DOI QR코드

DOI QR Code

Synthesis and Characterization of ZnS and ZnS/TiO2 Nanocomposites and Their Enhanced Photo-decolorization of MB and 1,5-Diphenyl Carbazide

  • Meng, Ze-Da (Jiangsu Key Laboratory of Environmental Functional Materials, College of Chemistry and Bioengineering, Suzhou University of Science and Technology) ;
  • Ullah, Kefayat (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Zhu, Lei (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Ye, Shu (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Oh, Won-Chun (Department of Advanced Materials Science & Engineering, Hanseo University)
  • Received : 2013.12.21
  • Accepted : 2014.06.13
  • Published : 2014.07.31

Abstract

ZnS and $ZnS/TiO_2$ were prepared by chemical deposition. The prepared photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), and transmission electron microscopy (TEM). The generation of reactive oxygen species was detected by monitoring the oxidation reaction from 1,5-diphenyl carbazide (DPCI) to 1,5-diphenyl carbazone (DPCO). Excellent catalytic degradation of methylene blue (MB) solution was observed using the $ZnS/TiO_2$ composites during irradiation with visible light. The results show that the photocatalytic performance of $TiO_2$ nanoparticles is improved by loading with ZnS.

Keywords

References

  1. X. Chen and S. S. Mao, "Titanium Dioxide Nanomaterials, Synthesis, Properties, Modifications and Applications," Chem. Rev., 107 [7] 2891-959 (2007). https://doi.org/10.1021/cr0500535
  2. C. Burda, Y. Lou, X. Chen, A. Samia, J. Stout, and J. Gole, "Enhance Nitrogen Doping in $TiO_2$ Nanomaterials," Nano Lett., 3 [8] 1049-51 (2003). https://doi.org/10.1021/nl034332o
  3. K. Ullah, L. Zhu, Z. D. Meng, S. Ye, Q. Sun, and W. C. Oh, "A Facile and Fast Synthesis of Novel Composite Pt-graphene/$TiO_2$ with Enhanced Photocatalytic Activity under UV/Visible Light," Chem. Eng. J., 231 76-83 (2013). https://doi.org/10.1016/j.cej.2013.07.014
  4. Y. Xie, J. Huang, B. Li, Y. Liu, and Y. Qian, "A Novel Peanut-like Nanostructure of II-VI Semiconductor CdS and ZnS," Adv. Mater., 12 [20] 1523-26 (2000). https://doi.org/10.1002/1521-4095(200010)12:20<1523::AID-ADMA1523>3.0.CO;2-T
  5. K. Ullah, S. Ye, S. B. Jo, L. Zhu, K. Y. Cho, and W. C. Oh, "Optical and Photocatalytic Properties of Novel Heterogeneous $PtSe_2$-graphene/$TiO_2$ Nanocomposites Synthesized via Ultrasonic Assisted Techniques," Ultrason. Sonochem., 21 [5] 1849-57 (2014). https://doi.org/10.1016/j.ultsonch.2014.04.016
  6. S. Yu and M. Yoshimura, "Shape and Phase Control of ZnS Nanocrystals Template Fabrication of Wurtzite ZnS Single-crystal Nanosheets and ZnO Flake-like Dendrites from a Lamellar Molecular Precursor $ZnS(NH_2CH_2CH_2NH_2)_{0.5}$," Adv Mater., 14 [4] 296-300 (2002). https://doi.org/10.1002/1521-4095(20020219)14:4<296::AID-ADMA296>3.0.CO;2-6
  7. T. Torimoto, A. Obayashi, S. Kuwabata, H. Yasuda, H. Mori, and H. Yoneyama. "Preparation of Size-quantized ZnS Thin Films Using Electrochemical Atomic Layer Epitaxy and their Photo Electro Chemical Properties," Langmuir, 16 [13] 5820-34 (2000). https://doi.org/10.1021/la000133y
  8. K. Sooklal, B. S. Cullum, M. Angel, and C. J. Murphy, "Photo Physical Properties of ZnS Nanoclusters with Spatially Localized $Mn^{2+}$," J. Phys. Chem., 100 [11] 4551-55 (1996). https://doi.org/10.1021/jp952377a
  9. T. Mokari and U. Banin, "Synthesis and Properties of CdSe/ ZnS Core/shell Nanorods," Chem. Mater., 15 [20] 3955-60 (2003). https://doi.org/10.1021/cm034173+
  10. Z. D. Meng, T. Ghosh, L. Zhu, J. G. Choi, C. Y. Park, and W. C. Oh, "Synthesis of Fullerene Modified with Ag2S with High Photocatalytic Activity under Visible Light," J. Mater. Chem., 22 [31] 16127-35 (2012). https://doi.org/10.1039/c2jm32344c
  11. J. Wang, Y. W. Guo, B. Liu, X. D. Jin, L. J. Liu, R. Xu, Y. M. Kong, and B. X. Wang, "Detection and Analysis of Reactive Oxygen Species (ROS) Generated by Nano Sized $TiO_2$ Powder under Ultrasonic Irradiation and Application in Sonocatalytic Degradation of Organic Dyes," Ultrason. Sonochem., 18 [1] 177-83 (2011). https://doi.org/10.1016/j.ultsonch.2010.05.002
  12. V. Ramaswamy, N. B. Jagtap, S. Vijayanand, D. S. Bhange, and P. S. Awati, "Photocatalytic Decomposition of Methylene Blue on Nanocrystalline Titania Prepared by Different Methods," Mater. Res. Bull., 43 [5] 1145-52 (2008). https://doi.org/10.1016/j.materresbull.2007.06.003
  13. X. W. Zhang, M. H. Zhou, and L. C. Lei, "Preparation of Photocatalytic $TiO_2$ Coating of Nano Sized Particles Supported on Activated Carbon by AP-MOCVD," Carbon, 43 [8] 1700-08 (2005). https://doi.org/10.1016/j.carbon.2005.02.013
  14. H. Liu, X. N. Dong, X. C. Wang, C. C. Sun, J. Q. Li, and Z. F. Zhu, "A Green and Direct Synthesis of Graphene Oxide Encapsulated $TiO_2$ Core/shell Structures with Enhanced Photoactivity," Chem. Eng. J., 230 279-85 (2013). https://doi.org/10.1016/j.cej.2013.06.092
  15. P. Xu, T. Xu, J. Lu, S. M. Gao, N. S. Hosmae, B. B. Huang, Y. Dai, and Y. B. Wang, "Visible Light-driven Photocatalytic S-and C-co Doped Meso/nanoporous $TiO_2$," Energy Environ. Sci., 3 [8] 1128-34 (2010). https://doi.org/10.1039/c001940m
  16. Y. Xiaodan, W. Qingyin, J. Shicheng, and G. Yihang, "Nanoscale $ZnS/TiO_2$ Composites: Preparation, Characterization, and Visible-light Photocatalytic Activity," Mater. Charact., 57 [4-5] 333-41 (2006). https://doi.org/10.1016/j.matchar.2006.02.011
  17. S. Bagwasi, B. Z. Tian, J. L. Zhang, and M. Nasir, "Synthesis, Characterization and Application of Bismuth and Boron Co-doped $TiO_2$: A Visible Light Active Photocatalyst," Chem. Eng. J., 217 108-18 (2013). https://doi.org/10.1016/j.cej.2012.11.080
  18. Y. Hu, W. Chen, J. Chen, and Z. Zhang, "Preparation of ZnS Nanocrystals in Network of Hydrogen," Mater. Lett., 57 1312-16 (2003). https://doi.org/10.1016/S0167-577X(02)00978-3
  19. W. Wang, I. Germanenko, and M. S. El-Shall, "Room-temperature Synthesis and Characterization of Nanocrystalline CdS, ZnS, and $Cd_xZn_{1-x}$S," Chem. Mater., 14 [7] 3028-33 (2002). https://doi.org/10.1021/cm020040x
  20. Z. D. Meng, L. Zhu, K. Ullah, S. Ye, Q. Sun, W. K. Jang, and W. C. Oh, "Study of the Photochemically Generated of Oxygen Species by Fullerene Photosensitized $CoS_2$ Nanocompounds," Mater. Res. Bull., 49 272-78 (2014). https://doi.org/10.1016/j.materresbull.2013.08.061
  21. O. C. Monteiro, M. C. Neves, and T. Trindade, "Submicron Silica Nano Coating with Zinc Sulfide Using a Singlesource Method," J. Nanosci. Nanotechnol., 4 [1-2] 146-50 (2004). https://doi.org/10.1166/jnn.2004.024
  22. K. Ullah, Z. D. Meng, S. Ye, L. Zhu, and W. C. Oh, "Synthesis and Characterization of Novel PbS-Graphene/ $TiO_2$ Composite with Enhanced Photocatalytic Activity," J. Ind. Eng. Chem., 20 [3] 1035-42 (2014). https://doi.org/10.1016/j.jiec.2013.06.040
  23. J. Wang, Z. Jiang, L. Q. Zhang, P. L. Kang, Y. P. Xie, Y. Lv, R. Xu, and X. D. Zhang, "Sonocatalytic Degradation of Some Dyestuffs and Somparison of Catalytic Activities of Nano-sized $TiO_2$, Nano-sized ZnO and Composite $TiO_2$/ZnO Powders under Ultrasonic Irradiation," Ultrason. Sonochem., 16 [2] 225-31 (2009). https://doi.org/10.1016/j.ultsonch.2008.08.005