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Estimation of CO2 Net Atmospheric Flux in the Middle and Lower Nakdong River, and Influence Factors Analysis (낙동강 중하류에서 이산화탄소 순배출 플럭스 산정 및 영향인자 분석)

  • Lee, Eunju;Chung, Sewoong;Park, Hyungseok;Kim, Sungjin;Park, Daeyeon
    • Journal of Korean Society on Water Environment
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    • v.35 no.4
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    • pp.316-331
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    • 2019
  • Carbon dioxide($CO_2$) emission from rivers to the atmosphere is a key component in the global carbon cycle. Most of the rivers are supersaturated with $CO_2$. At a global scale, the amount of $CO_2$ emission from rivers is reported to be five-fold greater than that from lakes and reservoirs, but relevant data are rare in Korea. The objectives of this study is to estimate the $CO_2$ net atmospheric flux(NAF) from the upstream of Gangjeong-Goryeong Weir(GGW), Dalseong Weir(DSW), Hapcheon-Changnyeong Weir(HCW), and Changnyeong-Haman Weir(CHW) located in Nakdong River South Korea) using field and laboratory experiments and to apply data mining techniques to develop parsimonious prediction models that can be used to estimate $CO_2$ NAF with physical and water quality variables that can be collected easily. As a result, the study sites were all heterotrophic systems that often released $CO_2$ to the atmosphere, except when the algal photosynthesis was active.The median $CO_2$ NAF was minimum $391.5mg-CO_2/m^2$ day at GGW and maximum $1472.7mg-CO_2/m^2$ day at DSW. The $CO_2$ NAF showed a negative correlation with pH and Chl-a since the overgrowth of the algae consumed $CO_2$ in the water and increased the pH. As the parsimonious multiple regression model and random forest model developed, this study showed an excellent performance with the $Adj.R^2$ value higher than 0.77 in all weirs. Thus, these methods can be used to estimate $CO_2$ NAF in the river even if there is no $pCO_2$ measurement data.

Reinforced Anion-exchange Membranes Employing Porous PTFE Support for All-vanadium Redox Flow Battery Application (전 바나듐 레독스 흐름전지 응용을 위한 다공성 PTFE 지지체를 사용한 강화 음이온교환막)

  • Moon, Ha-Nuel;Song, Hyeon-Bee;Kang, Moon-Sung
    • Membrane Journal
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    • v.31 no.5
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    • pp.351-362
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    • 2021
  • All-vanadium redox flow battery (VRFB) is one of the promising high-capacity energy storage technologies. The ion-exchange membrane (IEM) is a key component influencing the charge-discharge performance and durability of VRFB. In this study, a pore-filled anion-exchange membrane (PFAEM) was fabricated by filling the pores of porous polytetrafluoroethylene (PTFE) support with excellent physical and chemical stability to compensate for the shortcomings of the existing hydrocarbon-based IEMs. The use of a thin porous PTFE support significantly lowered the electrical resistance, and the use of the PTFE support and the introduction of a fluorine moiety into the filling ionomer significantly improved the oxidation stability of the membrane. As a result of the evaluation of the charge-discharge performance, the higher the current efficiency was seen by increasing the fluorine content in the PFAEM, and the superior voltage and energy efficiencies were shown owing to the lower electrical resistance compared to the commercial membrane. In addition, it was confirmed that the use of a hydrophobic PTFE support is more preferable in terms of oxidation stability and charge-discharge performance.

Evaluation of a Thermal Conductivity Prediction Model for Compacted Clay Based on a Machine Learning Method (기계학습법을 통한 압축 벤토나이트의 열전도도 추정 모델 평가)

  • Yoon, Seok;Bang, Hyun-Tae;Kim, Geon-Young;Jeon, Haemin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.2
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    • pp.123-131
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    • 2021
  • The buffer is a key component of an engineered barrier system that safeguards the disposal of high-level radioactive waste. Buffers are located between disposal canisters and host rock, and they can restrain the release of radionuclides and protect canisters from the inflow of ground water. Since considerable heat is released from a disposal canister to the surrounding buffer, the thermal conductivity of the buffer is a very important parameter in the entire disposal safety. For this reason, a lot of research has been conducted on thermal conductivity prediction models that consider various factors. In this study, the thermal conductivity of a buffer is estimated using the machine learning methods of: linear regression, decision tree, support vector machine (SVM), ensemble, Gaussian process regression (GPR), neural network, deep belief network, and genetic programming. In the results, the machine learning methods such as ensemble, genetic programming, SVM with cubic parameter, and GPR showed better performance compared with the regression model, with the ensemble with XGBoost and Gaussian process regression models showing best performance.

Estimation and Analysis of the Vertical Profile Parameters Using HeMOSU-1 Wind Data (HeMOSU-1 풍속자료를 이용한 연직 분포함수의 매개변수 추정 및 분석)

  • Ko, Dong-Hui;Cho, Hong-Yeon;Lee, Uk-Jae
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.33 no.3
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    • pp.122-130
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    • 2021
  • A wind-speed estimation at the arbitrary elevations is key component for the design of the offshore wind energy structures and the computation of the wind-wave generation. However, the wind-speed estimation of the target elevation has been carried out by using the typical functions and their typical parameters, e.g., power and logarithmic functions because the available wind speed data is limited to the specific elevation, such as 2~3m, 10 m, and so on. In this study, the parameters of the vertical profile functions are estimated with optimal and analyzed the parameter ranges using the HeMOSU-1 platform wind data monitored at the eight different locations. The results show that the mean value of the exponent of the power function is 0.1, which is significantly lower than the typically recommended value, 0.14. The values of the exponent, the friction velocity, and the roughness parameters are in the ranges 0.0~0.3, 0~10 (m/s), and 0.0~1.0 (m), respectively. The parameter ranges differ from the typical ranges because the atmospheric stability condition is assumed as the neutral condition. To improve the estimation accuracy, the atmospheric condition should be considered, and a more general (non-linear) vertical profile functions should be introduced to fit the diverse profile patterns and parameters.

A Study on the Improvement of Welding Method for Ice Evaporator (얼음증발기 용접방법 개선에 관한 연구)

  • Lee, Jeong-Youn;Yoo, Heung-Ryol;Son, Yung-Deug
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.2
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    • pp.558-564
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    • 2021
  • The water purifier market has increased rapidly in recent years. The welding technology of the evaporator is a key component that determines the level of ice production and the cold water performance of an ice purifier. The finger type evaporator of an ice purifier can remove ice and is divided largely into an instant heat method and a hot gas method. In the hot gas type evaporator, particularly during the production process, the pinhole phenomenon inside the copper pipe and clogging problems occur intermittently when welding high-pressure pipes due to the high-temperature oxygen welding. Its use in a water purifier can cause a problem in that ice and cold water do not form, and repairs cannot be made on site. To solve this problem, in this study, a cap jig was applied to improve the welding defect of the hot gas evaporator. In addition, the oxygen welding flame size was adjusted so that the heat source could be well supplied to the cap jig, and the effectiveness was confirmed through a wave pressure test, a test, and a thermal shock test.

Research of Cross-linked Hydrocarbon based Polymer Electrolyte Membranes for Polymer Electrolyte Membrane Fuel Cell Applications (고분자 전해질 막 연료전지 응용을 위한 탄화수소계 기반 가교 전해질 막의 연구동향)

  • Ko, Hansol;Kim, Mijeong;Nam, Sang Yong;Kim, Kihyun
    • Membrane Journal
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    • v.30 no.6
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    • pp.395-408
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    • 2020
  • Polymer electrolyte membrane fuel cells (PEMFCs) have gained much attention as eco-friendly energy conversion devices without emission of environmental pollutant. Polymer electrolyte membrane (PEM) that can transfer proton from anode to cathode and also prevent fuel cross-over has been regarded as a key component of PEMFCs. Although perfluorinated polymer membranes such as Nafion® were already commercialized in PEMFCs, their high cost and toxic byproduct generated by degradation have still limited the wide spread of PEMFCs. To overcome these issues, development of hydrocarbon based PEMs have been studied. Incorporation of cross-linked structure into the hydrocarbon based PEM system has been reported to fabricate the PEMs showing both high proton conductivity and outstanding physicochemical stability. This study focused on the various cross-linking strategies to the preparation of cross-linked PEMs based on hydrocarbon polymers with ion conducting groups for application in PEMFCs.

Numerical Investigation of Aerodynamic Characteristics of a Ducted Fan-Vane Configuration and Improvement of Control Performance in Hover (덕트 팬-베인 형상의 제자리 비행 공력 특성 및 조종 성능 개선에 관한 수치적 연구)

  • Kang, Dong Hun;Yim, Jinwoo;You, Heung-Cheol
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.49 no.3
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    • pp.221-231
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    • 2021
  • In the present study, numerical simulation was performed to investigate aerodynamic characteristics of a ducted fan-upper/lower vanes system in hover. Sensitivity analysis of aerodynamic forces for a system component was conducted with the deflection angle of upper vanes varying but at the constant rotational speed and the collective pitch angle of fan blades. Then, vane control performance and duct airload distributions were analyzed in detail to physically understand operating mechanisms of individual vane and interference effect between duct and vanes. Finally, new control concept of operating upper vanes has been proposed to improve the control performance of the full configuration. It is found that the side force and rolling moment of upper vanes increase linearly with the variation of those deflection angle; however, the total side force is significantly small due to the reaction force acted on the duct. It is also found that upper vanes close to the duct contraction side have a key role in changing vane control forces. It is revealed that the duct suction pressure is induced by the interaction with the suction side of upper vanes, while duct pressure recovery by the interaction with the pressure side, leading to increase in duct asymmetric force. When four upper vanes are kept in situ at 0° deflection angle or removed, the total control performance was improved with duct asymmetric force reduced and the total magnitude of roll remarkably increasing up to 80%.

Source Identification and Trends in Atmospheric Particulate-bound Mercury at Seoul and Baengnyeong, South Korea (서울과 백령도의 대기 중 입자상 수은의 분포 특성 및 발생원 추정연구)

  • Noh, Seam;Park, Kwang-Su;Kim, Hyuk;Yu, Seok-Min;Lim, Yong-Jae;Lee, Min-Do;Seok, Kwang-Seol;Kim, Younghee
    • Journal of Environmental Analysis, Health and Toxicology
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    • v.21 no.4
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    • pp.220-228
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    • 2018
  • $PM_{2.5}$-bound mercury (PBM) was monitored at weekly intervals for three years (from 2014 to 2016) at an urban (Seoul) and rural site (Baengnyeong) in South Korea. The average PBM concentrations in $PM_{2.5}$ samples over the entire sampling period were $12{\pm}11pg/m^3$ and $36{\pm}34pg/m^3$ for Baengnyeong and Seoul, respectively. Seasonal differences were pronounced, with concentrations being highest in winter due to local meteorological conditions (high gas-particle coefficient due to low temperature and low mixing layer height in winter) as well as seasonal factors, such as coal combustion for heating purposes in China. In Baengnyeong, the significant positive correlation of PBM with $PM_{2.5}$, air pollutants, and heavy metals suggested that coal combustion in China might be the most important source of ambient mercury in Korea. In winter, no correlation of PBM with $PM_{2.5}$, air pollutants, and heavy metals was seen in Seoul. Furthermore, Seoul showed higher $PBM/PM_{2.5}$ and $Pb/PM_{2.5}$ ratios in winter due to the strong atmospheric oxidation-reduction reaction conditions as well as local and regional PBM sources. We conclude that immediate attention must be given to addressing PBM levels in Korea, including considering it as a key component of future air quality monitoring activities and mitigation measures.

A Study on the Risk Analysis and Fail-safe Verification of Autonomous Vehicles Using V2X Based on Intersection Scenarios (교차로 시나리오 기반 V2X를 활용한 자율주행차량의 위험성 분석 및 고장안전성 검증 연구)

  • Baek, Yunseok;Shin, Seong-Geun;Park, Jong-ki;Lee, Hyuck-Kee;Eom, Sung-wook;Cho, Seong-woo;Shin, Jae-kon
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.20 no.6
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    • pp.299-312
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    • 2021
  • Autonomous vehicles using V2X can drive safely information on areas outside the sensor coverage of autonomous vehicles conventional autonomous vehicles. As V2X technology has emerged as a key component of autonomous vehicles, research on V2X security is actively underway research on risk analysis due to failure of V2X communication is insufficient. In this paper, the service scenario and function of autonomous driving system V2X were derived by presenting the intersection scenario of the autonomous vehicle, the malfunction was defined by analyzing the hazard of V2X. he ISO26262 Part3 process was used to analyze the risk of malfunction of autonomous vehicle V2X. In addition, a fault injection scenario was presented to verify the fail-safe of the simulation-based intersection scenario.

Ginsenoside Ro, an oleanolic saponin of Panax ginseng, exerts anti-inflammatory effect by direct inhibiting toll like receptor 4 signaling pathway

  • Xu, Hong-Lin;Chen, Guang-Hong;Wu, Yu-Ting;Xie, Ling-Peng;Tan, Zhang-Bin;Liu, Bin;Fan, Hui-Jie;Chen, Hong-Mei;Huang, Gui-Qiong;Liu, Min;Zhou, Ying-Chun
    • Journal of Ginseng Research
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    • v.46 no.1
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    • pp.156-166
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    • 2022
  • Background: Panax ginseng Meyer (P. ginseng), a herb distributed in Korea, China and Japan, exerts benefits on diverse inflammatory conditions. However, the underlying mechanism and active ingredients remains largely unclear. Herein, we aimed to explore the active ingredients of P. ginseng against inflammation and elucidate underlying mechanisms. Methods: Inflammation model was constructed by lipopolysaccharide (LPS) in C57BL/6 mice and RAW264.7 macrophages. Molecular docking, molecular dynamics, surface plasmon resonance imaging (SPRi) and immunofluorescence were utilized to predict active component. Results: P. ginseng significantly inhibited LPS-induced lung injury and the expression of proinflammatory factors, including TNF-α, IL-6 and IL-1β. Additionally, P. ginseng blocked fluorescencelabeled LPS (LPS488) binding to the membranes of RAW264.7 macrophages, the phosphorylation of nuclear factor-κB (NF-κB) and mitogen-activated protein kinases (MAPKs). Furthermore, molecular docking demonstrated that ginsenoside Ro (GRo) docked into the LPS binding site of toll like receptor 4 (TLR4)/myeloid differentiation factor 2 (MD2) complex. Molecular dynamic simulations showed that the MD2-GRo binding conformation was stable. SPRi demonstrated an excellent interaction between TLR4/ MD2 complex and GRo (KD value of 1.16 × 10-9 M). GRo significantly inhibited LPS488 binding to cell membranes. Further studies showed that GRo markedly suppressed LPS-triggered lung injury, the transcription and secretion levels of TNF-α, IL-6 and IL-1β. Moreover, the phosphorylation of NF-κB and MAPKs as well as the p65 subunit nuclear translocation were inhibited by GRo dose-dependently. Conclusion: Our results suggest that GRo exerts anti-inflammation actions by direct inhibition of TLR4 signaling pathway.