하였다. 중성자에너지 측정은 중성자 비행시간법(TOF: Time-of-Flight)을 통하여 측정하였다. 광핵반응을 통한 중성자발생에서는 고에너지영역에서 강한 제동복사선이 발생하므로 수 keV영역 이하 영역의 중성자에너지에 대해서만 중성자공명을 측정하였다. 얻어진 Ta에 대한 중성자 포획 공명에너지 측정결과는 이전의 실험에 의한 측정 결과들 및 ENDF/B-VI와 Mughabghab의 평가된 값들과 비교 및 검토를 하였다. 측정되어진 공명들은 4.28 eV에서 거대 공명들을 측정하였고 그 이상의 에너지 영역의 다른 공명들도 이론에 의해서 계산되어진 값들과 비교하였다. 144.3 eV를 제외한 공명들은 평가값들과 거의 일치하는 경향을 보였다.

• 대한약학회:학술대회논문집
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• 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.1
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• pp.213.2-213.2
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• 2002

• 한국강구조학회 논문집
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• 제26권5호
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• pp.375-383
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• 2014

최근 자전거나 보행자들이 쉽고 편리하게 이동 할 수 있는 보도교와 미관중심의 보도교가 가설되고 있다. 그러나 보행자의 보행이 보도교의 고유진동수와 근접할 경우 공진현상에 의해 큰 진폭이 발생하여 보행자에게 보행시 불안감을 조성시킨다. 그러나 보행시 진동에 따른 연구는 매우 미약하다. 따라서 휴대용 진동계측기를 통하여 서울시에 가설된 65개소의 보도교를 대상으로 공진발생에 따른 고유진동수를 분석하였고 경간별 고유진동수 상관관계와 구조시스템에 따른 경간과 고유진동수의 상관관계를 분석하였다.

• 한국자기공명학회논문지
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• 제15권2호
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• pp.137-145
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• 2011

Hsp33, a prokaryotic molecular chaperone, exerts holdase activity in response to oxidative stress. In this study, the stepwise conformational change of Hsp33 upon oxidation was monitored by NMR. In order to overcome its high molecular weight (33 kDa as a monomer and 66 kDa as a dimer), spectra were simplified using a selectively [$^{15}N$]His-labeled protein. All of the eight histidines were observed in the TROSY spectrum of the reduced Hsp33. Among them, three peaks showed dramatic resonance shifts dependent on the stepwise oxidation, indicating a remarkable conformational change. The results suggest that unfolding of the linker domain is associated with dimerization, but not entire region of the linker domain is unfolded.