• Proceedings of the KSME Conference
• /
• 2000.04b
• /
• pp.37-44
• /
• 2000

Numerical investigation is made to study the effects of natural convection on the formation of macrosegregation of a Pb-Sn alloy solidification process in a 2-D confined rectangle mold. The governing equations are calculated using previous continuum models with SIMPLE algorithm doring the solidification process. In addition. to track the solid-liquid interface with time variations. the moving boundary condition Is adopted and irregular interface shapes are treated with Boundary-Fitted Coordinate system. As the temperature reduce from the liquidus to the solidus, the liquid concentration of Sn. the lighter constituent, increases. Then the buoyancy-driven flow due to temperature and liquid composition gradients, called thermosolutal convection or double diffusion, occurs in the mushy region and forms the complicated macrosegregation maps. Related to this phnomena, effects on the macrosegregation formation depending on the cooling condition and gravity values are described.

• Transactions of Materials Processing
• /
• v.16 no.3 s.93
• /
• pp.178-186
• /
• 2007

Rheo-forging process of aluminum alloy is suitable for large parts of net shape without defects and excellent mechanical properties in comparison with conventional die casting and forging process. To control the microstructure of the product with high mechanical properties in rheo-forming, solid fraction is required to prevent porosity and liquid segregation. Therefore, in rheo-forging process, die shape, pressure type and solid fraction are very important parameters. The defects such as porosity, liquid segregation and unfitting phenomena occur during rheo-forging process. To prevent these defects, mechanical properties and microstructure analysis of samples versus the change of pressure are carried out and the problem and its solutions are proposed. Also, the mechanical properties versus various pressures were compared with and without heat treatment. The alloys used for rheo-forming are A356 and 2024 aluminum alloy. The rheology material is fabricated by electromagnetic process with controlling current and stirring time.

• Journal of Korea Foundry Society
• /
• v.37 no.5
• /
• pp.157-163
• /
• 2017

In the present study, the microstructural evolution and deformation behavior of AA 2014 aluminum alloys with different microstructures in a semi-solid state were investigated. For a given alloy, applied load and deformation time, the measured strain was higher at a higher temperature, indicative of a lower solid fraction. When a large proportion of the liquid was present as intragranular droplets, the alloy would not as easily deform because the effective liquid fraction between the solid grains had decreased. Greater deformation was achieved with higher grain boundary misorientations due to the enhanced wetting of the grain boundaries with liquid. A semi-empirical constitutive model is proposed for semi-solid deformation under the conditions in the present study. The mechanism of semi-solid deformation incorporates the initial flow of the liquid in the early stages of deformation, followed by a more gradual increase in the strain due to deformation by grain sliding accompanied by self-diffusion in the solid grains.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2000.04a
• /
• pp.26-26
• /
• 2000

• International Journal of Korean Welding Society
• /
• v.2 no.2
• /
• pp.42-46
• /
• 2002

The solidification cracking susceptibilities of Al-Mg-Si alloy laser welds were assessed using the self-restraint tapered specimen crack test. The cracking susceptibility of 6061 and 6082 Al-Mg-Si alloy laser welds was substantially reduced when the filler wire containing high Si such as Al-12 wt.% Si (4047A) was used. The amount of eutectic was observed to affect the solidification cracking of Al-Mg-Si alloy laser welds. Abundant eutectic seems to heal the cracking and reduces the cracking susceptibility, while an initial increase in eutectic liquid leads to the increased cracking tendency.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2003.10a
• /
• pp.93-96
• /
• 2003

Recently, various bulk metallic glasses (BMG's) haying good mechanical and chemical properties were developed. BMG's can easily be deformed in the supercooled liquid region, via viscous flow mechanism. In our previous work, we evaluated the deformation behavior and some other basic properties of Z $r_{41.2}$ $Ti_{13.8}$C $u_{12.5}$N $i_{10}$B $e_{22.5}$ alloy. In this study, we investigated the micro forming of Z $r_{41.2}$ $Ti_{13.8}$C $u_{12.5}$N $i_{10}$B $e_{22.5}$ alloy. The process condition was chosen based on the viscosity data from TMA, and superalloy and Si wafer with micro patterns on the surface were used as forming die. The alloy showed good replication of the patterns. However, some stripe patterns, resembling scratches, appeared on the deformed alloy surface. These scratches can be reduced or eliminated by polishing before forming.ing.ore forming.ing.

• Journal of Powder Materials
• /
• v.27 no.1
• /
• pp.8-13
• /
• 2020

In this study, we investigated the effects of precipitates and oxide dispersoids on the high-temperature mechanical properties of oxide dispersion-strengthened (ODS) Ni-based super alloys. Two ODS Ni-based super alloy rods with different chemical compositions were fabricated by high-energy milling and hot extrusion process at 1150 ℃ to investigate the effects of precipitates on high-temperature mechanical properties. Further, the MA6000N alloy is an improvement over the commercial MA6000 alloy, and the KS6000 alloy has the same chemical composition as the MA6000 alloy. The phase and microstructure of Ni-based super alloys were investigated by X-ray diffraction and scanning electron microscopy. It was found that MC carbide precipitates and oxide dispersoids in the ODS Ni-based super alloys developed in this study may effectively improve high-temperature hardness and creep resistance.

• Corrosion Science and Technology
• /
• v.6 no.6
• /
• pp.304-307
• /
• 2007

As to the reflection electrode of LCD (liquid crystal displays), silver-copper-gold alloy (hereafter, it is called as ACA (Ag98%, Cu1%, Au1%)) is an effective material of which weathering resistance can be improved more compared with pure silver. However, there is a problem that gold remains on the substrate as residues when ACA is etched in cerium ammonium nitrate solution or phosphoric acid. Gold can not be etched in these etchants as readily as the other two alloying elements. Gold residue has actually been removed physically by brushing etc. This procedure causes damage to the display elements. Another etchant of iodine/potassium iodide generally known as one of the gold etchants can not give precise etch pattern because of remarkable difference in etching rates among silver, copper and gold. The purpose of this research is to obtain a practical etchant for ACA alloy. The results are as follows. The cyanogen complex salt of gold generates when cyanide is used as the etchant, in which gold dissolves considerably. Oxygen reduction is important as the cathodic reaction in the dissolution of gold. A new etchant of sodium cyanide / potassium ferricyanide whose cathodic reduction is stronger than oxygen, can give precise etch patterns in ACA alloy swiftly at room temperature.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.24 no.3
• /
• pp.426-434
• /
• 2000

This paper deals with a generalized similarity solution for the one-dimensional solidification of ternary or higher-order multicomponent alloys. The present approach not only retains the existing features of binary systems such as temperature- solute coupling, shrinkage-induced flow, solid-liquid property differences, and finite back diffusion, but also is capable of handling a multicomponent alloy without restrictions on the partition coefficient and microsegregation parameter. For an alloy of N-solute species, governing equations in the mushy region reduce to (N+2) nonlinear ordinary differential equations via similarity transformation, which are to be solved along with the closed-form solutions for the solid and liquid regions. A linearized correction scheme adopted in the solution procedure facilitates to determine the solidus and liquidus positions stably. The result for a sample ternary alloy agrees excellently with the numerical prediction as well as the reported similarity solution. Additional calculations are also presented to show the utility of this study. Finally, it is concluded that the present analysis includes the previous analytical approaches as subsets.

• Journal of Powder Materials
• /
• v.12 no.2 s.49
• /
• pp.131-135
• /
• 2005

7xxx series Al alloy has the most attractive properties including its excellent high specific strength, stress corrosion cracking and corrosion-resistance. However, in case of the Al-Zn system, the liquid phase has a transient aspect because of the high solid solubility of Zn in Al. Therefore, transient liquid phase sintering behavior was observed during the sintering process. And the amount of liquid and its duration were influenced by the process variables including heating rate and final sintering temperature. At high heating rates($100^{\circ}C/min$), the liquid fraction increased during sintering because diffusion was minimized and therefore local saturation could easily occur. The sintered density increased with increasing heating rate.