• Title/Summary/Keyword: high-temperature state

Search Result 1,592, Processing Time 0.024 seconds

Structural Stability of High-Temperature State of Bacteriorhodopsin: A Model of Multi-state Membrane Proteins

  • Mitaku, Shigeki;Yokoyama, Yasunori;Sonoyama, Masashi
    • Journal of Photoscience
    • /
    • v.9 no.2
    • /
    • pp.118-121
    • /
    • 2002
  • A state of bacteriorhodopsin at high temperature was studied by various spectral measurements. The stability measurements indicated that the onset temperature of the denaturation was 70$^{\circ}C$ in the dark and 60$^{\circ}C$ under illumination. The reactivity of hydroxylamine with the Schiff's base also significantly increased in the temperature range between 60 and 70$^{\circ}C$. A spectral band at about 470 nm appeared in the temperature range higher than 60$^{\circ}C$. The circular dichroism spectra in the visible region started to change from a bilobed exiton type to a positive band at about 60$^{\circ}C$, suggesting that the two-dimensional configuration of bacteriorhodopsin molecules changed from crystalline to amorphous. All the measurements suggested a new state between 60 and 70$^{\circ}C$ in which bacteriorhodopsin is stable only in the dark.

  • PDF

High Temperature Characteristics of SOI BMFET (SOI BMFET 의 고온 특성 분석)

  • Lim, Moo-Sup;Kim, Seoung-Dong;Han, Min-Koo;Choi, Yearn-Ik
    • Proceedings of the KIEE Conference
    • /
    • 1996.07c
    • /
    • pp.1579-1581
    • /
    • 1996
  • The high temperature characteristics of SOI BMFET are analyzed by the numerical simulation and compared with MOS-gated SOI power devices at high temperatures. The proposed SOI BMFET combines bipolar operation in the on-state with unipolar FET operation in the off-state, so that it may be suitable for high temperature operation without any significant degradation of performance such as the leakage current and blocking capability. The simulation results show that SOI BMFET with a higher doped n-resurf layer is the most promising device far high temperature application as compared with MOS-gated SOI power devices, exhibiting the low on-state voltage drop as well as the excellent forward blocking capability at high temperature.

  • PDF

Bending Creep and Creep Fracture of Sintered Alumina under High-Temperature (알루미나의 고온 굽힘크리프 및 크리프 파괴)

  • 김지환;권영삼;김기태
    • Journal of the Korean Ceramic Society
    • /
    • v.31 no.5
    • /
    • pp.543-551
    • /
    • 1994
  • The creep behavior and creep fracture of sintered alumina at high temperature were investigated under four point flexural test. Steady-state creep behavior was observed at low bending stress and primary creep until fracture was observed at hish bending stress. The loading history of bending stress did not affect on steady-state creep rate. Intergranular fracture was dominant for fracture of alumina at room and high temperature. However, transgranular fracture was dominant on creep of alumina under high temperature by nucleation and growth of microcracks due to residual flaws or cavities in the material.

  • PDF

A study on the diffusion bonding of the $Al_2$O$_3$ ceramics to metal (A$_2$O$_3$세라믹과 Ni-Cr-Mo鋼과의 인서트 合金을 이용한 擴散接合에 關한 硏究)

  • 김영식;박훈종;김정일
    • Journal of Welding and Joining
    • /
    • v.10 no.3
    • /
    • pp.63-72
    • /
    • 1992
  • The joining methods of ceramics to metals which can be expected to obtain high temperature strength are mainly classified into the solid-state diffusion bonding method and the active brazing method. Between these two, the solid-state diffusion bonding method is given attentions as substituting method for active brazing method due to being capable of obtaining higher bonding strength at high temperature and accurate bonding. In this paper, the solid-state diffusion bonding of $Al_{2}$O$_{3}$ ceramics to Ni-Cr-Mo alloy steel (SNCM21) using insert metal was carried out. The insert metal employed in this study was experimentally home-made, Ag-Cu-Ti alloy. Influence of several bonding parameters of $Al_{2}$O$_{3}$SNCM21 joint was quantitatively evaluated by bonding strength test, and microstructural analyses at the interlayer were performed by SEM/EDX. From above experiments, the optimum bonding condition of the solid-state diffusion bonding of $Al_{2}$O$_{3}$/SNCM21 using Ag-Cu-Ti insert metal was determined. Futhermore, high temperature strength and thermal-shock properties of $Al_{2}$O$_{3}$/SNCM21 joint were also examined. The results obtained are as follows. 1. The maximum bonding strength was obtained at the temperature of 95% melting point of insert metal. 2. The high temperature strength of $Al_{2}$O$_{3}$/SNCM21 joint appeared to bemaximum value at test temperature 500.deg.C and the bonding strength with increasingtemperature showed parabolic curve. 3. The strength of thermal-shocked specimens was far deteriorated than those of as-bonded specimens. Especially, water-quenched specimen after heated up to 600.deg. C was directly fractured in quenching.

  • PDF

Battery State Estimation Algorithm for High-Capacity Lithium Secondary Battery for EVs Considering Temperature Change Characteristics

  • Park, Jinho;Lee, Byoungkuk;Jung, Do-Yang;Kim, Dong-Hee
    • Journal of Electrical Engineering and Technology
    • /
    • v.13 no.5
    • /
    • pp.1927-1934
    • /
    • 2018
  • In this paper, we studied the state of charge (SOC) estimation algorithm of a high-capacity lithium secondary battery for electric vehicles (EVs) considering temperature characteristics. Nonlinear characteristics of high-capacity lithium secondary batteries are represented by differential equations in the mathematical form and expressed by the state space equation through battery modeling to extract the characteristic parameters of the lithium secondary battery. Charging and discharging equipment were used to perform characteristic tests for the extraction of parameters of lithium secondary batteries at various temperatures. An extended Kalman filter (EKF) algorithm, a state observer, was used to estimate the state of the battery. The battery capacity and internal resistance of the high-capacity lithium secondary battery were investigated through battery modeling. The proposed modeling was applied to the battery pack for EVs to estimate the state of the battery. We confirmed the feasibility of the proposed study by comparing the estimated SOC values and the SOC values from the experiment. The proposed method using the EKF is expected to be highly applicable in estimating the state of the high-capacity rechargeable lithium battery pack for electric vehicles.

Determination of Energy Distribution of Interface State Density in the MNOS Memory Device (MNOS 기억소자의 계면상태밀도의 에너지 분포의 결정)

  • 한태현;강창수;박종하;서광열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1988.10a
    • /
    • pp.1-4
    • /
    • 1988
  • The high frequency and quasi-state C-V curves were measured to determine the interface state density in MNOS devices. Berglund method was appropriate for determination of energy distribution of interface state density all over the energy gap. Applying Vg vs Øs relation by Berlund method to comparison-analysis method of the high-frequency and quasi-static C-V curves, we were able to determine the energy distribution by only measured C-V curves without theoretical C-V curves. The interface state density near the conduction band was high at lower temperature than room temperature.

  • PDF

Mechanical behavior of Beishan granite samples with different slenderness ratios at high temperature

  • Zhang, Qiang;Li, Yanjing;Min, Ming;Jiang, Binsong
    • Geomechanics and Engineering
    • /
    • v.24 no.2
    • /
    • pp.157-166
    • /
    • 2021
  • This paper aims at the temperature and slenderness ratio effects on physical and mechanical properties of Beishan granite. A series of uniaxial compression tests with various slenderness ratios and temperatures were carried out, and the acoustic emission signal was also collected. As the temperature increases, the fracture aperture of intercrystalline cracks gradually increases, and obvious transcrystalline cracks occurs when T > 600℃. The failure patterns change from tensile failure mode to ductile failure mode with the increasing temperature. The elastic modulus decreases with the temperature and increases with slenderness ratio, then tends to be a constant value when T = 1000℃. However, the peak strain has the opposite evolution as the elastic modulus under the effects of temperature and slenderness ratio. The uniaxial compression strength (UCS) changes a little for the low-temperature specimens of T < 400℃, but a significant decrease happens when T = 400℃ and 800℃ due to phase transitions of mineral. The evolution denotes that the critical brittle-ductile transition temperature increases with slenderness ratio, and the critical slenderness ratio corresponding to the characteristic mechanical behavior tends to be smaller with the increasing temperature. Additionally, the AE quantity also increases with temperature in an exponential function.

Reactive Synthesis of ZrB2-based Ultra High Temperature Ceramics

  • Liu, Hai-Tao;Zhang, Guo-Jun
    • Journal of the Korean Ceramic Society
    • /
    • v.49 no.4
    • /
    • pp.308-317
    • /
    • 2012
  • Reactive processing, such as reactive hot pressing (RHP) and reactive spark plasma sintering (R-SPS), is effective densification method to prepare $ZrB_2$-based ultra high temperature ceramics (UHTCs). The present paper reviewed some typical reactive processing of $ZrB_2$-based UHTCs. All the reactions from the starting materials in the reactive processing are thermodynamically favorable, which generate enough energy and driving force for the densification of the final products under a relatively low temperature. Besides, compared with non-reactive processing, anisotropic $ZrB_2$ grains, such as $ZrB_2$ platelets, can only be obtained in the reactive processing, resulting in an improvement of the mechanical properties.

CHARACTERISTICS OF WALL IMPINGEMENT AT ELEVATED TEMPERATURE CONDITIONS ON GDI SPRAY

  • Park, J.;Im, K.S.;Kim, H.;Lai, M.C.
    • International Journal of Automotive Technology
    • /
    • v.5 no.3
    • /
    • pp.155-164
    • /
    • 2004
  • The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and double-spark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray. Vapor phase appears at both ambient and elevated temperature conditions, particularly in the toroidal vortex and impingement plume. More rapid impingement and faster horizontal spread after impingement are observed for elevated temperature conditions. Droplet rebounding and film break-up are clearly observed. Post-impingement droplets are significantly smaller than pre-impingement droplets with a more horizontal velocity component regardless of the wall temperature and impingement angle condition.

Manufacturing and Temperature Measurements of a Sodium Heat Pipe

  • Lee, Byeong-In;Lee, Seong-Hong
    • Journal of Mechanical Science and Technology
    • /
    • v.15 no.11
    • /
    • pp.1533-1540
    • /
    • 2001
  • A high-temperature sodium stainless steel heat pipe was fabricated and its performance has been investigated. The working fluid was sodium and it was sealed inside a straight tube container made of stainless steel. The amount of sodium occupied approximately 20% of the total volume of the heat pipe and its weight was 65.7gram. The length of a stainless steel container is 1002mm and its outside diameter is 25.4mm. Performance tests were carried out in a room air condition under a free convective environment and the measured temperatures are presented. The start-up behavior of the heat pipe from a frozen state was investigated for various heat input values between 600W and 1205W. In steady state, axial temperature distributions of a heat pipe were measured and its heat transfer rates were estimated in the range of vapor temperature from 50$0^{\circ}C$ to 63$0^{\circ}C$. It is found that there are small temperature differences in the vapor core along the axial direction of a sodium heat pipe for the high operating temperatures. But for the range of low operating temperatures there are large temperature drops along the vapor core region of a sodium heat pipe, because a small vapor pressure drop makes a large temperature drop. The transition temperature was reached more rapidly in the cases of high heat input rate for the sodium heat pipe.

  • PDF