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Assessment of Practical Use of Recycling Oil from the Pyrolysis of Mixed Waste Plastics (혼합폐플라스틱의 열분해를 통한 회수오일의 이용가능성 평가)

  • Phae Chae-Gun;Kim Young-shin;Jo Chang-Ho
    • Journal of Energy Engineering
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    • v.14 no.2 s.42
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    • pp.159-166
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    • 2005
  • In Korea, although the generation of waste plastic has been increasing, the rate of recycling is considerably low and moreover, there is no suitable method for the treatment of waste plastics. However, pyrolysis, which is appropriate for the treatment of highly polymerized compounds, such as plastics, has recently gained much interest. In this study, a property of the products from the pyrolysis of mixed waste plastics, with a possible practical use for the recycling oil produced, were assessed. First of all, in order to investigate the pyrolysis characteristic of waste plastics, TGA (Thermogravimetric analysis) and DCS (Differential Scanning Calorimetry) were performed on a number of different plastics, including PP, LDPE, HDPE, PET and PS, as well as others. According to the result, it appeared that PP was the most efficiently pyrolyzed by changing the temperature, followed by LDPE, HDPE, PET, PS and the other plastics, in that order. From the results, the optimum conditions f3r pyrolysis were set up, and the different waste plastics pyrolyzed. The recycling oil produced from the flammable gases generated during the pyrolysis was com-pared with fuel oil by an analysis using the petroleum quality inspection method on KS(Korea industrial Standard). The results of the analysis showed the recycling oil was of a similar standard to fuel oil, with the exception of the ignition point, with a quality somewhere between that of paraffin oil and diesel fuel. With respect to these results, the quality of the recycling oil produced by the pyrolysis of waste plastics was suf-ficient for use as fuel oil.

Application of Gamma Irradiation on Manufacturing Changran Jeotgal (aged and seasoned intestine of Alaska pollack) : Microbiological and Sensory Characteristics (양념 창란젓갈 제조시 감마선 조사기술 적용: 미생물학적 및 관능적 품질특성)

  • Jo, Cheorun;Kim, Dong-Ho;Lee, Won-Dong;Lee, Jae-Jin;Byun, Myung-Woo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.5
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    • pp.673-678
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    • 2003
  • Changran Jeotgal (aged and seasoned intestine of Alaska pollack) was prepared as the same method as commercial one and irradiated at 0, 2.5, 5.0 and 10 k㏉ by gamma ray for industrial application. Changran Jeotgal using 10 k㏉-irradiated red pepper powder was also prepared to compare with control (0 k㏉). Commercial red pepper powder was already contaminated at 3.8$\times$10$^{6}$ CFU/$m\ell$ level by total plate count and 10k㏉ of irradiation reduced the number about 4 log cycles. Gamma irradiated Changran Jeotgal at 2.5,5.0, and 10k㏉ showed 3 6, and 7 log cycles of reduction compared to the non-irradiated control in the total plate count after 12 weeks of storage at 1$0^{\circ}C$. Using irradiated (10k㏉) red pepper powder reduced the microbial contamination significantly by 2 log cycles compared to the control. Sensory evaluation showed that the sample irradiated at 2.5 k㏉ was the most acceptable, followed by the sample using irradiated red pepper powder and non-irradiated control. Thus, 2.5 k㏉ of irradiation of Changran Jeotgal was effective to improve safety during distribution and storage without change of sensory quality. Furthermore, using the irradiated red pepper powder is also recommended for safety enhancement of the products.

Microstructure and EDM Processing of $MoSi_2$ Intermetallic Composite ($MoSi_2$ 금속간화합물 복합재료의 미세구조와 방전가공특성)

  • Yoon, Han-Ki;Lee, Sang-Pill;Yoon, Kyong-Wok;Kim, Dong-Hyun
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.05a
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    • pp.23-28
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    • 2002
  • This paper describes the machining characteristics of the $MoSi_2$ based composites by electric discharge drilling with various tubular electrodes, besides, Hardness characteristics and microstructures of $Nb/MoSi_2$ laminate composites were evaluated from the variation of fabricating conditions such as preparation temperature, applied pressure and pressure holding time. $MoSi_2$ -based composites has been developed in new materials for jet engine of supersonic-speed airplanes and gas turbine for high- temperature generator. Achieving this objective may require new hard materials with high strength and high temperature-resistance. However, With the exception of grinding, traditional machining methods are not applicable to these new materials. Electric discharge machining (EDM) is a thermal process that utilizes a spark discharge to melt a conductive material, the tool electrode being almost non-unloaded, because there is no direct contact between the tool electrode and the workpiece. By combining a nonconducting ceramics with more conducting ceramic it was possible to raise the electrical conductivity. From experimental results, it was found that the lamination from Nb sheet and $MoSi_2$ powder was an excellent strategy to improve hardness characteristics of monolithic $MoSi_2$. However, interfacial reaction products like (Nb, Mo)$SiO_2$ and $Nb_2Si_3$ formed at the interface of $Nb/MoSi_2$ and increased with fabricating temperature. $MoSi_2$ composites which a hole drilling was not possible by the conventional machining process, enhanced the capacity of ED-drilling by adding $NbSi_2$ relative to that of SiC or $ZrO_2$ reinforcements.

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Soil healthy assesment of organic wastes-treated lysimeter by Basidiomycota (담자균류를 이용한 폐기물연용 밭토양의 건전성 간이평가)

  • Jang, Kab-Yeul;Weon, Hang-Yeon;Choi, Sun-Gyu;Kweon, Soon-Ik;Kim, Gyu-Hyun;Kong, Won-Sik;Yoo, Young-Bok;Sung, Jae-Mo
    • Journal of Mushroom
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    • v.5 no.1
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    • pp.43-49
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    • 2007
  • Application of sludge wastes into the field may help soil fertility with physical, chemical and biological properties. Efficient use of sludge waste, however, requires an individual assessment of the waste products. A lot of experiment into the organic waste-treated soils has been done for decade. However, studies have not been carried out on the assessment of agricultural soil by Basidiomycota. This study was assessed the influence of sludge application on soil healthy in agricultural upland soils. The organic wastes selected for long-term application experiment in this study were municipal sewage sludge (MSS), industrial sewage sludge (ISS), leather processing sludge (LS), alcohol fermentation processing sludge (FS), and pig manure compost (PMC). To develop the soil healthy assesment method, soil samples were diluted by 20X with distilled water. After shaking at 200rpm for 30 minutes, the shaked sample was mixed on PDA(Potato Dextrose Agar). And sterilized at $121^{\circ}C$ for 20 minutes. Coriolus hirsutus (MKACC 50560) was inoculated on petri-dish including PDA mixed sample. After the media was incubated at $25^{\circ}C$ for five days, the mycelial growth of C. hirsutus was measured. When the mycelial growth on sample media was compared with growth on media contained PDA only, well grown media contained sample soil was assesed as healthy soil. The results suggest that the simple method by Coriolus hirsutus is a handy way to assess the healthy of waste sludge-applied upland soils.

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The Effects of Service Qualities on Customer Satisfaction, Trust, and Behavioral Intention in Smartphone Shopping Malls (스마트폰 쇼핑몰의 서비스품질이 고객만족, 신뢰, 행동의도에 미치는 영향)

  • Yang, Seung-Kwon;Shim, Jae-Hyun
    • The Journal of Industrial Distribution & Business
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    • v.9 no.12
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    • pp.31-43
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    • 2018
  • Purpose - Smartphone shopping malls provide customers with a variety of tangible and intangible services including web sites, web design, use convenience, information for products and shopping and various after services. Accordingly, it is needed to expand and classify service qualities based on the various services provided by smartphone shopping malls, and then analyze path structures of smartphone shopping malls' qualities → customer satisfaction → behavioral intention. The purpose of this study is to categorize the qualities of smartphone shopping mall users based on the e-SERVQUAL by Lee(2002) and the SERVQUAL by Parasuraman et al.(1988, 2005), the smartphone shopping malls' service qualities based on service quality of smartphone shopping malls used in the previous use studies, and the Website quality factors of service industry and to analyze path structure of smartphone shopping mall's qualities → customer satisfaction → behavioral intention on college students in order to confirm the system of smartphone shopping malls' qualities. Research design, data, and methodology - This study's survey was carried out on the college students of university located in northeastern of Seoul. It was from December 7 - 15, 2017, and a total of 240 questionnaires were distributed, with 228 collected. Of them, effective questionnaires used in the final study were a total of 201 except 27 that couldn't be used. In this study, empirical analysis was done with factor analysis, correlation analysis, multiple regression analysis, simple multiple regression analysis and moderating regression analysis by using Statistics Package SPSS18.0. Results - The study results are as follows: First, smartphone shopping malls' qualities were classified into six categories like customer system quality, Web design quality, convenience quality, information-offering quality, service quality, and product quality. Second, it showed that system quality, Web design quality, and information-offering quality had a positive impact on customer satisfaction, respectively. Third, it suggested that quality factors of smartphone shopping mall users had a positive impact on customer satisfaction in the order of quality, information-offering quality, system quality and Web design quality. Finally, it showed that customer service quality, product quality, and convenience quality did not have a positive impact on customer satisfaction. In addition, it said that customer satisfaction of smartphone shopping mall users had a positive impact on behavioral intention and thereby, the higher the customer satisfaction was, the higher the relations between reuse intention and recommendation intention were. Meanwhile, moderating regression analysis showed that trust did not have moderating effect in the relations between customer satisfaction and behavioral intention. The above study revealed that smartphone shopping malls' qualities were classified into six categories and it was possible to generalize after empirical analysis was made in the path structure. Conclusions - Smartphone shopping mall users consider usefulness of obtaining shopping information and quality on quick and abundant shopping information more important than access environment of smartphone shopping malls and kind services of smartphone shopping mall managers. Thereby, smartphone shopping mall marketers need to take service qualities like system quality and information-offering quality into more consideration.

Effect of Liner Component Coatings by Oxidized Starch on Properties of Corrugated Board (라이너지의 산화전분 코팅이 골판지의 물성에 미치는 영향)

  • Ahn, Byoung-Kuk;Ahn, Won-Yung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.4 no.2
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    • pp.3-11
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    • 1998
  • Coating was carried out on liner components of B flute, single-wall corrugated board(SK180/S120/K200) to examine the effect of liner component coatings by oxidized starch on the properties of corrugated board. Both bursting strength and edgewise compression strength(ECS) of corrugated board were improved by coating of its liner components with oxidized starch. Bursting strength of corrugated board rapidly increased with an initial increase of coating weight, but as the coating weight further increased, there was no increase in bursting strength. The results showed 30.3% improvement for $2.32g/m^2$ coating on outside liner component, 36.8% improvement for $4.84g/m^2$ coating on inside liner component and 39.9% improvement for $7.16g/m^2$ coating on both liner components in bursting strength of corrugated board. Regardless of treated liner components, ECS of corrugated board was improved by coating of oxidized starch, and especially greater improvement was accomplished when corrugated board was coated on inside liner component or both liner components at low level of coating weight - 11.3% improvement for $1.58g/m^2$ coating on Inside liner component and 11.9% improvement for $2.99g/m^2$ coating on both liner components.

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Study on Mechanical Properties of Geopolymer Concrete using Industrial By-Products (산업부산물을 사용한 지오폴리머 콘크리트의 역학적 특성에 관한 연구)

  • Kim, Si-Hwan;Koh, Kyung-Taek;Lee, Jang-Hwa;Ryu, Gum-Sung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.52-59
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    • 2014
  • This study examines the compressive strength, elastic modulus and splitting tensile strength of geopolymer concrete in order to evaluate its mechanical characteristics according to the admixing of fly ash and blast furnace slag. Moreover, identical tests are also conducted considering the amount of powder, the mixing ratio of alkali activator and the mixing ratio of silica fume for further comparative analysis considering various variables. The comparison with the formulae specified in Korean and overseas codes reveal that a mixing ratio of 18% is adequate for the alkali activator and that a replacement ratio of 5% by silica fume is recommended for silica fume. The elastic modulus of the geopolymer concrete appears to increase slightly with the increase of the compressive strength per variable and age and to be smaller than the values predicted by the formulae specified in Korean and overseas codes. In addition, the examination of the stress-strain curves shows that the geopolymer concrete exhibits ductile behavior compared to the conventional OPC. In view of the splitting tensile strength, high strength is observed for a powder content of $400kg/m^3$ and a replacement ratio of 18% by silica fume. The resulting ratio of the compressive strength to the splitting tensile strength is seen to range between 8.7 and 10.2%.

An Empirical Study on Clothing Distribution Center to Improve Storage Efficiency : Especially on Hanger Rack Storage According to Distance between Columns (의류 물류센터 보관효율 향상을 위한 실증적 연구 : 행거 랙 보관과 건물기둥 간격을 중심으로)

  • Nam, Hee Dae
    • Journal of the Korea Safety Management & Science
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    • v.21 no.4
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    • pp.75-80
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    • 2019
  • Sales of the Korean clothing industry grew to 16.9 percent on-year in 2010, but the growth rate dropped to 3 percent from 2011 to 2016 and the overall market began to slump to 1.1.6 percent in 2017. The competitiveness of clothing companies is also a major sector in logistics capability, and the average logistics cost of domestic clothing companies is 8.3 percent of sales in 2011, higher than the average 8 percent of domestic industries, and 36.4 percent of the total storage cost in 2011, higher than the 28.8 percent share of the total storage cost of domestic companies. As domestic production conditions such as wage hikes and labor disputes worsened in the 1990s, production facilities were rapidly moved overseas, which led many clothing companies to have no production facilities or a minimal production base in Korea and focus on marketing and design capabilities. The total storage capacity and storage efficiency of the logistics center became very important as the products were changed to the form of mass warehousing and small-volume forwarding. Research shows that building column spacing, a model of this research, can affect the amount of hanger rack storage empirically, so for sustainable growth of clothing companies, it is necessary to improve competitiveness in the logistics market by reducing costs and improving efficiency to overcome difficulties in corporate management. Because logistics costs are 8.3 percent and operating profit to sales ratio is 2 percent, it is expected that operating profit will increase by 41.5 percent if logistics costs are reduced by 10 percent. If 10% of storage cost is saved based on storage cost, operating profit is expected to increase by 15% To strengthen the competitiveness of the clothing industry, a reduction in logistics costs is essential. Therefore, the purpose of this study is to provide hints that logistics experts can have empirically small amounts in reducing storage costs through column spacing adjustment of logistics centers that have not been dealt with statistically until now, and to contribute to the continued growth of clothing companies and the development of the domestic logistics industry.

Oxidative Transformation of 1-Naphthol Using Manganese Oxide (망간산화물을 이용한 1-Naphthol의 산화 제거 연구)

  • Lim, Dong-Min;Kang, Ki-Hoon;Shin, Hyun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.535-542
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    • 2006
  • In this study, removals of 1-naphthol by oxidative-coupling reaction using birnessite, one of natural Mn oxides present in soil, was investigated in various experimental conditions(reaction time, Mn oxide loadings, pH, etc). Removal efficiency of 1-naphthol by birnessite was high in all the experimental conditions, and UV-vis. and mass spectrometric analyses on the supernatant after reaction confirmed that the reaction products were oligomers formed by oxidative-coupling reaction. Pseudo-first order rate constants, f, for the oxidative transformation of 1-naphthol by birnessite was derived from the kinetic experiments under various amount of birnessite loadings, and using the observed pseudo-first order rate constants with respect to birnessite loadings, surface area-normalized specific rate constant, $k_{surf}$ was also determined to be $9.31{\times}10^{-4}(L/m^2{\cdot}min)$ for 1-naphthol. In addition, the oxidative transformation of 1-naphthol was found to be dependent on solution pH, and the pseudo-first order rate constants were increased from 0.129 at pH 10 to 0.187 at pH 4.

Hydraulic Conductivity and Microscopic Analysis of Fly Ash Liner (플라이애쉬 혼합차수재의 투수특성과 미세구조 분석)

  • Jeong, Mun-Gyeong;Seo, Gyeong-Won;Lee, Yong-Su
    • Geotechnical Engineering
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    • v.14 no.1
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    • pp.109-126
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    • 1998
  • The use of fly ash as a contaminant barrier material was studied. Mixing ratio of fly ash to bentonite to meet the requirements for landfill liners was determined. The hydraulic behavior exhibited by the fly ash-bentonite liner and the effects of CaO were investigated through hydraulic conductivity tests under various conditions and microscopic analyses including XRD, SEM, helium porosimetry, and image analysis. The hydraulic conductivity of compacted fly ash decreased with the addition of bentonite, which was due mainly to the expanding of bentonite and partly to the filling of voids by chemical reaction products among constituents of the artificial liner. Because of insufficient CaO content, and rich in content but low-reactive $SiO_2$ contained in the fly ashes used, pozzolanic reaction and resulting effects in the artificial liner were not significant. The reactions among constituting materials and their resulting effects on hydraulic conductivity were controlled not by the apparent amounts of each constituent, but by reaction activities of the materials in the artificial liner.

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