• Title/Summary/Keyword: multi-electrode

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Distribution of Welding Residual Stresses in T-joint Weld with Root Gap (루트부 갭이 있는 양면 필릿용접 이음부의 용접잔류응력 분포)

  • H.S. Bang;S.H. Kim;Y.P. Kim;C.W. Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.39 no.3
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    • pp.81-88
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    • 2002
  • The root joint in the welding structures are apt to failure by the stress concentration which is occurred by the external force. Therefore, in the safety and reliability of structure, the complete penetration joint welding which are obtained by the groove welding with edge preparation is generally required. Nevertheless, fillet T-joint welding without edge preparation is often carried out in the fields to reduce working time and consumption of welding electrode, however, this process is likely to produce inadequate joint penetration such as root gap. In this paper, the focus of research is to investigate distribution of welding residual stresses in the plate(or flange) and web of T-joint weld, and especially in the near of root gap notch that is due to incomplete joint penetration. For the analysis, we have chosen model of T-joint weld in the cases of single and multi-pass welding with submerged arc welding and analyzed model by using finite element programs considering the heat conduction and thermal elasto-plastic theory.

The Electrical Insulation Characteristics of HTS SMES (초고온초전도 SMES의 절연특성)

  • Cheon, Hyeon-Gweon;Choi, Jae-Hyeong;Kim, Hae-Jong;Seong, Ki-Chul;Kim, Sang-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.623-626
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    • 2005
  • Toward the practical applications, on operation of conduction-cooled HTS SMES at temperatures well below 77 K should be investigated, in order to take advantage of a greater critical current density of HTS and considerably reduce the size and weight of the system. Recently, research and development concerning application of the conduction-cooled HTS SMES that is easily movement are actively progressing in Korea. Electrical insulation under cryogenic temperature is a key and an important element in the application of this apparatus. Using multi wrapped copper by polyimide film for HIS SMES, the breakdown characteristics of models for turn-to-turn, that is surface contact model, were investigated under ac and impulse voltage at 77 K. A material that is Polyimide film (Kapton) 0.025 mm thickness is used for multi wrapping of the electrode. Statistical analysis of the results using Weibull distribution to examine the wrapping number effects on breakdown voltage under ac and impulse voltage in $LN_2$ was carried.

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Improvement in Sensitivity of Electrochemical Glucose Biosensor Based on CuO/Au@MWCNTs Nanocomposites (CuO/Au@MWCNTs 나노복합재 기반 전기화학적 포도당 바이오센서의 민감도 개선)

  • Park, Mi-Seon;Bae, Tae-Sung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.145-152
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    • 2016
  • In this study, CuO was introduced on MWCNTs dispersed with Au nanoparticles to improve the glucose sensing capability of electrochemical biosensors. Nano-cluster shaped CuO was synthesized due to the presence of Au nanoparticle, which affects glucose sensing performance. The biosensor featuring CuO/Au@MWCNTs nanocomposite as an electrode material when 0.1 mole of CuO was synthesized showed the highest sensitivity of $504.1{\mu}A\;mM^{-1}cm^{-2}$, which is 4 times better than that of MWCNTs based biosensors. In addition, it shows a wider linear range from 0 to 10 mM and lower limit of detection (LOD) of 0.008 mM. These results demonstrate that CuO/Au@MWCNTs nanocomposite sensors are superior to other CuO based biosensors which are attributed that the nano-cluster shaped CuO is favorable for the electrochemical reaction with glucose molecules.

Gold/Copper Bi-Metallic Catalysts by Carbothermal Method for CO2 Reduction

  • Yoon, Hee-chan;Jung, Woo-bin;Jung, Hee-Tae
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2019.10a
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    • pp.83-83
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    • 2019
  • Increasing the CO2 concentration in the atmosphere induce high temperature and rising sea levels. So the technology that capture and reuse of the CO2 have been recently become popular. Among other methods, CRR(CO22 reduction reaction) is typical method of CO2 reusing. Electrocatalyst can show more higher efficiencies in CRR than photocatalyst because it doesn't use nature source. Nowadays, finding high efficient electrocatalyst by controlling electronic (affected by stoichiometry) and geometric (affected by atomic arrangement) factors are very important issues. Mono-atomic electro-catalyst has limitations on controlling binding energy because each intermediate has own binding energy range. So the Multi-metallic electro-catalyst is important to stabilize intermediate at the same time. Carbon monoxide(CO) which is our target product and important feedstock of useful products. Au is known for the most high CO production metal. With copper, Not only gold/copper has advantages which is they have FCC packing for easily forming solid solution regardless of stoichiometry but also presence of adsorbed CO on Cu promotes the desorption of CO on Au because of strong repulsion. And gold/copper bi-metal catalyst can show high catalytic activity(mass activity) although it has low selectivity relatively Gold. Actually, multi-metallic catalyst structure control method is limited in the solution method which is takes a lot of time. In here, we introduce CTS(carbo thermal shock) method which is using heat to make MMNP in a few seconds for making gold-copper system. This method is very simple and efficient in terms of time(very short reaction time and using carbon substrate as a direct working electrode) and increasing reaction sites(highly dispersed and mixing alloy structures). Last one is easy to control degree of mixing and it can induce 5 or more metals in one alloy system. Gold/copper by CTS can show higher catalytic activity depending on metal ratio which is altered easily by changing simple variables. The ultimate goals are making CO2 test system by CTS which can check the selectivity depending on metal types in a very short time.

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Comparison of Catalytic Activity for Methanol Electrooxidation Between Pt/PPy/CNT and Pt/C

  • Lee, C.G.;Baek, J.S.;Seo, D.J.;Park, J.H.;Chun, K.Y.
    • Journal of the Korean Electrochemical Society
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    • v.13 no.4
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    • pp.240-245
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    • 2010
  • This work explored the catalytic effect of Pt in multi-wall carbon nanotube and poly-pyrrole conductive polymer electrocatalysts (Pt/PPy/MWCNT). A home-made Pt/PPy/MWCNT catalyst was first evaluated by comparing its electrochemical active surface area (ESA) with E-Tek commercial catalysts by cyclic voltammetry in $H_2SO_4$ solution. Then, the methanol oxidation currents of Pt/PPy/MWCNT and the hydrogen peaks in $H_2SO_4$ solution were serially measured with microporous electrode. This provided the current density of methanol oxidation based on the ESA, allowing a quantitative comparison of catalytic activity. The current densities were also measured for Pt/C catalysts of E-Tek and Tanaka Precious Metal Co. The current densities for the different catalysts were similar, implying that catalytic activity depended directly on the ESA rather than charge transfer or electronic conductivity.

Field Emission From Carbon Nanotubes Grown On Line-patterned Cathode Electrodes

  • Kim, B.K.;Kong, B.Y.;Seon, J.Y.;Lee, N.S.;Kim, H.J.;Han, I.T.;Kim, J.M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.471-474
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    • 2004
  • We investigated field emission (FE) characteristics of multi-walled carbon nanotubes (CNTs) grown on all over patterned cathode electrode lines (CL pattern) and grown on along the central areas of the cathode lines(CL pattern). The CNTs grown on the SL pattern showed a lower threshold voltage and higher emission current than those on the CL pattern, due to the concentration of electric fields at the edges of the cathode lines. For the SL-patterned CNTs, however, the FE gradually spread out to the neighbors with time, and was instantly extinguished in some area and then slowly resumed again. Such areal- spread FE did not occur for the CL-patterned sample, leading to the stable FE together with the instant turn-on capability. It is suggested that the spread FE and instability for the SL-patterned CNTs may be related to the electrical charging on the insulator surface around the cathode line edges.

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Electrolytic Deposition of Metal Ions Using A Liquid Cadmium Cathode

  • Shim, Joon-Bo;Ahn, Byung-Gil;Kwon, Sang-Woon;Kim, Eung-Ho;Yoo, Jae-Hyung
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.337-337
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    • 2004
  • As one of researches for the P & T purposes, a basic experiment on the recovery of actinide elements from the mixture with rare earth elements by means of electrorefining using a liquid cadmium cathode in the LiCl-KC1 eutectic melt was carried out. In order to examine the behaviors of electrodeposition of metal ions on a liquid electrode, recovery experiments of rare earth metals resulting from forming electrodeposits were performed by a galvanostatic electrolysis method at various current densities. A cyclic voltammetric technique was applied to determine reduction-oxidation potential of each metal element in the melt and to detect the changes of the multi component melt composition for on-line monitoring. Also, a collaboration study with RIAR was completed to test the preliminary feasibility on a recovery of actinide elements from the mixture with rare earth elements using a liquid cadmium cathode and actinide metals. Experimental results showed that the ratio of actinides to rare earths, 9: 0.5∼1 led to the rare earth content of about 5∼10 wt% in the deposit.

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Durability Evaluation of ER Fluids in Hydraulic Control Systems (유압제어시스템 적용을 위한 ER 밸브의 내구성 평가)

  • Kim, Do-Tae;Jang, Sung-Cheol
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.2
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    • pp.100-105
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    • 2007
  • Electro-rheological(ER) fluid and valve are fabricated and evaluated experimentally in its durability to utilize the hydraulic control systems for long term operation. The two-ports ER valve used in the experiment consist of twelve parallel multi-layer electrodes and provide a restriction to the passage of ER fluid because of the viscous pressure drop and a component induced by the electric field. The durability test of ER valve are performed by measuring the surface roughness of electrodes with variation of an electric field strength and test time(1000 or 1800min.). Also, the shear stress and shear rate are measured to evaluate the durability of ER fluid as function of time. After durability test, ER shear stress increases approximately proportional to the shear rate with applied electric field intensity, In the ER valve, the center line average height roughness(Ra) of copper electrode increases about 1.56 times and ten-point median height roughness(Rz) increases about 2.2 times after the durability test. An understanding of these durability is essential to predicting the service life of ER fluid and valves.

Estimation of Partial Discharge Sources in a Model GIS through the Analysis of UHF Signals (UHF 신호 분석을 통한 모의 GIS내 부분방전원 추정)

  • 전재근;곽희로;노영수;이동준
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.4
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    • pp.112-117
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    • 2004
  • This paper describes the analysis of the UHF signal characteristics due to the partial discharge sources which can exist in a GIS. For the experiment, a model GIS was made and 5 types of discharge source were created as follows; corona discharge, surface discharge, void discharge, discharge due to free particle, discharge from floating electrode. The frequency spectra and the phase characteristics of UHF signals were induced by UHF signal analysis. The results were quantified to systematically adapt to analyze the PD sources in the GIS and utilized as algorithm data based on the neural network for Back-Propagation Algorithm with a multi-layer structure. The perception rate of the constructed algorithm showed approximately 94[%] and 82[%] in learning and testing data, respectively.

High Luminous Efficiency Flat Light Source with Xe mixture Gas Discharge and Areal Brightness Control Method (제논 혼합가스를 이용한 고효율 면광원과 국부적 밝기 제어 방식)

  • Jung, Jae-Chul;Seo, In-Woo;Oh, Byung-Joo;Whang, Ki-Woong
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2009.10a
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    • pp.153-157
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    • 2009
  • A Highly efficient Mercury-free Flat Fluorescent Lamp (MFFL) with dielectric barrier Xe gas discharge was developed for an alternative of conventional line-type Cold Cathode Fluorescent Lamps (CCFLs) which shows a wide voltage margin and a stable discharge operation for diffuse glow discharge with an application of a auxiliary electrode. Electro-optic characteristics of the MFFL were examined through the changes in ambient temperature, total pressure and Xe partial pressure. the single cell is expanded into a multi-structured configuration to realize a large sized lamp by a simple repetition of the single cells, and a new driving scheme is proposed for an adaptive brightness control using dual auxiliary electrodes and bi-polar drive scheme. In addition, interesting application of this ultra high luminance flat lamp by the optimization of the gas condition and the pattern of the rear phosphor layer is suggested as a good alternative of daylight lamp source

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