• Journal of the Mineralogical Society of Korea
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• v.27 no.4
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• pp.197-205
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• 2014

Study area (Jikjeon-ri) is located in south end of the Hadong anorthositic rocks. And along the south-western boundary, diorite intruded the Hadong anorthosite. Ilmenite ore bodies are extended in both anorthosite and diorite. And their occurrence in the diorite are not studied yet. While no particular textures are found in the ilmenite within the anorthosite, the ilmenite within the diorite shows characteristic exsolution texture, that is, ilmenite phases are separated into rutile and Fe-oxide and the ilmenite and Fe-oxide. MnO composition in ilmenite ratios are 2.14~3.74wt%, it has higher composition in diorite than that in anorthosite. The plagioclase composition display andesine ($An_{28.7-42.9}$) in the diorite and labradorite ($An_{57.1-72.8}$) in the anorthosite in composition. The exsolution of ilmenite has been developed during the cooling of partly melted ilmenite into rutile and Fe-oxides which is related to the intrusion of the diorite.

• Solar Energy
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• v.8 no.2
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• pp.39-45
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• 1988

Photo-decomposition experiments to produce hydrogen from organic compound such as alcohols and organic acids were investigated using the Korean natural ilmenite, which was used as ore itself as well as the calcined in vacuum. The decomposition activities of alcohol on ore (30-60 mesh) which was not calcined did not decrease even if it was repeatedly used. But crushed ore which had newly formed ilmenite surface revealed enhanced activities. The ilmenite powder calcined in vacuum showed 3-8 times higher activies than the ore powder itself and also the decomposition activity of formic acid was much higher than that of alcohols.

• Resources Recycling
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• v.13 no.5
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• pp.17-22
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• 2004

It has been carried our for establishing the methodology to upgrade $TiO_2$ by carbothermal reduction of iron oxide in ilmenite. Based on present experimental results, the possibility for substitution with rutile has been investigated. It could by proposed that the 2 wt.% $FeCl_3$ of sample and carbon of 2 equivalents are optimum conditions as a feeding materials. And also appropriate reducing temperature and reduction time were about $1100^{\circ}C$ and 30 minutes. The product obtained by the processes of carbon reduction and magnetic separation may be used the substitute mineral of rutile.

• Resources Recycling
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• v.27 no.3
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• pp.30-38
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• 2018

In this study, the behaviors of Fe selective chlorination in ilmenite ore by using PVC or $CO-Cl_2$ gas mixture as reducing agents under the condition of 1173 K, for 60 minutes were investigated. The weight loss ratio was 28% when PVC was applied as the reducing agent. The condensate formed at the outlet of reaction tube was identified as $FeCl_2$ by X-ray diffraction analysis. From these results, it was observed that iron in ilmenite ore reacted with HCl gas and Fe was selectively removed in the form $FeCl_2$. However, when $CO-Cl_2$ gas mixture was used as a reducing agent, the weight reduction ratio was 54%, and the condensate formed at the outlet of reaction tube after the experiment was estimated to be $FeCl_3$. It was observed that the ilmenite ore reacted with the $CO-Cl_2$ gas mixture and was simultaneously removed in the form of $FeCl_3$ and $TiCl_4$. However, the results of X-ray diffraction of ilmenite ore after the reaction showed that Fe was almost removed.

• Resources Recycling
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• v.28 no.5
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• pp.68-73
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• 2019

Ilmenite is one of the principal ores for the production of titanium dioxide. To produce titanium dioxide with purity higher than 99.9% from ilmenite, Ti(IV) should be separated from the dissolved impurities such as Fe(III), Si(IV), and Mn(II) present in ilmenite. In this work, a hydrometallurgical process was investigated to recover pure titanium dioxide from ilmenite by HCl leaching followed by separation and hydrolysis of Ti(IV). An optimum leaching condition was obtained by investigating the effect of HCl concentration, pulp density, and leaching time on the leaching percentage of Ti(IV), Fe(III), Si(IV), and Mn(II). Ammonium hydroxide and sodium hydroxide solutions were employed as neutralizing agents to hydrolyze Ti(IV) from the stripping solution of Ti(IV). Titanium dioxide of the anatase phase was obtained by calcination of the hydrolyzed precipitates with $NH_4OH$ solution. A hydrometallurgical process can be developed to produce pure $TiO_2$ powders from ilmenite.

• Journal of the Mineralogical Society of Korea
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• v.23 no.1
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• pp.25-37
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• 2010

Ilmenite ore bodies are deposited within the Precambrian anorthosite body distributed in the Hadonggun and Sancheonggun district, Gyeongsangnamdo. This study tries to identify the occurrence of ilmenite ore body in titanium mine area distributed in Wheolheongri, Okjongmyon, Hadonggun and six mining concession areas (Danseong claim no. 64, 65, 74, 75, 84, 85) in Danseongmyon, Sancheonggun. Wheolheongri ilmenite ore body occurs as vein with about 10~50 m width and 100 m length and shows NNE strike and NW dipping. High grade ore with $TiO_2$ 20 wt% in this area is distributed in intercumulated anorthosite and is sheared and brecciated. Ilmenite occurring in this type is commonly associated with hornbelnde. Ilmenite ore bodies distributed in Danseonggun, Sancheongmyon are deposited in layered anorthosite. They occur as stratiform with variable width from several and several tens meters. Ilmenite which is disseminated in the matrix is sheared and elongated. This type shows generally low grade ($TiO_2$ 1.0~6.0 wt%). The ilmenite ore bodies occur as vein and stratiform, and the former shows higher grade than the latter.

• Journal of the Mineralogical Society of Korea
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• v.15 no.3
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• pp.161-169
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• 2002

high pressure and temperature conditions. However, those results are not consistent with one another, and phase boundary between ilmenite and perovskite phases determined only from the quenching method may be not so reliable at all. Therefore, in-situ high pressure-temperature (hP-T) X-ray diffraction measurements were performed up to 19 GPa and $700^{\circ}C$ in a large volume press apparatus using synchrotron radiation. Experimental results show that perovskite phase is stable at pressures above 16 GPa, and transforms back to $LiNbO_3$phase near 15 CPa at room temperature, and that the perovskite-ilmenite transition is back and forth near 15 CPa at $500^{\circ}C$. LiNbO$_3$phase transforms to ilmenite at 13 CPa and $300^{\circ}C$ and at 10.8 CPa and $400^{\circ}C$, respectively. These data indicate that $LiNbO_3$phase may have a stability region in the hP-T phase diagram and that the perovskite-ilmenite phase boundary would be quite different from that previously reported.

• Journal of the Mineralogical Society of Korea
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• v.24 no.3
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• pp.195-204
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• 2011

Exsolution intergrowth of ilmenite and hematite was studied by the Rietveld refinement method. According to the analysis on these two structural analog minerals, it was found that octahedron (M2) of Ti in ilmenite is in the least deformation, then that (M1) of Fe in ilmenite is deformed next, and octaheron deformation of Fe in hematite is between M1 and M2. High pressure compression experiment was performed up to 5.8 GPa, where two minerals' XRD peaks merged completely. Ilmenite shows normal compression behavior, whereas hematite shrinks in very small amount. This kind of abnormal behavior might be due to the differential response to the applied pressure corresponding to the different compressibilities of the minerals each other.

• Journal of the Mineralogical Society of Korea
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• v.26 no.4
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• pp.285-297
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• 2013

Ilmenite deposits are developed along the Precambrian intercumulated anorthosite body in Jikjeon-Ri, Bukcheon-Myeon, Hadong, Korea. Both detailed geological survey and drilling prospecting data for seven boreholes can be used to do resource estimation with GOCAD S/W. 3D modeling using geostatistics is applied to predict the shape and size of Ti ore bodies. As a result, 5 Ti ore veins occurred along N-S direction and average grade of Ti and ilmenite resources are calculated as 2.98 wt% Ti and 7,494,303 metric tons ilmenite ore reserves (Ti 223,330 t). This 3D modeling will be applied to the whole ilmenite deposits in Hadong-Sancheong area to predict the exact distribution and resources estimations of Ti ores.

• Economic and Environmental Geology
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• v.11 no.3
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• pp.89-98
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• 1978

Mineralogy, beneficiation, and processes of titanium ores are reviewed from petrographic viewpoints. The most important titanium minerals are ilmenite ($FeTiO_3$) and rutile ($TiO_2$). Ilmenite will play major role :for raw material, because rutile are rapidly diminishing. Thus, there is a need to develope a successful process for producing high grade Ti02 from ilmenite. Commercial, as well as R and D processes to treat more abundant ilmenite ores fall in three general classess: 1. Iron in ilmenite is partially or completely reduced and separated either physically or chemically. 2. Iron is reduced to ferrous state and chemically leached away from the titanium. 3. Ore is treated to make chlorides either selectively or with subsequent separation and purification of $TiC_4$. Routes and efficiencies of these process technologies are primarily influenced by the particular ore deposit to be mined and secondly by environmental considerations. One deposit parameters which influence ilmenite process technologies are: 1. Complexity of microtextures of ilmenite intergrown with Fe-oxide minerals. 2. Composition of concentrates; ilmenites contain minor amounts of substituted Mg, Mn, and V. These elements plus iron and gangue minerals can cause difficulties to complete reactions, substantial acid consumption, difficulties of removing waste solids, and waste disposal problems. Major contributions to be made by petrologists for process optimization are: characterization and interpretation of compositional and physical changes of raw materials and solids derived from process streams. These informations can play significant role in selecting and improving process steps for titania production.