• Title/Summary/Keyword: multifunctional materials

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Development of Three-Dimensional Deformable Flexible Printed Circuit Boards Using Ag Flake-Based Conductors and Thermoplastic Polyamide Substrates

  • Aram Lee;Minji Kang;Do Young Kim;Hee Yoon Jang;Ji-Won Park;Tae-Wook Kim;Jae-Min Hong;Seoung-Ki Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.420-426
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    • 2024
  • This study proposes an innovative methodology for developing flexible printed circuit boards (FPCBs) capable of conforming to three-dimensional shapes, meeting the increasing demand for electronic circuits in diverse and complex product designs. By integrating a traditional flat plate-based fabrication process with a subsequent three-dimensional thermal deformation technique, we have successfully demonstrated an FPCB that maintains stable electrical characteristics despite significant shape deformations. Using a modified polyimide substrate along with Ag flake-based conductive ink, we identified optimized process variables that enable substrate thermal deformation at lower temperatures (~130℃) and enhance the stretchability of the conductive ink (ε ~30%). The application of this novel FPCB in a prototype 3D-shaped sensor device, incorporating photosensors and temperature sensors, illustrates its potential for creating multifunctional, shape-adaptable electronic devices. The sensor can detect external light sources and measure ambient temperature, demonstrating stable operation even after transitioning from a planar to a three-dimensional configuration. This research lays the foundation for next-generation FPCBs that can be seamlessly integrated into various products, ushering in a new era of electronic device design and functionality.

Development of a Centrifugal Microreactor for the Generation of Multicompartment Alginate Hydrogel (다중 알긴산 입자제조를 위한 원심력 기반 미세유체 반응기 개발)

  • Ju-Eon, Jung;Kang, Song;Sung-Min, Kang
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.23-29
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    • 2023
  • Microfluidic reactors have been made to achieve significant development for the generation of new functional materials to apply in a variety of fields. Over the last decade, microfluidic reactors have attracted attention as a user-friendly approach that is enabled to control physicochemical parameters such as size, shape, composition, and surface property. Here, we develop a centrifugal microfluidic reactor that can control the flow of fluid based on centrifugal force and generate multifunctional particles of various sizes and compositions. A centrifugal microfluidic reactor is fabricated by combining microneedles, micro- centrifuge tubes, and conical tubes, which are easily obtained in the laboratory. Depending on the experimental control param- eters, including centrifuge rotation speed, alginate concentration, calcium ion concentration, and distance from the needle to the calcium aqueous solution, this strategy not only enables the generation of size-controlled microparticles in a simple and reproducible manner but also achieves scalable production without the use of complicated skills or advanced equipment. Therefore, we believe that this simple strategy could serve as an on-demand platform for a wide range of industrial and academic applications, particularly for the development of advanced smart materials with new functionalities in biomedical engineering.

Phase Transformation and Microstructural Change of Alumina Membrane (알루미나 여과막의 상전이와 미세구조 변화)

  • Cheong, Hun;Choi, Duck-Kyun;Cheong, Deck-Soo
    • Korean Journal of Materials Research
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    • v.10 no.9
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    • pp.619-623
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    • 2000
  • Alumina membrane was prepared by sol-gel coating method using boehmite powder(${\Upsilon}-AlOOH$). The supported and the unsupported alumina membrane were fabricated to investigate the phase transformation and change of microstructure. It is important to control the homogeneous pore size and distribution in application of filtering process. The ${\theta}-to\;{\alpha}-AL_2O_3$ phase transformation (XRD) and the change of microstructure was investigated using scanning electron microscopy(SEM). XRD patterns showed that the supported membrane had $100^{\circ}C$ higher ${\theta}-to\;{\alpha}-AL_2O_3$ transformation temperature compared to the unsupported membrane. The similar effect was also observed for microstructural change of the membrane.

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Numerical Simulation of the Delamination Behavior of Polymeric Adhesive Tapes Using Cohesive Zone Element (응집 영역 요소를 이용한 고분자 접착 테이프의 박리거동 모사)

  • Jang, Jinhyeok;Sung, Minchang;Yu, Woong-Ryeol
    • Composites Research
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    • v.29 no.4
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    • pp.203-208
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    • 2016
  • Metal and polymer sandwich composites, which are made of sheet metal sheath and polymer or fiber reinforced plastic core, have been reconsidered as an alternative to sheet metal due to their lightness and multifunctional properties such as damping and sound-proof properties. For the successful applications of these composites, the delamination prediction based on the adhesion strength is important element. In this study, the numerical simulation of the delamination behavior of polymeric adhesive tapes with metallic surfaces was performed using cohesive zone elements and finite element software. The traction-separation law of the cohesive zone element was defined using the fracture energy derived from peel mechanics and experimental results from peel test and implemented in finite element software. The peel test of the polymeric adhesive film against steel surface was simulated and compared with experiments, demonstrating reasonable agreement between simulation and experiment.

Platinum Nano-Dispersion via In Situ Processing - Preparation and catalytic Property of Porous $CaZrO_3/MgO/Pt$ Nanocomposite

  • Yoshikazu;Hwang, Hae-Jin;Naoki Kondo;Tatsuki Ohji
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.163-167
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    • 2001
  • A bulk porous $CaZrO_3/MgO$ composite with plantinum nano-dispersion was synthesized in air atmosphere through the combination of several in situ reactions, including the pyrolysis of $PtO_2$. A mixture of $CaMg(CO_3)_2$(dolomite), $ZrO_2$, $PtO_2$ and LiF (0.5 wt%, as an additive) was cold isostatically pressed at 200 MPa and sintered at $1100^{\circ}C$ for 2 h. The porous $CaZrO_3/MgO/Pt$ composite ($CaZrO_3/MgO$ : Pt=99 : 1 in volume) had a uniformly open-porous structure (porosity: 56%) with three-dimensional (3-D) network and a narrow pore-size distribution, similarly to the porous $CaZrO_3/MgO$ composites reported before. Catalytic Properties (viz., NO direct decomposition and NO reduction by $C_2H_4$) of the $CaZrO_3/MgO/Pt$ composite were investigated up to $900^{\circ}C$. In the absence of oxygen, the NO conversion rate reached ~52% for the direct decomposition and ~100% for the reduction by $C_2H_4$, respectively. The results suggest the possibility of the porous composite as a multifunctional filter, i.e., simultaneous hot gas-filtering and $de-NO_x$ in one component.

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Surface structure modification of vertically-aligned carbon nanotubes and their characterization of field emission property

  • adil, Hawsawi;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.159-159
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    • 2016
  • Vertically-aligned carbon nanotubes (VCNT) have attracted much attention due to their unique structural, mechanical and electronic properties, and possess many advantages for a wide range of multifunctional applications such as field emission displays, heat dissipation and potential energy conversion devices. Surface modification of the VCNT plays a fundamental role to meet specific demands for the applications and control their surface property. Recent studies have been focused on the improvement of the electron emission property and the structural modification of CNTs to enable the mass fabrication, since the VCNT considered as an ideal candidate for various field emission applications such as lamps and flat panel display devices, X-ray tubes, vacuum gauges, and microwave amplifiers. Here, we investigate the effect of surface morphology of the VCNT by water vapor exposure and coating materials on field emission property. VCNT with various height were prepared by thermal chemical vapor deposition: short-length around $200{\mu}m$, medium-length around $500{\mu}m$, and long-length around 1 mm. The surface morphology is modified by water vapor exposure by adjusting exposure time and temperature with ranges from 2 to 10 min and from 60 to 120oC, respectively. Thin films of SiO2 and W are coated on the structure-modified VCNT to confirm the effect of coated materials on field emission properties. As a result, the surface morphology of VCNT dramatically changes with increasing temperature and exposure time. Especially, the shorter VCNT change their surface morphology most rapidly. The difference of field emission property depending on the coating materials is discussed from the point of work function and field concentration factor based on Fowler-Nordheim tunneling.

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Effect of Alumina Particle Size on R-curve Behavior of (Y,Nb)-TZP/${Al_2}{O_3}$ Composites (알루미나 입도가 (Y,Nb)-TZP/${Al_2}{O_3}$ 복합체의 R-curve 거동에 미치는 영향)

  • Lee, Deuk-Yong;Kim, Dae-Joon;Kim, Bae-Yeon;Song, Yo-Seung
    • Journal of the Korean Ceramic Society
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    • v.38 no.10
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    • pp.936-941
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    • 2001
  • The influence of the ${Al_2}{O_3}$ particle size on flaw tolerance of the $ZrO_2/{Al_2}{O_3}$ composites prepared by mixing 5.31 mol% ${Y_2}{O_3}$-4.45 mol% ${Nb_2}{O_5}$-90.31 mol% $ZrO_2$ and ${Al_2}{O_3}$ was investigated. The composites exhibited rising R-curve behavior and plateau fracture toughness of 7.9 and $8.8MPam^{1/2}$ for the additions of 20 vol% of 0.2 and $2.8{\mu}m$ ${Al_2}{O_3}$ particles, respectively. The difference in the fracture toughness resistance was attributed mainly to the grain size of tetragonal $ZrO_2$ phase in the composites, which scaled with the ${Al_2}{O_3}$ particle size.

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Antistatic Behavior of UV-curable Multilayer Coating Containing Organic and Inorganic Conducting Materials (유·무기 전도성 물질을 함유한 UV 경화형 다층 코팅의 대전방지 특성)

  • Kim, Hwa-Suk;Kim, Hyun-Kyoung;Kim, Yang-Bae;Hong, Jin-Who
    • Journal of Adhesion and Interface
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    • v.3 no.3
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    • pp.22-29
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    • 2002
  • UV curable coating system described here consists of double layers, namely under layer and top laser coatings. The former consists of organic-inorganic conductive materials and the latter consists of multifunctional acrylates. Transparent double layer coatings were prepared on the transparent substrates i.e. PMMA, PC, PET etc. by the wet and wet coating procedure. Their surface resistances and film properties were measured as a function of the top layer thickness and relative humidity. As the thickness of the top layer was less than $10{\mu}m$, the surface resistance in the range of $10^8{\sim}10^{10}{\Omega}/cm^2$ was obtained. The surface properties of the two-layer coating were remarkably improved compared with the single layer coating. The effects of migration of conducting materials on the film properties of multilayer coating were investigated by using contact angle and Fourier transform infrared/attenuated total reflection(FT-IR/ATR). It was found that the migration of dopant(dodecyl benzenesulfonic acid, DBSA) molecules were occurred from film-substrate interface to film-air interface in the organic conductive coating system but not in the inorganic one.

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Corrosion Protection of Rebars Using High Durability Polymer Cementitious Materials for Environmental Load Reduction (환경부하저감형 고내구성 폴리머 시멘트계 재료를 이용한 철근 부식저감기술)

  • Kim, Wan-Ki;Chung, Seung-Jin
    • KIEAE Journal
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    • v.10 no.5
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    • pp.131-137
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    • 2010
  • The building industry must aim at high-durability and sustainability. A holistic life cycle based approach is recommended to reduce the environmental load. In recent years, technical innovations in the construction industry have advanced to a great extent, and caused the active research and development of high-performance and multifunctional construction materials. Nowadays, various polymer powders have been commercialized to manufacture construction materials in the form of prepackaged-type products, which have rapidly been developed for lack of skilled workmen in construction sites. Recently, terpolymer powders of improved quality have been developed and commercialized as cement modifiers. And, hydrocalumite is a material that can adsorb the chloride ions (Cl-) causing the corrosion of reinforcing bars and liberate the nitrite ions (NO2-) inhibiting the corrosion in reinforced concrete, and can provide a self-corrosion inhibition function to the reinforced concrete. The purpose of this study is to ascertain the self-corrosion inhibition function of polymer-modified mortars using redispersible powders with hydrocalumite. Polymer-modified mortars using VA/E/MMA and VAE redispersible powders are prepared with various calumite contents and polymer-binder ratios, and tested for chloride ion penetration depth, corrosion inhibition. As a result, regardless of the polymer-binder ratio, the replacement of ordinary portland cement with hydrocalumite has a marked effect on the corrosion-inhibiting property of the polymer-modified mortars. Anti-corrosion effect of polymer-modified mortars using VA/E/MMA terpolymer powder with hydrocalumite is higher than that of VAE copolymer powder.

Research Status and Prospectives of Magnetic Nanoparticles in Bio-medical Applications (바이오-메디컬 자성나노입자 연구의 현황과 전망)

  • Min, J.H.;Song, A.Y.;Kim, Y.K.;Wu, J.H.
    • Journal of the Korean Magnetics Society
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    • v.19 no.1
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    • pp.28-34
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    • 2009
  • Magnetic nanoparticles are widely used for bio-medical applications such as MRI contrast agents, drug-delivery systems, cell separation and hyperthermia, thanks to their unique magnetic properties and physico-chemical characteristics. In the early stage, efforts were focused on synthesis of uniform nanoparticles of desired dimension to achieve targeted, stable functionalities. Recently, it has been of great interest in dispersion of such nanoparitcles in aqueous solution and to render the nanoparticles bio-compatible with biofunctionality on request for utilization in bio-medical fields. In this paper, we survey the research status and give prospective on future work of magnetic nanoparticles for biomedical applications.