• Mass Spectrometry Letters
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• v.2 no.2
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• pp.49-52
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• 2011

Competitive binding of $C_{60}$ and $C_{70}$ to meso-substituted porphyrins was studied by mass spectrometry (MS). Electrospray ionization MS was employed to acquire the mass spectra of 1 : 1 porphyrin-fullerene complexes formed in a mixture of mesosubstituted porphyrin and fullerite to determine the ratio of complexes between $C_{60}$ and $C_{70}$. Matrix-free laser desorption ionization MS was used to obtain the mass spectra of fullerite to measure the mole fraction of $C_{60}$ and $C_{70}$. The binding constant ratio ($K_{70}$/$K_{60}$) was determined from the mass spectral data. The difference in standard Gibbs free energy change, ${\Delta}({\Delta}G^o)_{70-60}$, for the competitive binding of $C_{60}$ and $C_{70}$ was calculated from $K_{70}$/$K_{60}$. Of the five porphyrins, tetraphenyl, tetra(4-pyridyl), tetra(4-carboxyphenyl), tetra(3,5-di-tert-butylphenyl), and tetra(pentafluorophenyl) porphyrins, the first three non-bulky porphyrins yield negative values of ${\Delta}({\Delta}G^o)_{70-60}$, whereas the other two bulky porphyrins result in positive values of ${\Delta}({\Delta}G^o)_{70-60}$. This result indicates that $C_{70}$ binding to porphyrin is thermodynamically favored over $C_{60}$ binding in non-bulky porphyrins, but disfavored in bulky ones. It also suggests that the binding mode of $C_{70}$is different between non-bulky and bulky porphyrins, which is in line with previous experimental findings of the "side-on" binding to non-bulky porphyrins and the $C_{60}$-like "end-on" binding to bulky porphyrins.

• Food Science of Animal Resources
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• v.32 no.6
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• pp.763-768
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• 2012

This study has been performed to measure the prevalence and microbial flora on chicken slaughtering as well as the processing process from the months of October to November. Whole-chicken rinsing technique was used in order to analyze the incidence of microorganisms on chicken carcass at the stage before chilling (after evisceration), after chilling and after cutting. The swab technique was used on processing the processed samples, such as working plates and cutting knives. Brine and cooling water from four cooling tubs were taken from each processing processes and were used as samples. Furthermore, the matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) for whole cell fingerprinting in combination with a dedicated bioinformatic software tool was used to identify the isolated microorganisms. Of the tested samples and processes, brine ($4.50{\pm}0.64$ Log CFU/mL) and chicken carcass before chilling ($4.15{\pm}0.46$ Log CFU/mL) showed the highest population of microorganisms; the predominant microbial flora of them were Moellerella wisconsensis (54.84%), a member of the Enterobacteriaceae family, and Escherichia coli (60.36%), respectively. However, the predominant microbial flora of cut carcass was changed to Staphylococcus aureus (27.32%), which is a kind of pathogenic microorganism that can cause a food-borne illness. Therefore, the slaughtering and processing procedure of chicken are needed to be controlled more hygienically.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2006.05a
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• pp.1334-1337
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• 2006

System identification is the field of modeling dynamic systems from experimental data. As a modeling technique, we can mention finite element method (FEM). In addition, we are able to measure modal data as the experimental data. The system can be generally categorized into a gray box and black box. In the gray box, we know mathematical model of a system, but we don't know structural parameters exactly, so we need to estimate structural parameters. In the black box, we don't know a system completely, so we need to identify system from nothing. To date, various system identification methods have been developed. Among them, we introduce system realization theory which uses Hankel matrix and Eigensystem Realization Algorithm (ERA) that enable us to identify modal parameters from noisy measurement data. Although we obtain noise-free data, however, we are likely to face difficulties in identifying a structure with hidden modes. Hidden modes can be occurred when the input or output position comes to a nodal point. If we change a system using a mode decoupling controller, the hidden modes can be revealed. Because we know the perturbation quantities in a closed loop system with the controller, we can realize an original system by subtracting perturbation quantities from the closed loop system. In this paper, we propose a novel method to identify a structure with hidden modes using the mode decoupling controller and the associated example is given for illustration.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.30 no.1
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• pp.49-55
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• 2002

In this paper, we present the simulation monitoring of strain and temperature during and after the cure of unsymmetric composite laminate using fiber optic sensors. Fiber Bragg grating/extrinsic Fabry-Perot interferometric (FBG/EFPI) hybrid sensors are used to measure those measurands. The characteristic matrix of the sensor is analytically derived and measurements can be done without sensor calibration. A wavelength-swept fiber laser is utilised as a lighr source. Two FBG/EFPI sensors are embedded in a graphite/epoxy unsymmetric cross-ply composite laminate in different directions and different locations. We perform a real time monitoring of fabrication strains and temperatures at two points of the composite laminate during cure process in an autoclave. Also, the thermal strains and temperatures of the fabricated laminate are measured in a thermal chamber. Through these experiments, we can provide a basis for the efficient smart processing of composite and know the thermal behavior of unsymmetric cross-ply composite laminate.

• The Journal of Korean Academy of Prosthodontics
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• v.44 no.3
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• pp.333-342
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• 2006

Statement of problem. Although many studies have been carried out to investigate the correlation between the degree of conversion and the flexural strength of composite resins, there is minimal information in the literature attempting to compare degree of conversion, flexural strength and their correlation between restorative composite resins and flowable composite resins. Purpose. The purposes of this study were to measure the degree of conversion and flexural strength of composite resins with different rheological behavior and to correlate the two properties. Materials and methods. Four restorative (Vit-1-escence, Z-250, Tetric ceram, Esthet-X) and four flowable (Aeliteflo, Admiraflow, Permaflo, Revolution) light-curing composite resins were investigated. The degree of conversion(DC) was analyzed with Fourier transfer infra-red spectroscopy(FTIR) spectrum by a potassium bromide(KBr) pellet transmission method. The spectrum of the unpolymerized specimen had been measured before the specimen was irradiated for 60s with a visible light curing unit. The Poiymerized specimen was scanned for its in spectrum. The flexural strength(FS) was measured with 3-point bending test according to ISO 4049 after storage in water at $37^{\circ}C$ for 24 hours. The data were statistically analyzed by an independent sample t-test and one-way ANOVA at the significance level of 0.05. The dependence of flexural strength on the degree of conversion was also analyzed by regression analysis. Results. Mean DC and FS values ranged from 43% to 61% and from 84.7MPa to 156.7MPa respectively. DC values of the flowable composite resins were significantly higher than those of restorative composite resins (P < 0.05). The FS values of restorative composite resins were greater than those of flowable composite resins. No statistically significant correlation was observed between the DC and the FS tested in any of the composites. The dependence of FS on DC in restorative or flowable composite resins was not significant. Conclusion. It can be concluded that radical polymerization of the organic matrix is not a major factor in determining flexural strength of the commercially available composite resins.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.15 no.2
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• pp.121-126
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• 2004

This paper presents an SAR-data calibration technique using a well-calibrated scatterometer. At first a fully-polarimetric antenna pattern(magnitude and phase) of the antenna main-beam using a conducting sphere was measured. Then, this data were used to calibrate polarimetrically an auto-mounted network analyzer-based scatterometer system. This scatterometer system can be used to measure the accurate Mueller matrices of earth surfaces such as grass fields, rice fields and bare soil surfaces; i.e., the phase-difference parameters can be obtained as well as the radar scattering coefficients. If a polarimetrically calibrated scatterometer is operated at the same time with the SAR system, the scatterometer data can be used to correct the SAR data, especially the phase-difference parameters. It was found that the correction effect is remarkable for the degree of correlation ${\alpha}$, which is one of the phase-difference parameter, while the correction effect is negligible for the magnitude parameters(backscattering coefficients).

• International Journal of Naval Architecture and Ocean Engineering
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• v.6 no.4
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• pp.1130-1147
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• 2014

Large size ships have a very flexible construction resulting in low resonance frequencies of the structural eigen-modes. This feature increases the dynamic response of the structure on short period waves (springing) and on impulsive wave loads (whipping). This dynamic response in its turn increases both the fatigue damage and the ultimate load on the structure; these aspects illustrate the importance of including the dynamic response into the design loads for these ship types. Experiments have been carried out using a segmented scaled model of a container ship in a Seakeeping Basin. This paper describes the development of the model for these experiments; the choice was made to divide the hull into six rigid segments connected with a flexible beam. In order to model the typical feature of the open structure of the containership that the shear center is well below the keel line of the vessel, the beam was built into the model as low as possible. The model was instrumented with accelerometers and rotation rate gyroscopes on each segment, relative wave height meters and pressure gauges in the bow area. The beam was instrumented with strain gauges to measure the internal loads at the position of each of the cuts. Experiments have been carried out in regular waves at different amplitudes for the same wave period and in long crested irregular waves for a matrix of wave heights and periods. The results of the experiments are compared to results of calculations with a linear model based on potential flow theory that includes the effects of the flexural modes. Some of the tests were repeated with additional links between the segments to increase the model rigidity by several orders of magnitude, in order to compare the loads between a rigid and a flexible model.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.6
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• pp.1186-1190
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• 2009

In this paper, we studied on a characteristic of movement of charged particle in equal electric field. In order to fabricate a panel, we used positive charged toner particles of black and negative one of yellow. Panel was biased rectangle pulse without any overshoot. Also, panel's optical characteristics with contrast ratio and viewing angle is measured with RT-200. Response time was measure by using incident laser and detective photodiode. The distribution of m/q of particles by driving in panel throughout the contrast ratio and response time. As a results, driving voltage, contrast ratio, and response time are decided by m/q of charged particles and when m/q of charged particles in panel have regular distribution, it is induce improvement driving characteristics.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.13 no.1
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• pp.75-85
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• 2000

When applying a system identification technique, which incorporates an experimental model to a corresponding finite element model of a structure, one of the major problems is the large difference in the numbers of degrees of freedom (dof) between the two models. While there are large number of dofs in a finite element model, the number of measurement points is practically limited. So it is very difficult to incorporate them. Especially rotational dofs are hard to measure. In this study a method is presented for estimating structural dynamic responses at unmeasurable locations in frequency domain. The proposed method is tested numerically and the feasibility for practical application has been demonstrated through an example structure under moving loads, where translational and rotational dofs of beam at a center point are estimated from the partial measurements of responses at accessible points.

• The Journal of Korean Medicine
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• v.31 no.2
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• pp.36-47
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• 2010

Objective: The purpose of this study was to investigate the effects of skin application with Gelidium amansii extract on skin with deep second degree burns in mice. Methods: BALB/c mice were divided into four groups: normal (NOR) group; burn-elicited mice (CON) group, Silmazine-treated mice after burn elicitation (ST) group, and Gelidium amansii-extract treated mice after burn elicitation (GT) group. To examine the skin recovery effect after burn, changes of burn area, angiogenesis and histologic structure were analyzed. To measure effect of edema regulation, matrix metalloproteinase-9 (MMP-9) was analyzed. To estimate the skin regenerative & stable effect, 5-bromo-2'-deoxyuridine (BrdU) and substance P were analyzed. Results: 2 weeks later, 1. The size of burn area decreased in the GT and ST groups more than the CON group. 2. Alleviation of angiogenesis appeared in the GT and ST groups more than in the CON group. 3. Blood clot, epithelial cell hyperplasia, and inflammatory cell infiltration declined in the GT and ST groups more than in the CON group. 4. MMP-9, BrdU, and substance P positive reaction decreased in the GT and ST groups more than in the CON group 5. In the comparative study, the GT group was superior to the ST group. Conclusion: The skin application of Gelidium amansii extract could lessen skin damage by the medium of regulation MMP-9 activation. This skin stabilization was induced in mice with deep second degree burns.