• Title/Summary/Keyword: high resolution spectra

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A Prediction of Infrared Spectrum of Rocket Plume with Considering Soot Particles (Soot 입자를 고려한 로켓 플룸의 적외선 스펙트럼 예측)

  • Jo, Sung Min;Nam, Hyun Jae;Kim, Duk Hyun;Kwon, Oh Joon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.4
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    • pp.24-36
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    • 2015
  • In the present study, numerical predictions of infrared spectrum of rocket plume with considering effect of particles based on approximation theories were performed by using a line-by-line radiation model with radiation databases. The high-resolution radiation databases were used to predict thermal emission spectra of gas molecules within the rocket plume regime. The particles were modeled as soot particles by using 1st term approximation of Mie theory and Rayleigh approximation. The reliability of modeled effect of soot particles using the two approximation theories was verified, and the spectral radiance of rocket plume was predicted based on the verification. The results were improved in the short wavelength range by considering the effect of soot particles.

The Preliminary Study on the Structure of Cop Protein by CD and NMR

  • Kim, Yun-Kyong;Park, Sang-Ho;Lee, Jee-Hyun;Kwak, Jin-Hwan;Lee, Bong-Jin
    • Journal of the Korean Magnetic Resonance Society
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    • v.3 no.2
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    • pp.100-108
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    • 1999
  • Cop protein is the transcription repressor protein in rolling circle replication plasmid. With antisense RNA, Cop protein controls the copy number of plasmid. Cop family proteins have been found in various plasmids. Among Cop family proteins, Cop studied in this paper consists of 55 amino acids (Mw. 6,400), and was known to have trimer structure. Since no structural facts are elucidated, we have carried out preliminary experiments aimed at the elucidation of its three dimensional structure. The secondary structure of Cop is studied by CD and NMR. To solve the aggregation of Cop at high concentration, we tested various detergents and salts. The addition of detergents and salts could not solve the aggregation problem. However, we found that concentration is important in solving the aggregation problem. We knew that 0.18mM in 50mM potassium phosphate without any other ingredients is maximum concentration not to aggregate. Wa also investigated the pH dependence of Cop protein, and knew that Cop protein is more stable in acid state. At various temperatures, 15N-1H HSQC spectra were measured in order to find the optimal experimental condition. To enhance the peak resolution, 3D NOESY-HSQC spectrum is acquired. Since there are NOE peaks in the NH-NH region, we knew that Cop protein has $\alpha$-helical content, which was also confirmed by CD.

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Mass Spectrometry Analysis of In Vitro Nitration of Carbonic Anhydrase II

  • Lee, Soo Jae;Kang, Jeong Won;Cho, Kyung Cho;Kabir, Mohammad Humayun;Kim, Byungjoo;Yim, Yong-Hyeon;Park, Hyoung Soon;Yi, Eugene C.;Kim, Kwang Pyo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.709-714
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    • 2014
  • Protein tyrosine nitration is considered as an important indicator of nitrosative stresses and as one of the main factors for pathogenesis of inflammation and neuronal degeneration. In this study, we investigated various nitrosative modifications of bovine carbonic anhydrase II (CAII) through qualitative and semi-quantitative analysis using the combined strategy of Fourier transformation ion cyclotron resonance mass spectrometry (FT-ICR MS) and ion-trap tandem mass spectrometry (IT-MS/MS). FT-ICR MS and its spectra were used for the search of the pattern of nitrosative modifications. Identification of nitrosatively modified tyrosine sites were executed through IT-MS/MS. In addition, we also tried to infer the reason for the site-specific nitrosative modifications in CAII. In view of the above purpose, we have explored- i) the side chain accessibility, ii) the electrostatic environment originated from the acidic/basic amino acid residues neighboring to the nitrosatively modified site and iii) the existence of competing amino acid residues for nitration.

[ Hα ] SPECTRAL PROPERTIES OF VELOCITY THREADS CONSTITUTING A QUIESCENT SOLAR FILAMENT

  • Chae, Jong-Chul;Park, Hyung-Min;Park, Young-Deuk
    • Journal of The Korean Astronomical Society
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    • v.40 no.3
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    • pp.67-82
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    • 2007
  • The basic building block of solar filaments/prominences is thin threads of cool plasma. We have studied the spectral properties of velocity threads, clusters of thinner density threads moving together, by analyzing a sequence of $H{\alpha}$ images of a quiescent filament. The images were taken at Big Bear Solar Observatory with the Lyot filter being successively tuned to wavelengths of -0.6, -0.3, 0.0, +0.3, and +0.6 ${\AA}$ from the centerline. The spectra of contrast constructed from the image data at each spatial point were analyzed using cloud models with a single velocity component, or three velocity components. As a result, we have identified a couple of velocity threads that are characterized by a narrow Doppler width($\Delta\lambda_D=0.27{\AA}$), a moderate value of optical thickness at the $H{\alpha}$ absorption peak($\tau_0=0.3$), and a spatial width(FWHM) of about 1". It has also been inferred that there exist 4-6 velocity threads along the line of sight at each spatial resolution element inside the filament. In about half of the threads, matter moves fast with a line-of-sight speed of $15{\pm}3km\;s^{-1}$, but in the other half it is either at rest or slowly moving with a line-of-sight velocity of $0{\pm}3km\;s^{-1}$. It is found that a statistical balance approximately holds between the numbers of blue-shifted threads and red-shifted threads, and any imbalance between the two numbers is responsible for the non-zero line-of-sight velocity determined using a single-component model fit. Our results support the existence not only of high speed counter-streaming flows, but also of a significant amount of cool matter either being at rest or moving slowly inside the filament.

TIME VARIATIONS OF THE RADIAL VELOCITY OF H2O MASERS IN THE SEMI-REGULAR VARIABLE R CRT

  • Sudou, Hiroshi;Shiga, Motoki;Omodaka, Toshihiro;Nakai, Chihiro;Ueda, Kazuki;Takaba, Hiroshi
    • Journal of The Korean Astronomical Society
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    • v.50 no.6
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    • pp.157-165
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    • 2017
  • $H_2O$ maser emission at 22 GHz in the circumstellar envelope is one of the good tracers of detailed physics and kinematics in the mass loss process of asymptotic giant branch stars. Long-term monitoring of an $H_2O$ maser spectrum with high time resolution enables us to clarify acceleration processes of the expanding shell in the stellar atmosphere. We monitored the $H_2O$ maser emission of the semi-regular variable R Crt with the Kagoshima 6-m telescope, and obtained a large data set of over 180 maser spectra over a period of 1.3 years with an observational span of a few days. Using an automatic peak detection method based on least-squares fitting, we exhaustively detected peaks as significant velocity components with the radial velocity on a $0.1kms^{-1}$ scale. This analysis result shows that the radial velocity of red-shifted and blue-shifted components exhibits a change between acceleration and deceleration on the time scale of a few hundred days. These velocity variations are likely to correlate with intensity variations, in particular during flaring state of $H_2O$ masers. It seems reasonable to consider that the velocity variation of the maser source is caused by shock propagation in the envelope due to stellar pulsation. However, it is difficult to explain the relationship between the velocity variation and the intensity variation only from shock propagation effects. We found that a time delay of the integrated maser intensity with respect to the optical light curve is about 150 days.

PERFORMANCE OF THE TRAO 13.7-M TELESCOPE WITH NEW SYSTEMS

  • Jeong, Il-Gyo;Kang, Hyunwoo;Jung, Jaehoon;Lee, Changhoon;Byun, Do-Young;Je, Do-Heung;Kang, Sung-Ju;Lee, Youngung;Lee, Chang Won
    • Journal of The Korean Astronomical Society
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    • v.52 no.6
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    • pp.227-233
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    • 2019
  • We report the performance of the 13.7-meter Taeduk Radio Astronomy Observatory (TRAO) radio telescope. The telescope has been equipped with a new receiver, SEQUOIA-TRAO, a new backend system, FFT2G, and a new VxWorks operating system. The receiver system features a 16-pixel focal plane array using high-performance MMIC preamplifiers; it shows very low system noise levels, with system noise temperatures from 150 K to 450 K at frequencies from 86 to 115 GHz. With the new backend system, we can simultaneously obtain 32 spectra, each with a velocity coverage of 163 km s-1 and a resolution of 0.04 km s-1 at 115 GHz. The new operating system, VxWorks, has successfully handled the LMTMC-TRAO observing software. The main observing method is the on-the-fly (OTF) mapping mode; a position-switching mode is available for small-area observations. Remote observing is provided. The antenna surface has been newly adjusted using digital photogrammetry, achieving a rms surface accuracy better than 130 ㎛. The pointing uncertainty is found to be less than 5" over the entire sky. We tested the new receiver system with multi-frequency observations in OTF mode. The aperture efficiencies are 43±1%, 42±1%, 37±1%, and 33±1%, the beam efficiencies are 45±2%, 48±2%, 46±2%, and 41±2% at 86, 98, 110, and 115 GHz, respectively.

DC magnetron sputtering을 이용하여 증착한 $SnO_2$ 기반의 박막 트랜지스터의 전기적 및 광학적 특성 비교

  • Kim, Gyeong-Taek;Mun, Yeon-Geon;Kim, Ung-Seon;Sin, Sae-Yeong;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.104-104
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    • 2010
  • 현재 디스플레이 시장은 급변하게 변화하고 있다. 특히, 비정질 실리콘의 경우 디스플레이의 채널층으로 주로 상용화되어 왔다. 비정질 실리콘 기반의 박막 트랜지스터는 제작의 경제성 및 균일성을 가지고 있어서 널리 상용화되고 있다. 하지만 비정질 실리콘의 경우 낮은 전자 이동도(< $1\;cm^2/Vs$)로 인하여 디스플레이의 대면적화에 부적합하며, 광학적으로 불투명한 특성을 갖기 때문에 차세대 디스플레이의 응용에 불리한 점이 있다. 이런 문제점의 대안으로 현재 국내외 여러 연구 그룹에서 산화물 기반의 반도체를 박막 트랜지스터의 채널층으로 사용하려는 연구가 진행중이다. 산화물 기반의 반도체는 밴드갭이 넓어서 광학적으로 투명하고, 상온에서 증착이 가능하며, 비정질 실리콘에 비해 월등히 우수한 이동도를 가짐으로 디스플레이의 대면적화에 유리하다. 특히 Zinc Oxide, Tin Oxide, Titanum Oxide등의 산화물이 연구되고 있으며, indium이나 aluminum등을 첨가하여 전기적인 특성을 향상시키려는 노력을 보이고 있다. Tin oxide의 경우 천연적으로 풍부한 자원이며, 낮은 가격이 큰 이점으로 작용을 한다. 또한, $SnO_2$의 경우 ITO나 ZnO 열적으로 화학적 과정에서 더 안정하다고 알려져 있다. 본 연구에서는 $SnO_2$ 기반의 박막 트랜지스터를 DC magnetron sputtering를 이용하여 상온에서 제작을 하였다. 일반적으로, $SnO_2$의 경우 증착 과정에서 산소 분압 조절과 oxygen vacancy 조절를 통하여 박막의 전도성을 조절할 수 있다. 이렇게 제작된 $SnO_2$의 박막을 High-resolution X-ray diffractometer, photoluminescence spectra, Hall effect measurement를 이용하여 전기적 및 광학적 특성을 알 수 있다. 그리고 후열처리 통하여 박막의 전기적 특성 변화를 확인하였다. gate insulator의 처리를 통하여 thin film의 interface의 trap density를 감소시킴으로써 소자의 성능 향상을 시도하였다. 그리고 semiconductor analyzer로 소자의 출력 특성 및 전이 특성을 평가하였다. 그리고 Temperature, Bias Temperature stability, 경시변화 등의 다양한 조건에서의 안정성을 평가하여 안정성이 확보된다면 비정질 실리콘을 대체할 유력한 후보 중의 하나가 될 것이라고 기대된다.

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THE SWINGS EFFECTS OF THE A-X SYSTEM AND v''= 1-0 BAND OF CO

  • KIM SANG-JOON
    • Journal of The Korean Astronomical Society
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    • v.29 no.2
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    • pp.223-243
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    • 1996
  • We have constructed a line-by-line model of the A-X system of CO in order to analyze the CO bands appearing in the UV spectra of comets. The model includes electronic, rotational, vibrational transitions, excitations by solar UV radiation, and effects of neutral and electron collisions. The major bands of the A-X system occur in the $1200 - 1800{\AA}$ range where the temporal variation of solar irradiation is significant. The solar spectrum in this spectral range shows many emission lines, which cause a significant Swings effect. We derived fluorescence efficiencies of the bands as functions of heliocentric velocity and cometocentric distance using a high resolution spectrum of the sun. We compared our model with a spectrum of comet P/Halley obtained with the IUE, and estimated that the UV Swings effects are less than 20 fluorescence efficiencies for the most bands of the A-X system. We discuss the temporal variation of solar UV irradiation and its effects on the fluorescence efficiencies. The study of the A-X system also requites knowledge of vibrational and rotational fluorescent processes in the infrared and radio regions because the majority of CO molecules in the coma is in the ground rotational states. The solar infrared spectrum near 5 microns, where the fundamental band of CO occurs, contains strong absorption lines of the fundamental band and hot bands of CO and its isotopes. We derived fluorescence efficiencies of the infrared band as functions of heliocentric velocity and cometrocentric distance. The solar absorption lines near 5 microns cause a 20 reduction of the g-factor of the fundamental band at heliocentric velocities close to 0 km/sec. We discuss the effects of neutral and electron collisions on the fluorescence efficiencies of the infrared and UV bands.

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Mössbauer Study of Ti1-x-yCoxFeyO2

  • Kim, Eng-Chan;Lee, S.R.;Kim, T.H.;Ryu, Y.S.;Cho, J.H.;Joh, Y.G.;Kim, D.H.
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.11-13
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    • 2006
  • [ $M\"{o}ssbauer$ ] spectra of $Ti_{1-x-y}Co_xFe_yO_2(0.01{\leq}x,\;y{\leq}0.05)$ prepared with $^{57}Fe$ enriched iron have been taken at various temperatures ranging from 80 to 300K. The Mossbauer spectrum of $Ti0.94Co_{0.03}Fe_{0.03}O_2$ consists of a ferromagnetic (six-Lorentzian), a paramagnetic phase (doublet) and armorphous phase over all temperature ranges. Isomer shifts indicate $Fe^{3+}$ for the ferromagnetic phase and the paramagneic phase of $Ti_{1-x-y}Co_xFe_yO_2$ samples. It is noted that the magnetic hyperfine field of ferromagnetic phase had the value about 1.5 times as large as that of u-fe. The XRB data for $Ti_{1-x-y}Co_xFe_yO_2$ showed mainly rutile phase with tetragonal structures without any segregation of Co and Fe into particulates within the instrumental resolution limit. The magnetic moment per (Co+Fe) atom in $Ti0.94Co_{0.03}Fe_{0.03}O_2$, under the applied field of 1T was estimated to be about $0.332{\mu}_B$ which is ten times as large as that of $Ti0.97Co_{0.03}Fe_{0.03}O_2,\;0.024{\mu}_B$ per Co atom, suggesting a high spin configuration of Co and fe ions.

Observational Properties of GSC 2855-0585 in the Vicinity of the Eclipsing Binary V432 Per

  • Koo, Jae-Rim;Lee, Jae Woo;Kim, Seung-Lee;Lee, Chung-Uk;Lee, Byeong-Cheol
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.142.1-142.1
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    • 2012
  • During the photometric runs of the eclipsing binary V432 Per in 2006, we serendipitously discovered peculiar light variations of GSC 2855-0585 that imaged on the same target field. Its brightness decreased about 0.02 mag for about 0.15 days in all B, V, and R bands. The depth, duration, and box-shaped light curves are very similar to those of typical transiting exoplanets. We gathered the time-series data of GSC 2855-0585 from the SuperWASP public archive and detected the same light variations with a period of about 2.406 days. The period and transitlike features were confirmed by photometric follow-up observations at a predicted epoch in 2010 November. In order to estimate the mass of the companion that produced the light variations, we obtained 10 high-resolution spectra with different orbital phases in 2010 November and 2011 October-December. The radial velocities showed large variations of about 44 km/s. It indicates that the transitlike light variations do not originate from a transiting exoplanet, but from the single-lined spectroscopic eclipsing binary with a cool dwarf companion. Using the photometric and spectroscopic data, we estimated the physical parameters of the eclipsing binary GSC 2855-0585, such as orbital period, effective temperature, surface gravity, and mass.

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