• Tunnel and Underground Space
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• v.32 no.6
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• pp.363-372
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• 2022

Precast concrete is an effective method to increase the construction quality and construction speed by optimizing and making the manufacturing conditions similar. In order to more effectively produce a fireproof material-integrated precast duct slab, the purpose of this study was to determine whether the fire resistance performance of the fireproof layer is maintained when a method of increasing the curing rate using a hardening accelerator is used. As a result of performing a fire resistance performance test on specimens classified according to whether or not the hardening accelerator was included, increase of temperature inside the specimen was high in the specimens using the hardening accelerator, and the section loss of the fireproof layer occurred locally on the surface exposed to fire heating. In conclusion, it is judged that the fireproof layer in the case where the strength at 3th day of age is gained within 1 day curing age using a hardening accelerator does not guarantee sufficient fire resistance performance in the conditions used in this study.

• Carbon letters
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• v.19
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• pp.1-11
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• 2016

In efforts to characterize and understand the properties and processing of phenylethynyl-terminated imide (LaRC PETI-5, simply referred to as PETI-5) oligomers and polymers as a high-temperature sizing material for carbon fiber-reinforced polymer matrix composites, PETI-5 imidization and thermal curing behaviors have been extensively investigated based on the phenylethynyl end-group reaction. These studies are reviewed here. In addition, the use of PETI-5 to enhance interfacial adhesion between carbon fibers and a bismaleimide (BMI) matrix, as well as the dynamic mechanical properties of carbon/BMI composites, are discussed. Reports on the thermal expansion behavior of intercalated graphite flake, and the effects of exfoliated graphite nanoplatelets (xGnP) on the properties of PETI-5 matrix composites are also reviewed. The dynamic mechanical and thermal properties and the electrical resistivity of xGnP/PETI-5 composites are characterized. The effect of liquid rubber amine-terminated poly(butadiene-co-acrylonitrile) (ATBN)-coated xGnP particles incorporated into epoxy resin on the toughness of xGnP/epoxy composites is examined in terms of its impact on Izod strength. This paper provides an extensive overview from fundamental studies on PETI-5 and xGnP, as well as applied studies on relevant composite materials.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.65-66
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• 2012

The cement used in the construction industry of the manufacturing process, large amounts of the greenhouse gas, CO₂ and is currently being studied for cement substitutes that reduce greenhouse gas issue. Therefore, the this study as a replacement for cement industrial by-product of blast furnace slag, red mud, silica fume and alkali-activator, using only inorganic composites without high-temperature calcination process were manufactured. The waste gypsum board micro powder added to compensate for the shrinkage cracks, the compressive strength and flow, and length change characteristics were investigated. Consequently, The setting time was shortened as GB added And liquidity was reduced. GB 2%, 7 days curing the added strength of specimens was the highest. Came out, and change the length of the Plain least.

• Composites Research
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• v.15 no.2
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• pp.40-47
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• 2002

The di-functional epoxy resins, i.e., diglycidylether of bisphenol A(DGEBA) and diglycidylethere of bisphenol F(DGEBF) were initiated by cationic catalyst, i.e., benzylquinoxalinium hexafluoroantimonate(BQH) using electron-beam(EB) technique. And the effect of structure of DGEBA and DGEBF on thermal stabilities and cure behaviors was investigated. According to the experimental results, the decomposed activation energy based on Horowitz-Metzger method was higher in the case of DGEBA, but intergral procedural decomposition temperature(IPDT) of DGEBA was lower than DGEBF. This could be interpreted in terms of high crosslink density resulted from hydroxyl bond of DGEBF backbone. It was confirmed in increasing the hydroxyl band at $7000\;cm^{-1}$ and $5235\;cm^{-1}$ using near-infrared spectroscopy(NIRS).

• Transactions of the Korean Society of Automotive Engineers
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• v.25 no.3
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• pp.350-359
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• 2017

This paper presents a new holistic development approach for the carbon continuous-fiber composite frame of an automotive sunroof assembly. The original steel frame has been designed to get higher bending stiffness with its corrugated cross-sectional shape. The new approach uses the prepregs of a fast cure epoxy and PCM manufacturing processing. For higher productivity, the new frames feature a very simple plat cross sectional shape but achieve high bending stiffness through the laminate design. The sandwich structure with a PET foam core was presented. The frames were made of carbon UD laminae covered single carbon fabric on the outer surfaces. The fabrics provide torsional stiffness and also hold the carbon UD fibers floating in the low viscous epoxy resin of prepregs at the curing temperature during processing. The final product yields approximately 18 % savings in weight compared with the original.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2008.11a
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• pp.1-5
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• 2008

In this study, batcher plant composition test and mock-up test were carried out to conduct comparison and analysis on flow behavior and strength properties of concrete at early age. As a result, it was found that slump and amount of air in batcher plant composition test reached the target range. As for compressive strength, composition using HESPC showed the most excellent strength development. In mock-up test which was carried out to find out the strength properties, two methods with specimen and core test body both revealed HESPC as the most excellent composition. However, strength estimation with ultrasonic survey presented less reliable data. As a result of the previously conducted indoor composition test and the mock-up test in this study, target performance of concrete at early age was 4day/cycle. It was found that the optimum conditions that meet the required strength, 5MPa/18hr and 14MPa/36hr in mullion and transom are; curing temperature above 15℃, W/B 45%, unit-water 165kg/㎥ and CHC cement.

• Carbon letters
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• v.11 no.2
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• pp.107-111
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• 2010

We prepared the amine epoxy adducts (AEA)/thin multiwalled carbon nanotubes (TWCNTs) composite particles using nonsolvent based methods including dry mechano-chemical bonding(MCB) process and supercritical fluid (SCF) process. The resulting TWCNTs/AEA composite particles have been used as curing agents for urethane modified bispheol A type epoxy resin. The thermal, thermomechanical properties of the epoxy resins cured with TWCNTs/AEA composite particles were measured by DMA and the dispersion of CNT was characterized by SEM. Because of high degree of CNT dispersion, thermal and mechanical properties of the epoxy resin cured with TWCNTs/AEA composite particles prepared by SCF process are better than those cured with mechano-chemically prepared TWCNTs/AEA composite particles.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.1108-1109
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• 2008

To survive in outdoor environments, photovoltaic modules rely on packaging materials to provide requisite durability. We analyzed the properties of encapsulant materials that are important for photovoltaic module packaging. Recently, the thickness of solar cell gets thinner to reduce the quantity of silicon. And the reduced thickness make it easy to be broken while PV module fabrication process. Solar cell's micro cracks are increasing the breakage risk over the whole value chain from the wafer to the finished module, because the wafer or cell is exposed to tensile stress during handling and processing. This phenomenon might make PV module's maximum power and durability down. So, when using thin solar cell for PV module fabrication, it is needed to optimize the material and fabrication condition which is quite different from normal thick solar cell process. Normally, gel-content of EVA sheet should be higher than 80% so PV module has long term durability. But high gel-content characteristic might cause micro-crack on solar cell. In this experiment, we fabricated several specimen by varying curing temperature and time condition. And from the gel-content measurement, we figure the best fabrication condition. Also we examine the crack generation phenomenon during experiment.

• Applied Science and Convergence Technology
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• v.23 no.6
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• pp.376-386
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• 2014

Zinc oxysulfide nanocrystals (ZnOS NCs) were synthesized by forming ZnS phase on a ZnO matrix. ZnO nanocrystals (NCs) with a diameter of 10 nm were synthesized by forced hydrolysis in an organic solvent. As-synthesized ZnO NCs aggregated with each other due to the high surface energy. As acetic acid (AA) was added into the milky suspension of the aggregated ZnO NCs, transparent solution of well dispersed ZnO NCs formed. Finally ZnOS NCs were formed by adding thioacetic acid (TAA) to the transparent solution. The effect of recrystallization on the structural, optical and electrical properties of the ZnOS NCs were studied. The results of UV-vis absorption confirmed the band gap tunability caused by increasing the curing temperature of ZnOS thin films. This may have originated from the larger effective size due to the recrystallization of zinc sulfide (ZnS). From XRD result we identified that ZnOS thin films have a zinc blende crystal structure of ZnS without wurtzite ZnO structure. This is probably due to the small amount of ZnO phases. These assertions were verified through EDS of FE-SEM, XPS and EDS mapping of HR-TEM results; we clearly proved that ZnOS were comprised of ZnS and ZnO phases.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.215-216
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• 2016

Urethane waterproofing materials which currently being used most commonly in the Korean domestic market have high applicability and construct layers without forming any joints, but under the influence of low temperature and low humidity, as well as the thickness of the applied layer, the curing time of this material may become extended in construction sites. To resolve these issues, a proposed method of using water-hardening type of polyurethane waterproofing materials are being developed. However, there currently lacks any standards or evaluation methods on determining an optimal mixture ratio of water for the water-hardening polyurethane waterproofing materials. Therefore, for the establishment of a board applicability of the water-hardening polyurethane waterproofing methods in construction sites, this study objectively analyzes the changes in the performance of these materials depending on the changes of the water mixture ratio and attempts to procure the optimal ratio on the basis of forming a provisionary standard.