• Title/Summary/Keyword: high temperature high pressure

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Development of Thermoplastic Carbon Composite Bipolar Plates for High-temperature PEM Fuel Cells (고온 양성자 교환막 연료전지용 열가소성 탄소 복합재료 분리판 개발)

  • Lim, Jun Woo;Kim, Minkook;Lee, Dai Gil
    • Composites Research
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    • v.29 no.5
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    • pp.243-248
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    • 2016
  • Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

Safety Assessment of By-product Gas Piping after Design Change (부생가스 연료배관의 설계변경에 따른 안전성 평가)

  • Yoon, Kee Bong;Nguyen, Van Giang;Nguyen, Tuan Son;Jeong, Seong Yong;Lee, Joo Young;Kim, Ji Yoon
    • Journal of the Korean Institute of Gas
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    • v.17 no.2
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    • pp.50-58
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    • 2013
  • Various process piping usually carries out high flammable and explosible gas under high pressure and high temperature. Due to frequent change of design and structure it becomes more complicated and compactly located. The safety management level is relatively low since it is considered as simply designed component. In this study a safety assessment procedure is proposed for complicated piping system around a mixing drum in which natural gas and by-product gases were mixed. According to ASME code, pipe stress analysis was conducted for determining design margin at some key locations of the piping. These high stress locations can be used as major inspection points for managing the pipe integrity. Sensitivity analysis with outside temperature of the pipe and support constraint condition. Possible effect of hydroen gas to the pipe steel during the previous use of the by-product gas was also discussed.

Behaviors of Cavitation Damage in Seawater for HVOF Spray Coated Layer with WC-10Co4Cr on Cu Alloy (WC-10Co4Cr으로 초고속 화염용사 코팅된 Cu 합금의 해수내 캐비테이션 손상 거동)

  • Han, Min-Su;Kim, Min-Sung;Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of Surface Science and Engineering
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    • v.45 no.6
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    • pp.264-271
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    • 2012
  • Due to the good corrosion resistance and machinability, copper alloy is commonly employed for shipbuilding, hydroelectric power and tidal power industries. The Cu alloy, however, has poor durability, and the seawater application at fast flow condition becomes vulnerable to cavitation damage leading to economic loss and risking safety. The HVOF(High Velocity Oxygen Fuel) thermal spray coating with WC-10Co4Cr were therefore introduced as a replacement for chromium or ceramic to minimize the cavitation damage and secure durablility under high-velocity and high-pressure fluid flow. Cavitation test was conducted in seawater at $15^{\circ}C$ and $25^{\circ}C$ with an amplitude of $30{\mu}m$ on HVOF WC-10Co4Cr coatings produced by thermal spray. The cavitation at $15^{\circ}C$ and $25^{\circ}C$ exposed the substrate in 12.5 hours and in 10 hours, respectively. Starting from 5 hours of cavitation, the coating layer continued to show damage by higher than 160% over time when the temperature of seawater was elevated from $15^{\circ}C$ to $25^{\circ}C$. Under cavitation environment, although WC-10Co4Cr has good wear resistance and durability, increase in temperature may accelerate the damage rate of the coating layer mainly due to cavitation damage.

Evaluation of Cavitation Characteristics in Seawater on HVOF Spray Coated Layer with WC-27NiCr Material for Cu Alloy (구리합금에 대한 WC-27NiCr 초고속화염용사 코팅층의 해수내 캐비테이션 특성 평가)

  • Han, Min-Su;Kim, Min-Sung;Jang, Seok-Ki;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.263-269
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    • 2012
  • Copper alloys are commonly applied to ship's propellers, pumps and valves which are serviced in seawater due to their good castability and corrosion resistance. In the environment of high flow velocity, however, erosion damage predominates over corrosion damage. In particular, the cavitation in seawater environment accelerates surface damage to copper alloys, resulting in degradation of products and economic losses and also threatening safety. The surface was coated with WC-27NiCr by high velocity oxygen fuel(HVOF) spraying technique to attain durability and cavitation resistance of copper alloys under high velocity/pressure flow. The cavitation test was performed for the WC-27NiCr coating deposited by HVOF in seawater at the amplitude of $30{\mu}m$ with seawater temperature. The cavitation at $15^{\circ}C$ caused exfoliation of the coating layer in 17.5 hours while that of $25^{\circ}C$ caused the exfoliation in 12.5 hours. When the temperature of seawater was elevated to $25^{\circ}C$ from $15^{\circ}C$, more damage was induced by over 160%. Although WC-27NiCr has good durability, corrosion resistance and eletrochemical stability, the cavitation damage rate of the coating layer could remarkably increase at the elevated temperatures under cavitation environments.

Development of High Efficiency Cycle by Combining Double-Effect with Single-Effect Absorption Chiller Systems (이중 효용과 일중 효용을 복합한 다단 재생 고효율 흡수식 냉동 사이클 개발)

  • Yun, Sang Kook
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.7
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    • pp.360-365
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    • 2017
  • Recently, development efforts of triple-effect absorption chiller have been increased in order to improve the efficiency of double-effect absorption chiller. However, triple-effect absorption chiller has some disadvantages, including high corrosion characteristic of LiBr solution at high temperature of $200^{\circ}C$. Moreover, it is necessary to develop new components for operation under high pressure of 2 bars even though COP is increased to 1.6 or 1.7. The objective of this study was to introduce a new system by combining double effect absorption chiller with single effect absorption chiller with multi-generators using bypass flow of LiBr dilute solution to $3^{rd}$ generator to overcome the disadvantages of triple-effect chiller and improve energy efficiency. Results indicate that the new absorption cycle had a much higher efficiency than double-effect chiller system, showing significant improvement when bypass solution flow rate of 25% was applied to the $3^{rd}$ generator using the main dilute solution of the absorber. The COP of the new chiller system was found to be 1.438, which was 21.7% higher than that (1.18) of the present double-effect system. The COP was decreased when solution by-pass rate to the $3^{rd}$ generator was increased. In addition, lower cooling water temperature caused higher COP. Therefore, the multi-generator system with by-pass solution might be an excellent chiller alternative to triple-effect absorption chiller with higher efficiency.

A Study on Erosion Structure Properties for Thermal Insulation Materials on Carbon-Carbon Composites and Graphite Nozzle Throat (C-C 복합재료와 Graphite 노즐목 내열재의 침식조직 특성에 대한 연구)

  • Kim, Young In;Lee, Soo Yong
    • Journal of Aerospace System Engineering
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    • v.11 no.5
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    • pp.42-49
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    • 2017
  • The solid rocket motor(SRM) consists of a motor case, igniter, propellants, nozzle, insulation, controller, and driving device. The liquid rocket propulsion systems(LRPSs) cools the nozzle by the fuel and oxidizer but SRM does not cool the nozzle. The nozzle of SRM is high temperature condition and high velocity condition so occurs the erosion by combustion gas. This erosion occurs the change of nozzle throat and reduces thrust performance of rocket. The material of Rocket nozzle is minimization of erosion and insulation effect and endure the shear force, high temperature and high pressure. The purpose of this study is to investigate the erosion characteristics of solid rocket nozzles by each combustion time. Through the structure inspection of Graphite and C-C composite, identify the characteristics of the microstructure before and after erosion.

Characteristics of AlN Thin Films by Magnetron Sputtering System Using Reactive Gases of N2 and NH3 (N2와 NH3 반응성가스를 사용하여 마그네트론 스퍼터링법으로 제작한 AlN박막의 특성)

  • Han, Chang-Suk
    • Korean Journal of Materials Research
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    • v.25 no.3
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    • pp.138-143
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    • 2015
  • Aluminum nitride, a compound semiconductor, has a Wurtzite structure; good material properties such as high thermal conductivity, great electric conductivity, high dielectric breakdown strength, a wide energy band gap (6.2eV), a fast elastic wave speed; and excellent in thermal and chemical stability. Furthermore, the thermal expansion coefficient of the aluminum nitride is similar to those of Si and GaAs. Due to these characteristics, aluminum nitride can be applied to electric packaging components, dielectric materials, SAW (surface acoustic wave) devices, and photoelectric devices. In this study, we surveyed the crystallization and preferred orientation of AlN thin films with an X-ray diffractometer. To fabricate the AlN thin film, we used the magnetron sputtering method with $N_2$, NH3 and Ar. According to an increase in the partial pressures of $N_2$ and $NH_3$, Al was nitrified and deposited onto a substrate in a molecular form. When AlN was fabricated with $N_2$, it showed a c-axis orientation and tended toward a high orientation with an increase in the temperature. On the other hand, when AlN was fabricated with $NH_3$, it showed a-axis orientation. This result is coincident with the proposed mechanism. We fabricated AlN thin films with an a-axis orientation by controlling the sputtering electric power, $NH_3$ pressure, deposition speed, and substrate temperature. According to the proposed mechanism, we also fabricated AlN thin films which demonstrated high a-axis and c-axis orientations.

Measurement of outgassing rates of Kevlar and S-Glass materials used in torque tubes of High Tc Superconducting (HTS) Motors

  • Thadela, S.;Muralidhar, BVAS;Kalyani, B;Choudhury, UK;Yadav, SN;Rao, V.V.
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.4
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    • pp.11-15
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    • 2018
  • Torque tubes in High Temperature Superconducting (HTS) motor transfer torque from superconducting field winding rotor to the room temperature shaft. It should have minimum heat conduction property for minimizing the load on cryo-refrigerator. Generally, these torque tubes are made with stainless steel material because of high strength, very low outgassing and low thermal contraction properties at cryogenic temperatures and vacuum conditions. With recent developments in composite materials, these torque tubes could be made of composites such as Kevlar and S-Glass, which have the required properties like high strength and low thermal conductivity at cryogenic temperatures, but with a reduced weight. Development and testing of torque tubes made of these composites for HTS motor are taken up at Bharat Heavy Electricals Limited (BHEL), Hyderabad in collaboration with Central Institute of Plastics and Engineering Technology (CIPET), Chennai and Indian Institute of Technology (IIT), Kharagpur. As these materials are subjected to vacuum, it is important to measure their outgassing rates under vacuum conditions before manufacturing prototype torque tubes. The present study focusses on the outgassing characteristics of Kevlar and S-Glass, using an Outgassing Measurement System (OMS), developed at IIT Kharagpur. The OMS facility works under vacuum environment, in which the test samples are exposed to vacuum conditions over a sufficient period of time. The outgassing measurements for the composite samples were obtained using pressure-rise technique. These studies are useful to quantify the outgassing rate of composite materials under vacuum conditions and to suggest them for manufacturing composite torque tubes used in HTS motors.

A Facile Process for Surface Modification with Lithium Ion Conducting Material of Li2TiF6 for LiMn2O4 in Lithium Ion Batteries

  • Kim, Min-Kun;Kim, Jin;Yu, Seung-Ho;Mun, Junyoung;Sung, Yung-Eun
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.223-230
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    • 2019
  • A facile method for surface coating with $Li_2TiF_6$ which has a high lithium-ion conductivity, on $LiMn_2O_4$ spinel cathode material for high performance lithium ion batteries. The surface coating is performed by using a co-precipitation method with $Li_2CO_3$ powder and $H_2TiF_6$ solution under room temperature and atmospheric pressure without special equipment. Total coating amount of $Li_2TiF_6$ is carefully controlled from 0 to 10 wt.% based on the active material of $LiMn_2O_4$. They are evaluated by a systematic combination of analyses comprising with XRD, SEM, TEM and ICP. It is found that the surface modification of $Li_2TiF_6$ is very beneficial to high cycle life and excellent rate capability by reducing surface failure and supporting lithium ions transportation on the surface. The best coating condition is found to have a high cycle life of $103mAh\;g^{-1}$ at the 100th cycle and a rate capability of $102.9mAh\;g^{-1}$ under 20 C. The detail electrochemical behaviors are investigated by AC impedance and galvanostatic charge and discharge test.

A Study on Properties of SiC material Fabricated by Liquid Phase Sintering (액상소결법에 의해 제조된 탄화규소 재료의 특성에 대한 연구)

  • Sang-Pill Lee;Jae-Hwan Kwak;Jin-Kyung Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.6_2
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    • pp.1019-1024
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    • 2023
  • Ceramic materials have excellent material properties such as stability at high temperatures, chemical stability, corrosion resistance, and wear resistance, so they are applicable even in extreme environments of high temperature and pressure. In particular, silicon carbide can be applied in the field of structural ceramics due to its characteristics of high strength, hardness, corrosion resistance, and heat resistance even at high temperatures. In this study, considering the application of silicon carbide materials to next-generation turbines, silicon carbide materials were manufactured using a liquid phase sintering method. When manufacturing liquid phase sintered silicon carbide, sintering additives were added to lower the sintering temperature and densify the material. In Al2O3-SiO2, it was confirmed that the secondary product of the sintering additive was observed as a slightly dark area and was evenly distributed overall, and the fracture surface of Al2O3-SiO2 was in the form of transgranular fracture in which cracks progressed along the crystal plane, and the flexural strength for Al2O3-SiO2 was about 445.6 MPa.