• Title/Summary/Keyword: iodide

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Interaction of Water with Silver Iodide (AgI 결정면에 물의 흡착에 관한 이론적 고찰)

  • 백영현
    • Journal of the Korean institute of surface engineering
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    • v.7 no.1
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    • pp.5-12
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    • 1974
  • The interaction energy of water molecule over the surfaces of basal planes of silver iodide has been calculated , assuming 1-4-6--12 type potentials between the gas molecule and lattice ions in the silver iodide lattice. The heat of adsorption ranges from 12.25 to 12.75 kcal /mole at low coverage which is around the level of the latent heat of sublimaton of water.

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Synthesis and Quartemization of 6-(Substitutedamino)-Purines with Antitumor Activity Screening

  • El-Bayouki, Khairy-A.M.;Basyouni, Wahid-M.;El-Din, S.M.;Habeeb, A.G.
    • Archives of Pharmacal Research
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    • v.17 no.2
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    • pp.60-65
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    • 1994
  • Reaction of c-chloro-9-benzyl-8-(methylthio)purine 3 with primary amines afforoded, the comesponding 6-(substitutedamino)purines 4a-g. The latter products when methylated with methyl iodide yielded smoothly $N^3$-methyl purinium iodide salts 5a-f rather than the probable $N^1\;and\;N^7$-derivatives. 9-Benzyl-3-methyl-6-(methylmino)-8-(methylthio)purine 8 was obtained upon treating the purinium iodide 5a with alkali. Most of the synthesized compounds were screened for their antitumor activity.

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Microbiological Effects of Xanthorrhizol against Candida albicans (잔토리졸의 칸디다균 항균 효과)

  • Cho, Wan-Goo;Kim, Hyo-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.1
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    • pp.37-43
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    • 2010
  • The objective of this study was to evaluate the antifungal properties of xanthorrhizol (extract from curcuma xanthorrhiza) against Candida albicans. Some of the commercial products were evaluated for their ability to inhibit growth of C. albicans. OTC product containing povidone iodide and cosmetic grade product with surfactants were tested. Antifungal activity was shown in 1.56% of OTC product, however, there was no antifungal effect in cosmetic product. For the comparison, we tested several materials. Povidone iodide, lemon tea tree oil and xanthorrhizol showed antifungal activities against C albicans in 0.25, 0.062 and 0.007%, respectively. We also tested the antifungal effects of povidone iodide and xanthorrhizol in surfactant base. Test results revealed that 2.5% of povidone iodide and 0.156% of xanthorrhizol showed similar antifungal effects. These findings support the application of xanthorrhizol for vaginal cleanser or personal cares using antifungal effect.

Titanium Acetylacetonate as an Excellent Ion-Carrier in Construction of Iodide Sensor

  • Ganjali, Mohammad Reza;Daftari, Azadeh;Mizani, Farhang;Salavati-Niasari, Masoud
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.23-26
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    • 2003
  • Titanium acetylacetonate was used in the construction of a PVC-based membrane electrode. This sensor shows very good selectivity for iodide ion over a wide variety of common inorganic and organic anions. It exhibits Nernstian behavior with a slope of 59.1 mV per decade. The working concentration ranges of the sensor are with a detection limit of $3.0\;{\times}\;10^{-6}\;M$. The response time of the sensor is very fast (<8 s), and can be used for at least twelve weeks in the pH range of 4.0-9.2. The best performance was obtained with a membrane composition of 30% PVC, 65% dibutylphthalate, 3% titanium acetylacetonate and 2% hexadecyltrimethylammonium bromide. The proposed sensor was successfully applied as an indicator electrode for titration of iodide with silver ion.

The Multi-layer Fabrication and Characteristic Performance for Dark Current Reduction of Mercury Iodide (Hgl2의 누설전류 저감을 위한 다층구조 제작 및 특성 평가)

  • Kim, Kyung-Jin;Park, Ji-Koon;Kang, Sang-Sik;Cha, Byung-Youl;Cho, Sung-Ho;Kim, Jin-Yung;Mun, Chi-Ung;Nam, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.388-389
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    • 2005
  • In this paper, the electric properties of mercury Iodide multi-layer samples has been investigated. We measured and analyzed their performance parameters such as the X-ray sensitivity and dark-current for a mercury Iodide multi-layer X-ray detector with a dielectric layer. The digital X-ray image detector can be constructed by integrating photoconduction multi-layer that dielectric layer has characteristics of low dark-current, high X-ray sensitivity. However this process has found to have complexity on the performance of the sample. We have investigate dielectric layer that it substitute dielectric layer for HgO(Mercury Oxide). We have employed two approaches for producing the mercury Iodide sample : 1) Physical Vapor Deposition(PVD) and 2) Particle-In-Binder(PIB). In this paper fabricated by PIB Method with thicknesses ranging from approximately 180um to 240um and we could produce high-quality samples for each technique particular application. As results, the dielectric materials such as HgO between the dielectric layer and the top electrode may reduce the dark-current of the samples. Mercury Iodide multi-layer having HgO has characteristics of low dark-current, high X-ray sensitivity and simple processing. So we can acquired a enhanced signal to noise ratio. In this paper offer the method can reduce the dark-current in the X-ray detector.

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Removal Efficiency of Organic Iodide on Silver Ion-Exchanged Yeolite and TEDA-AC at High Temperature Process (고온공정에서 은교환 제올라이트 및 TEDA 첨착활성탄의 유기요오드 제거성능)

  • 최병선;박근일;김성훈;윤주현;배윤영;지성균;양호연;유승곤
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.65-72
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    • 2003
  • Adsorption and desorption characteristics of methyl iodide at high temperature conditions up to 25$0^{\circ}C$ by TEDA-impregnated activated carbon and silver-ion exchanged zeolite(AgX-10), which are used for radioiodine retention in nuclear facility, were experimentally evaluated. In the range of temperature from 3$0^{\circ}C$ to 25$0^{\circ}C$, the adsorption capacity of base activated carbon decreased sharply with increasing temperature but that of TEDA-impregnated activated carbon showed higher value even at high temperature ranges. Especially, the residual amount of methyl iodide after desorption on TEDA-AC represented 30% lower value than that on AgX-10. However, it can be used as an adsorbent for the removal of methyl iodide up to 15$0^{\circ}C$ if it is preventing explosion by Ignition. The breakthrough curves of methyl iodide in the fixed bed packed with AgX-10 uP to 40$0^{\circ}C$ were compared upon the effects of bed temperatures, bed depth and input concentration of methyl iodide. Removal mechanism of methyl iodide on AgX-10 was proposed, based on the analysis of by-product gas generated from adsorption reaction.

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