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Aging Characteristics of NOx Storage and Reduction Catalyst for Lean-bum Natural Gas Vehicles (린번 천연가스자동차용 NOx 흡장촉매의 열화특성)

  • Choi, Byung-Chul;Lee, Choon-Hee
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.147-152
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    • 2007
  • This study investigates the aging characteristics of NOx storage and reduction(NSR) catalyst on the emission conditions of lean burn natural gas vehicles. We designed various NSR catalysts using by the double-layer washcoat technology to increase of a surface area and a thermal durability performance of the catalysts. The experiments were conducted with 3 kinds of the NSR catalysts, which were manufactured using by a honeycomb cordierite substrate. It was found that Ba is weak in the thermal aging because it has lower melting temperature than that of precious metals (PMs). The suitable loading amount of Ba in this study should be about 42 g/L from the results of the NOx adsorption and the NOx reduction efficiency. The major reason in deactivation of the NSR catalyst is the decrease of the adsorption site owing to the agglomeration and sintering of Ba rather than PM aging by hydrothermal aging. It was confirmed by results of BET, SEM and TEM.

Potassium loading effects for activated carbon fiber pre-treated with phosphoric acid (인산을 전처리한 활성탄소섬유에 칼륨 처리효과)

  • Oh, Won-Chun;Bae, Jang-Soon
    • Analytical Science and Technology
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    • v.18 no.4
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    • pp.355-361
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    • 2005
  • The objective of this paper is to compare the surface features of two kinds of activated caron fiber (ACF) treated with potassium and the variation of their properties by phosphoric acid pre-treatment. X-ray diffraction (XRD) patterns indicate that activated carbon fiber containing potassium species show better performance for metal and metal salts by pre-treatment with phosphoric acid. In order to present the causes of the differences in surface properties and specific surface area after the samples were treated with phosphoric acid, pore structure and surface morphology were investigated by adsorption analysis and SEM. For the chemical composition microanalysis for potassium leading of the activated carbon fibers pre-treated with phosphoric acid, samples were analyzed by EDX. Finally, the type and quality of oxygen groups were determined from the method proposed by Boehm.

Stability augmentation of helicopter rotor blades using passive damping of shape memory alloys

  • Yun, Chul-Yong;Kim, Dae-Sung;Kim, Seung-Jo
    • International Journal of Aeronautical and Space Sciences
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    • v.7 no.1
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    • pp.137-147
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    • 2006
  • In this study, shape memory alloy damper with characteristics of pseudoelastic hysteresis for helicopter rotor blades are investigated. SMAs can be available in damping augmentation of vibrating structures. SMAs show large hysteresis in the process of pseudoelastic austenite-martensite phase transformation which takes place while subjected to loading above the austenite finish temperature. Since SMAs display pseudoelastic hysteresis behavior over large strain ranges, a significant amount of energy dissipation is possible. A damper can be designed with SMA wires prestressed to a baseline level somewhere in the middle of the pseudoelastic stress range. An experimental study of the effects of pre-strain and cyclic strain amplitude as well as frequency on the damping behavior of pseudoelastic shape memory alloy wires are performed. The effects of the shape memory alloy damper on aeroelastic and ground resonance stability of helicopter are studied. In aeroelastic stability, the dynamic characteristics of blades related to pitch angle and the amplitude of lag motion for the rotor equipped with SMA damper were examined. The performance of SMA damper on ground resonance instability are presented through the frequencies and modal damping with respect to rotating speed.

An energy-efficiency approach for bidirectional amplified-and-forward relaying with asymmetric traffic in OFDM systems

  • Jia, Nianlong;Feng, Wenjiang;Zhong, Yuanchang;Kang, Hong
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.8 no.11
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    • pp.4087-4102
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    • 2014
  • Two-way relaying is an effective way of improving system spectral efficiency by making use of physical layer network coding. However, energy efficiency in OFDM-based bidirectional relaying with asymmetric traffic requirement has not been investigated. In this study, we focused on subcarrier transmission mode selection, bit loading, and power allocation in a multicarrier single amplified-and-forward relay system. In this scheme, each subcarrier can operate in two transmission modes: one-way relaying and two-way relaying. The problem is formulated as a mixed integer programming problem. We adopt a structural approximation optimization method that first decouples the original problem into two suboptimal problems with fixed subcarrier subsets and then finds the optimal subcarrier assignment subsets. Although the suboptimal problems are nonconvex, the results obtained for a single-tone system are used to transform them to convex problems. To find the optimal subcarrier assignment subsets, an iterative algorithm based on subcarrier ranking and matching is developed. Simulation results show that the proposed method can improve system performance compared with conventional methods. Some interesting insights are also obtained via simulation.

An Experimental Study on The Fire Resistance Performance of Steel Framed motar Beam with Loading Condition (철골철망 모르타르 보의 재하하중에 따른 내화성능변화에 관한 실험적 연구)

  • Kim, Hyung-Jun;Kim, Heung-Youl;Cho, Bum-Yean;Yeo, In-Hwan;Min, Byung-Youl
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.11a
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    • pp.103-106
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    • 2011
  • 국토해양부령 제320호인 건축물의 피난 방화구조 등의 기준에 관한 규칙 제 3조에서는 내화구조에 관한 세부기준을 정하고 있다. 이러한 법정내화구조 중에서 철골철망 모르타르조의 피복두께에 따른 내화성능 변화를 분석하기 위하여, 본 연구에서는 고온 재하하중조건에서 내화실험을 수행하였다. 철골조의 피복두께를 50 mm ${\cdot}$ 60 mm ${\cdot}$ 70 mm로 변화하여 내화실험을 수행하였으며, 재하하중비를 변화시킴으로 동일 피복두께에서의 내화성능 변화를 분석하고자 하였다. 실험결과 단면소성모멘트 대비 하중비 0.4 조건에서의 철골철망 모르타르조의 내화성능은 180분이 나왔으며, 피난 방화구조 등의 기준의 별표 1에서 정하고 있는 내화구조의 성능기준 중 최대 내화성능시간인 3시간을 확보하는 것으로 나타났다.

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Performance Assessment of PVA Geotextile/HDPE Geomembrane Composites

  • Jeon, Han-Yong;Hong, Sang-Jin;Lyoo, Won-Seok
    • Journal of the Korean Geosynthetics Society
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    • v.4 no.1
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    • pp.37-46
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    • 2005
  • PVA geotextile/HDPE geomembrane composites were made to examine the waste landfill related properties. Tensile properties, tear and bursting strengths, AOS(apparent opening size) and permittivity of PVA geotextiles were evaluated, respectively. Ultraviolet stability and chemical resistance to the leachate was evaluated also. Friction property and creep deformation were tested at various loading condition. From this, it was seen that PVA geotextile/HDPE geomembrane composites have more excellent properties than the typically used polypropylene and polyester geotextiles in waste landfill. Finally, creep deformation behaviours of PVA geotextile/HDPE geomembrane composites were more stable than polypropylene and polyester geotextiles through the reduction factor analysis.

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Rapid Acquisition of m-sequence Signals by Sequential Estimation with Flexible Structure (가변구조를 갖는 순차 예측 방법을 이용한 m 계열 신호의 고속 포착)

  • 현광민;박상규
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.27 no.7B
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    • pp.664-672
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    • 2002
  • This paper analyzes a sequential estimator with flexible structure for rapid acquisition of the m-sequence signals. If the received PN chips stored in the estimator's internal registers as initial loading values include one error, this chip with error can be corrected through multiple local PN code generators to achieve high-speed acquisition performance. Hamming distance between regenerated local PN codes from the proposed system and received PN code is compared with given threshold to choose a possible correct path and to declare success of the code acquisition. Using signal flow graph, average acquisition time that depends on detection and false alarm probability is calculated. By modifying generally used matched filter structure for PN code acquisition, the proposed system provides flexible structure and rapid acquisition process.

Synthesis and Characterization of ZnS and ZnS/TiO2 Nanocomposites and Their Enhanced Photo-decolorization of MB and 1,5-Diphenyl Carbazide

  • Meng, Ze-Da;Ullah, Kefayat;Zhu, Lei;Ye, Shu;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.307-311
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    • 2014
  • ZnS and $ZnS/TiO_2$ were prepared by chemical deposition. The prepared photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), and transmission electron microscopy (TEM). The generation of reactive oxygen species was detected by monitoring the oxidation reaction from 1,5-diphenyl carbazide (DPCI) to 1,5-diphenyl carbazone (DPCO). Excellent catalytic degradation of methylene blue (MB) solution was observed using the $ZnS/TiO_2$ composites during irradiation with visible light. The results show that the photocatalytic performance of $TiO_2$ nanoparticles is improved by loading with ZnS.

Recent Developments in Metal Oxide Gas Sensors for Breath Analysis (산화물 반도체를 이용한 최신 호기센서 기술 동향)

  • Yoon, Ji-Wook;Lee, Jong-Heun
    • Ceramist
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    • v.22 no.1
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    • pp.70-81
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    • 2019
  • Breath analysis is rapidly evolving as a non-invasive disease recognition and diagnosis method. Metal oxide gas sensors are one of the most ideal platforms for realizing portable, hand-held breath analysis devices in the near future. This paper reviewed the recent developments in metal oxide gas sensors detecting exhaled biomarker gases such as nitric oxides, acetone, ammonia, hydrogen sulfide, and hydrocarbons. Emphasis was placed on strategies to tailor sensing materials/films capable of highly selective and sensitive detection of biomarker gases with negligible cross-response to ethanol, the major interfering breath gas. Specific examples were given to highlight the validity of the strategies, which include optimization of sensing temperature, doping additives, utilizing acid-base interaction, loading catalysts, and controlling gas reforming reaction. In addition, we briefly discussed the design and optimization method of gas sensor arrays for implementing the simultaneous assessment of multiple diseases. Breath analysis using high-performance metal oxide gas sensors/arrays will open new roads for point-of-care diagnosis of diseases such as asthma, diabetes, kidney dysfunction, halitosis, and lung cancer.

TFBAR Lattice and Balanced Type Filter Topologies (격자형 및 평형 구조를 가지는 박막공진 여파기에 관한 연구)

  • 김건욱;구명권;육종관;박한규
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.13 no.10
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    • pp.1048-1053
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    • 2002
  • In this paper, thin film bulk acoustic resonator(TFBAR) lattice and balanced type filter topologies are designed and fabricated. Aluminium nitride and platinum are used for piezoelectric material and top and bottom electrodes, respectively. Air-gap is placed to avoid silicon substrate loading effect and the performance of these lattice and balanced filters is compared with ladder filters. These filters have selectivity over 15 dB for lattice type and 30 dB for balanced type and reveal wider bandwidth of the ladder filters. For balanced type filters, minor tuning procedure is not needed and they are readily available for RF filter in wireless applications.