• Title/Summary/Keyword: modified ternary

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A Controllable Ternary Interpolatory Subdivision Scheme

  • Zheng, Hongchan;Ye, Zhenglin;Chen, Zuoping;Zhao, Hongxing
    • International Journal of CAD/CAM
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    • 제5권1호
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    • pp.29-38
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    • 2005
  • A non-uniform 3-point ternary interpolatory subdivision scheme with variable subdivision weights is introduced. Its support is computed. The $C^0$ and $C^1$ convergence analysis are presented. To elevate its controllability, a modified edition is proposed. For every initial control point on the initial control polygon a shape weight is introduced. These weights can be used to control the shape of the corresponding subdivision curve easily and purposefully. The role of the initial shape weight is analyzed theoretically. The application of the presented schemes in designing smooth interpolatory curves and surfaces is discussed. In contrast to most conventional interpolatory subdivision scheme, the presented subdivision schemes have better locality. They can be used to generate $C^0$ or $C^1$ interpolatory subdivision curves or surfaces and control their shapes wholly or locally.

알칼리 활성화제를 첨가한 페로니켈슬래그 혼입 삼성분계 콘크리트의 동결융해 저항성 (Freeze-Thaw Resistance of Alkali Activated Ternary Blended Cement Incorporated with Ferronickel Slag)

  • 조원정;박광필;안기용
    • 한국건설순환자원학회논문집
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    • 제10권2호
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    • pp.159-167
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    • 2022
  • 본 연구에서는 보통 포틀랜드시멘트를 사용한 콘크리트와 광물질 혼화재료 및 알칼리활성화제를 첨가한 4종류의 배합으로 시편을 제작한 후 X선 회절분석, 미세구조분석, 압축강도, 동결융해저항성 및 SEM Image 분석을 실시하여 각 배합별 강도발현, 상대동탄성계수, 중량변화 등을 측정하여 기초물성 평가를 진행하였다. 페로니켈슬래그 혼입 삼성분계 시멘트는 보통포틀랜드 시멘트 배합(OPC)과 비슷한 수화물을 생성하는 경향을 보였으며, MgO 성분으로 인한 팽창성 수화물은 확인되지 않았다. 페로니켈슬래그를 혼입 시 3성분계 시멘트(30SP20FN)의 경우 OPC와 비교 시 공극률이 커지는 경향을 보였지만, 알칼리활성화제를 첨가할 경우 공극 분포가 변화하는 경향을 보였다. 또한, 알칼리활성화제의 첨가는 30SP20FN의 장기강도발현을 앞당기는 효과를 보였으며, 18~26 % 가량 강도가 증가함을 확인하였다. 30SP20FN의 경우 dilution effect로 인한 낮은 수화도의 영향으로 동결융해저항성이 떨어졌지만, 알칼리활성화제를 첨가할 경우 높은 상대동탄성계수를 유지하였으며, 동결융해 저항성이 우수한 것을 알 수 있었는데, 이는 변화된 공극 분포 때문인 것으로 사료된다. 본 연구에서 실시한 상대동탄성계수 측정 실험에 사용된 콘크리트 시편 모두 300 사이클에서 상대동탄성계수가 60 % 이상으로 우수한 동결융해 저항성을 나타내었다. 동결융해 작용을 받은 콘크리트의 미세구조를 분석한 결과, OPC 및 30SP20FN 콘크리트의 경우 비정질의 수화물이 서로 결합되어 있지 않고, 미세 균열이 발생함을 확인한 반면, 알칼리 활성화제를 혼입한 배합의 경우 균질한 내부 구조를 유지하였다.

ASR Resistance of Ternary Cementitious Systems Containing Silica Fume-Fly Ash Using Modified ASTM C 1260 Method

  • Shon, Chang-Seon;Kim, Young-Su;Jeong, Jae-Dong
    • 콘크리트학회논문집
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    • 제15권3호
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    • pp.497-503
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    • 2003
  • Supplementary cementitious materials (SCM) such as fly ash, ground granulated blast furnace slag and silica fume are now being extensively used in concrete to control expansion due to alkali-silica reactivity (ASR). However, the replacement level of a single SCM needed to deleterious ASR expansion and cracking may create other problem and concerns. For example, incorporating silica fume at levels greater than 10% by mass of cement may lead to dispersion and workability concerns, while fly ash can lead to poor strength development at early age, The combination of silica fume and fly ash in ternary cementitious system may alleviate this and other concerns, and result in a number of synergistic effects. The aim of the study was to enable evaluation of more realistic suitability of a silica fume-fly ash combination system for ASR resistance based on an in-house modification of ASTM C 1260 test method. The modification can be more closely identified with actual field conditions. In this study three different strengths of NaOH test solution(1N, 0.5N, and 0.25N) were used to measure the expansion characteristics of mortar bar made with a reactive aggregate. The other variable included longer testing period of 28 days instead of a conventional 14 days.

Electrodeposition of Ternary CdZnS Semiconductor Thin Films Using a S-Modified Polycrystalline Au Electrode

  • Ham, Sun-Young;Cho, Se-Jin;Lee, Ung-Ki;Jeon, So-Yeon;Shin, Ji-Cheol;Myung, No-Seung;Paeng, Ki-Jung
    • 전기화학회지
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    • 제10권4호
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    • pp.262-264
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    • 2007
  • This paper describes a two-step approach for the electrochemical deposition of CdZnS thin films on the polycrystalline Au electrode. Initially, an Au substrate is electrochemically modified with a sulfur layer. In the second step, the layer is electroreduced to $S^{2-}$ in the electrolyte dosed with the requisite amount of $Cd^{2+}$ and $Zn^{2+}$ ions to generate CdZnS films in situ. This approach was validated using a combination of linear sweep voltammetry and electrochemical quartz crystal microgravimetry. Thus synthesized CdZnS thin films have different composition depending on the composition of electrolytes. CdZnS thin films are characterized by energy-dispersive X-ray analysis and Raman spectroscopy.

상용화제의 종류가 선형 PPS/PET 블렌드의 물성에 미치는 영향 (Effect of Compatibilizer Types on the Properties of Linear PPS/PET Blends)

  • 김성기;홍인권;이상묵
    • 폴리머
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    • 제37권4호
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    • pp.500-506
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    • 2013
  • 비혼화성인 선형의 폴리페닐렌설파이드(PPS)와 상용 폴리에틸렌테레프탈레이트(PET)의 블렌드 물성에 미치는 상용화제의 구조에 따른 영향을 조사하였다. 머독 혼련 스크류가 장착된 단축 압출기를 통하여 제조한 블렌드를 성형하여 그 특성들을 살펴보았다. 물성과 경제성을 고려하여 PPS/PET(40/60)을 기초 블렌드로 선정한 후 여기에 도메인 크기감소와 계면접착력 향상을 위하여 상용화제로 styrene-ethylene/butylene-styrene(SEBS), modified SEBS(m-SEBS), modified polystyrene(m-PS) 등을 사용하였다. 이들을 기초블렌드에 첨가하여 삼원블렌드를 제조한 후 열적, 유변학적, 기계적 특성을 측정하고 모폴로지를 관찰하였다. 기계적 물성은 각각 m-SEBS와 m-PS 첨가량 1 phr 부근에서 최대값을 보였는데 그 값이 이론적인 혼화성계의 값에 거의 근접하였으며 m-PS가 가장 뛰어난 성능을 보였다. m-SEBS와 m-PS는 선형 PPS와/또는 PET와의 부분적인 반응을 통해 상용성을 증대시켜서 더 큰 효과를 보인 것으로 판단된다. 이러한 삼원블렌드는 경제성있는 PPS 알로이로서 적용이 가능하리라 사료된다.

Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3계에 Yttria 첨가시 미세구조와 전기적 물성변화에 관한 연구 (Microstructure and Electrical Properties of Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 Ceramics Modified with Yttria)

  • 김창삼;이응상
    • 한국세라믹학회지
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    • 제24권3호
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    • pp.263-269
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    • 1987
  • It is investigated that the determination of the correlation between the change of microstructure and electrical properties. Yttria is added to the compositiojn of rhombohedral region in Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 ternary system. Average grian size, lattice parameters and distribution of yttrium are characterized by XRD, SEM and EDS. Electrical properties are determined by measurement of Curie temperature, piezoelectric properties and hysteresis loops. The results are as follows; 1. Both lattice parameters, a and ${\alpha}$, are changed by addition of yttria to the composition of rhomboheadral region in Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 ternary system and Curie temperature is proportional to the values at (90-${\alpha}$).

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삼치전가산기의 구성 (Construction of a Ternary Full-Adder)

  • 임인칠;조원경
    • 대한전자공학회논문지
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    • 제11권1호
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    • pp.15-22
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    • 1974
  • 본 논문은 전류제어형각성저항 회로를 사용한 새로운 삼치전가산기의 구성에 관하여 논한다. 부성저항특성을 이용하여 먼저 특수한 반가산기를 설계하고 이에 의하여 전가산기를 구성한다. 이평가계기는 부성저항 회로와 쇼트키-베리어 다이오드를 사용한 삼자정 회로에 의해 구성되며, 두 입력신호가 모두 "2"일 경우 Sum과 Carry 출력이 각각 "0"과 "1"의 간을 갖는다. 여기에 제안한 전가산기는 종래의 전가산기에 비하여 게이트 수가 감소되고, 속도가 개선된다. 회로소자는 트랜지스터와 쇼트키-베리어 다이오드, 저항만을 사용하여 IC화하는데 편리하게 하였다.

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SBR/Organoclay Nanocomposites for the Application on Tire Tread Compounds

  • Kim, Wook-Soo;Lee, Dong-Hyun;Kim, Il-Jin;Son, Min-Jin;Kim, Won-Ho;Cho, Seong-Gyu
    • Macromolecular Research
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    • 제17권10호
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    • pp.776-784
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    • 2009
  • N,N-dimethyldodecylamine (tertiary amine)-modified MMT (DDA-MMT) was prepared as an organically modified layered silicate (OLS), after which styrene-butadiene rubber (SBR) nanocomposites reinforced with the OLS were manufactured via the latex method. The layer distance of the OLS and the morphology of the nanocomposites were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). By increasing the amount of N,N-dimethyldodecylamine (DDA) up to 2.5 g, the maximum values of torque, tensile strength and wear resistance of the SBR nanocomposites were increased due to the increased dispersion of the silicate layers in the rubber matrix and the increased crosslinking of the SBR nanocomposites by DDA itself. When SBR nanocomposites were manufactured by using the ternary filler system (carbon black/silica/OLS) to improve their dynamic properties as a tire tread compound, the tan $\delta$(at $0^{\circ}C$ and $60^{\circ}C$) property of the compounds was improved by using metal stearates instead of stearic acid. The mechanical properties and wear resistance were increased by direct substitution of calcium stearate for stearic acid because the filler-rubber interaction was increased by the strong ionic effect between the calcium cation and silicates with anionic surface. However, as the amount of calcium stearate was further increased above 0.5 phr, the mechanical properties and wear resistance were degraded due to the lubrication effect of the excessive amount of calcium stearate. Consequently, the SBR/organoclay nanocomposites that used carbon black, silica, and organoclay as their ternary filler system showed excellent dynamic properties, mechanical properties and wear resistance as a tire tread compound for passenger cars when 0.5 phr of calcium stearate was substituted for the conventionally used stearic acid.

Removal Efficiency of Toxic Heavy Metal Ions in Wastewater by Double Surface-Modified Activated Carbon

  • Park, Geun-Il;Kim, In-Tae;Song, Kee-Chan;Kim, Kwang-Wook;Kim, Joon-Hyung;Yoo, Jae-Hyung
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.307-312
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    • 2001
  • Adsorption capacities of toxic heavy metal ions using as-received carbon(AC), single and double surface-modified activated carbon(OAC and DSMC) in wide pH ranges are extensively evaluated. Physical and chemical properties of surface-modified activated carbons are evaluated through BET analysis, surface acidity and oxides measurements. Based oil tile adsorption isotherms of Pb, Cd and Cr ions by AC, OAC and DSMC, the adsorption amount on DSMC was obviously higher than that on the other carbons. Breakthrough behaviors of ternary metal ions in a column packed with three kinds of carbon were also characterized with respect to the variations of the influent pH and concentration. The adsorption capacity of DSMC in a fixed bed stood a favorable comparison with that of as-received carbon.

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