• 제목/요약/키워드: impurity layer

검색결과 128건 처리시간 0.034초

PAALD 방법을 이용한 TaN 박막의 구리확산방지막 특성 (Characteristics of TaN Film as to Cu Barrier by PAALD Method)

  • 부성은;정우철;배남진;권용범;박세종;이정희
    • 반도체디스플레이기술학회지
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    • 제2권2호
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    • pp.5-8
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    • 2003
  • In this study, as Cu diffusion barrier, tantalum nitrides were successfully deposited on Si(100) substrate and $SiO_2$ by plasma assisted atomic layer deposition(PAALD) and thermal ALD, using pentakis (ethylmethlyamino) tantalum (PEMAT) and NH$_3$ as precursors. The TaN films were deposited at $250^{\circ}C$ by both method. The growth rates of TaN films were 0.8${\AA}$/cycle for PAALD and 0.75${\AA}$/cycle for thermal ALD. TaN films by PAALD showed good surface morphology and excellent step coverage for the trench with an aspect ratio of h/w -1.8:0.12 mm but TaN films by thermal ALD showed bad step coverage for the same trench. The density for PAALD TaN was 11g/cmand one for thermal ALD TaN was 8.3g/$cm^3$. TaN films had 3 atomic % carbon impurity and 4 atomic % oxygen impurity for PAALD and 12 atomic % carbon impurity and 9 atomic % oxygen impurity for thermal ALD. The barrier failure for Cu(200 nm)/TaN(10 nm)/$SiO_2$(85 nm)/ Si structure was shown at temperature above $700^{\circ}C$ by XRD, Cu etch pit analysis.

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수평 구조의 MOS-controlled Thyristor에서 채널에서의 길이 및 불순물 농도에 의한 스위칭 특성 (Switching Characteristics due to the Impurity Concentration and the Channel Length in Lateral MOS-controlled Thyristor)

  • 김남수;최지원;이기영;주병권;정태웅
    • 한국전기전자재료학회논문지
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    • 제18권1호
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    • pp.17-23
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    • 2005
  • The switching characteristics of MOS-Controlled Thyristor(MCT) is studied with variation of the channel length and impurity concentration in ON and OFF FET channel. The proposed MCT power device has the lateral structure and P-epitaxial layer in substrate. Two dimensional MEDICI simulator and PSPICE simulator are used to study the latch-up current and forward voltage-drop from the characteristics of I-V and the switching characteristics with variation of channel length and impurity concentration in P and N channel. The channel length and N impurity concentration of the proposed MCT power device show the strong affect on the transient characteristics of current and power. The N channel length affects only on the OFF characteristics of power and anode current, while the N doping concentration in P channel affects on the ON and OFF characteristics.

재생골재의 도로적용을 위한 이물질 정량화 연구 (An Impurity Quantitative Study for Pavement Application in Recycled Waste Aggregates)

  • 박준영;조윤호;임남웅
    • 한국도로학회논문집
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    • 제7권1호
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    • pp.21-29
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    • 2005
  • 건설폐기물의 재활용방법 중 하나는 폐콘크리트 재생골재를 도로포장재료로 활용하는 것이다. 하지만 재생골재에 대한 많은 연구와 기술개발에도 불구하고 생산공정에 포함된 이물질 때문에 실제 도로포장재료로의 적용은 미비한 실정이다. 본 연구에서는 재생골재내에 포함된 이물질의 특성에 따라 무기이물질과 유기이물질로 구분하였으며 , 각 이물질이 포장 공용성에 미치는 영향을 제시하였다. 또한 재생골재내에 포함된 무기이물질 함유량과 압축강도와의 관계, 유기이물질 함유량과 수정 CBR과의 상관관계를 통하여 도로포장층인 린콘크리트 기층과 보조기층에 적용 가능한 이물질 함량기준을 제시하였다. 린콘크리트 기층에는 무기이물질 함유량 질량비 10% 이하, 입상재료 보조기층에는 유기이물질 함유량 부피비 2% 이하일 때 재생골재를 포장에 적용 가능한 것으로 나타났다.

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Bi 박막의 성막 특성에 관한 연구 (Study on the deposition Characteristics of Bi Thin Film)

  • 이희갑;박용필;이준웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.1071-1074
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    • 2002
  • This paper presents Bi thin films have been fabricated by atomic layer-by-layer deposition and co-deposition at an IBS method. The growth rates of the films was set in the region from 0.17 to 0.27 nm/min. MgO(100) was used as a substrate. In order to appreciate stable existing region of Bi 2212 phase with temperature and ozone pressure, the substrate temperature was varied between 655 and $820^{\circ}C$ and the highly condensed ozone gas pressure$(PO_3)$ in vacuum chamber was varied between $2.0{\times}10^{-6}$ and $2.3{\times}10^{-5}Torr$. Bi 2212 phase appeared in the temperature range of 750 and $795^{\circ}C$: and single phase of Bi 2201 existed in the lower region than $785^{\circ}C$. Whereas, $PO_3$ dependance on structural formation was scarcely observed regardless of the pressure variation. And high quality of c-axis oriented Bi 2212 thin film with $T_c$(onset) of about 90 K and $T_c$(zero) of about 45 K is obtained. Only a small amount of CuO in some films was observed as impurity, and no impurity phase such as $CaCuO_2$ was observed in all of the obtained films.

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Salt and Sand Transport from Aral Sea Basin

  • 이귀주
    • 한국해양공학회지
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    • 제19권3호
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    • pp.47-53
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    • 2005
  • Model for dust and salt transportation from the dried bottom of the Aral Sea is suggested. Theoretical analysis is based on the turbulent diffusion equation for the averaged function of passive impurity concentration. One-layer model of the atmospheric boundary layer is assumed. Impurity precipitation rates are calculated as the functions of the particle size and the distance source of particles. Analytical solutions for the point and two-dimensional sources of impurities are found. Model calculations for salt and sand transport from the Aral Sea basin are made on the basis of 2D source model with a constant intensity.

The Outgasing characteristics of MgO film for protecting layer of plasma display panel

  • Song, Byoung-Kwan;Lee, Young-Joon;Lee, Chang-Heon;Hwang, Hyun-Ki;Yeom, Guen-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.621-624
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    • 2002
  • In this study, outgassing characteristics of MgO films, and the plasma cleaning effects of the deposited MgO films by atmospheric pressure plasma on outgassing rate were compared. The MgO layer was heated up to 350 $^{\circ}C$ and the outgassing characteristics were observed for the heated conditions. As the main impurity species $H_2,\;H_2O,\;N_2,\;CO_2,\;and\;H_2O$ were released from this panel. Impurity species of plasma treatment panel were lower than non-treated panels for the heating temperature

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플라즈마 식각에 의하여 실리콘 표면에 유기된 불순물 오염의 분석 및 제거 (Analysis and Reduction of Impurity Contamination Induced by Plasma Etching on Si Surface)

  • 조선희;이원종
    • 한국전기전자재료학회논문지
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    • 제19권12호
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    • pp.1078-1084
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    • 2006
  • Impurity contamination induced by $CF_4\;and\;HBr/Cl_2/O_2$ plasma etching on Si surface was examined by using surface spectroscopes. XPS(x-ray photoelectron spectroscopy) surface analysis showed that F of 0.4 at % exists in the surface layer in the form of Si-F bonding but Br and Cl are below the detection limit $(0.1{\sim}1.0%)$ of the spectroscope. Static-SIMS(secondary ion mass spectrometry) surface analysis showed that the etched Si surface was contaminated with etching gas elements such as H, F, Cl and Br, and they existed to the depth of about $20{\sim}40nm$. The etched Si surface was treated with three different methods that were HF dip, thermal oxidation followed by HF dip and oxygen-plasma oxidation followed by HF dip. They showed an effect in reducing the impurity contamination and the oxygen-plasma oxidation followed by HF dipping method appears to be a little bit more effective.

PAALD 방법을 이용한 TaN 박막의 구리확산방지막 특성

  • 부성은;정우철;배남진;권용범;박세종;이정희
    • 한국반도체및디스플레이장비학회:학술대회논문집
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    • 한국반도체및디스플레이장비학회 2002년도 추계학술대회 발표 논문집
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    • pp.14-19
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    • 2002
  • In this study, as Cu diffusion barrier, tantalum nitrides were successfully deposited on Si(100) substrate and SiO2 by plasma assisted atomic layer deposition(PAALD) and thermal ALD, using pentakis (ethylmethlyamino) tantalum (PEMAT) and $NH_3$ as precursors. The TaN films were deposited on $250^{\circ}$C by both method. The growth rates of TaN films were $0.8{\AA}$/cycle for PAALD and $0.75{\AA}$/cycle for thermal ALD. TaN films by PAALD showed good surface morphology and excellent step coverage for the trench with an aspect ratio of h/w - $1.8 : 0.12 \mu\textrm{m}$ but TaN films by thermal ALD showed bad step coverage for the same trench. The density for PAALD TaN was $11g/\textrm{cm}^3$ and one for thermal ALD TaN was $8.3g/\textrm{cm}^3$. TaN films had 3 atomic % carbon impurity and 4 atomic % oxygen impurity for PAALD and 12 atomic % carbon impurity and 9 atomic % oxygen impurity for thermal ALD. The barrier failure for Cu(200nm)/TaN(l0nm)/$SiO_2(85nm)$/Si structure was shown at temperature above $700^{\circ}$C by XRD, Cu etch pit analysis.

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공기극과 연료극의 복합 황불순물에 의한 고분자 전해질막 연료전지의 성능에 미치는 영향 (The performance of PEMFC during exposure to simultaneous sulfur impurity poisoning on cathode and anode)

  • 이수;진석환
    • 한국응용과학기술학회지
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    • 제29권4호
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    • pp.594-598
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    • 2012
  • 고분자 전해질막 연료전지는 연료극의 연료와 공기극의 공기에 각각 $H_2S$$SO_2$이 포함되어 있을 때 그 성능이 심각하게 감소한다. 본 연구는 고분자전해질막 연료전지의 공기극과 연료극에 1 ppm에서 10 ppm의 불순물 가스를 공급하여 전기적 성능측정을 통해 복합적인 황불순물이 단위전지에 미치는 영향을 확인하였다. 최적의 운전조건에서 불순물가스를 피독하였을 때 $SO_2$$H_2S$의 농도가 증가할수록 성능이 급격히 감소하였다(단위전지 온도 $65^{\circ}C$, 상대습도 100%). 그리고 황의 흡착은 MEA의 백금 촉매층 표면서 일어나며, 불순물 가스가 MEA에 누적되는 것을 확인하였다. 1, 3, 5, 및 10 ppm 4회의 연속적인 피독 후 연료전지의 성능이 0.71 V에서 0.54 V(76 %)로 감소하였다.

MQW electroabsorption modulator integrated with a tapered waveguide vertical interconnect

  • Han, Sang-Kook
    • Journal of the Optical Society of Korea
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    • 제1권1호
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    • pp.44-47
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    • 1997
  • The integration of a GaAs/AlGaAs multi-quantum well electroabsorption modulator and a tapered waveguide vertical direction optical interconnect has been performed without the complicated regrowth process. Zn impurity-induced layer disordering of MQW layer is used to achieve the energy transfer between SQW and MQW regions. Light coupled into a SQW region was transferred to an MQW region and an intensity modulation of 10 dB extinction ratio was demonstrated.