• Title/Summary/Keyword: heat of formation

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The numerical model for predicting frost layer growth (서리층 성장 예측을 위한 수치적 모델)

  • Lee, K.S.;Jhee, S.;Lee, T.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.2
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    • pp.249-258
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    • 1997
  • In this study, a numerical model for analyzing frost formation phenomena on a cold flat plate has been developed. Both regions of air flow and frost layer have been coupled to calculate the amount of the heat and mass transfer between air flow and frost layer. Experiments have been also conducted to validate the numerical model. The present numerical results show a good agreement with the experimental data. The present numerical model also provides some useful data such as the temperature distribution inside the frost layer which could not be obtained through the experiments.

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A Study on Cu(In,Ga)Se2 Thin Film with Substrate Temperature Change (기판 온도 변화에 따른 Cu(In,Ga)Se2 박막에 관한 연구)

  • Park, Jung-Cheul;Chu, Soon-Nam
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.12
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    • pp.888-893
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    • 2013
  • In this paper, we prepared $Cu(In,Ga)Se_2$ thin films by using co-evaporation method, and analyzed the properties of the thin films. During the thin film preparation process, we confirmed $InGaSe_2$ phase was formed at $400^{\circ}C$ in first stage, and also confirmed the thin films showed the vacancy decrease. In second and third stage, we confirmed the density increase of crystalline structure at over $480^{\circ}C$ and the formation of $Cu(In_{0.7}Ga_{0.3})Se_2$ phase. As the result of SEM and XRD analysis of the films which were before and after heat-treated, we confirmed the disappearance of $Cu_2Se_2$ and the formation of $Cu(In_{0.7}Ga_{0.3})Se_2$ single phase after the heat-treatment, We, therefore, confirmed the heat-treatment did not affect the absorbency spectra of the thin films.

Fabrication and Characteristics of Thermal Sprayed Ni-Cr-B-Si System Amorphous Coatings (Ni-Cr-B-Si계 비정질 용사피막의 제조 및 특성)

  • 정하윤;김태형;박경채
    • Journal of Welding and Joining
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    • v.17 no.4
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    • pp.53-59
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    • 1999
  • Amorphous alloys have also been called glassy alloys or non-crystalline alloys. They are made by the rapid solidification. The solidification occurs so rapid that the atoms are frozen in their liquid configuration. There are unique magnetic, mechanical, electrical and corrosive behaviors which result form their amorphous structure. In the study. amorphous coatings were manufactured with Ni-Cr-B-Si powders by flame spray. Measurement of hardness, were resistance, corrosion resistance and observation of microstructures and XRD, DSC were performed to investigate characteristics of amorphous coatings. The experimental results obtained as follow: 1) Amorphous powders could not be manufactured with the spraying in the spraying in the liquid nitrogen. But, amorphous coatings could be manufactured with the rotation cooling method by liquid nitrogen. In the fabrication of amorphous coatings, major factor was the rapid cooling by rotation of the substrate. 2) Hardness of coatings was obtained Hv 960 by formation of amorphous phase. But, wear resistance decreased. That was due to porosity in the coatings by the rapid cooling. 3) In the case of corrosion resistance, amorphous coatings were superior to air-cooled coatings. That was due to formation of amorphous phase. 4) After amorphous coatings were heat-treated at 520℃ for 1hr. hardness increased 80% and wear resistance increased 30% comparing with air cooled coatings. These were due to crystallization of amorphous phase and decrease of porosity by heat-treatment.

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Preparation of Carbon Nanomaterial from the Microbial Cellulose (미생물 셀룰로오스로부터 탄소 나노물질의 제조)

  • Kim Bong Gyun;Sohng Jae Kyung;Liou Kwangkyoung;Lee Hei Chan
    • KSBB Journal
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    • v.20 no.1 s.90
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    • pp.50-54
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    • 2005
  • Tar is often produced during the carbonization of cellulose that limits the formation fibrous structure of the carbonized sample. This problem was reduced by applying a high temperature $(up\;to\;800{\circ}C)$ during carbonization process. Alternatively, dry cellulose was immersed in toluene and ultrasonicated prior to carbonization. In both cases, complete fibrous structures were not achieved. The formation of tar was reduced by the heat treatment of cellulose in the presence of HCI vapor before carbonization process. Such treatment before carbonization yielded mostly the fibrous structures of the carbonized sample as evident from SEM analysis. Similar results were found when the cellulose was subjected to a heat treatment in an inert condition followed by the removal of tar by the oxidation process prior to the carbonization.

A Study on Variable Mold for Improving the Forging Process of Transition Nozzle using TRIZ and DEFORM (TRIZ와 DEFORM을 활용한 트랜지션 노즐의 성형 공정 개선을 위한 가변 금형에 대한 연구)

  • Hwang, Hui-Geon;Chung, Won-Jee;Sul, Sang-Suk;Kim, Dae-Young
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.6
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    • pp.29-35
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    • 2020
  • Transition Nozzles are used in industrial air-cooled heat exchangers and widely used in industrial sites as an important component in the heat energy transfer between a heat source and an actuating fluid. There is a worldwide demand for transition nozzles with various materials and shapes, depending on the use environment. This paper aims to improve the transition nozzle forging process suitable for the production of many varieties using Steps 1 to 6 of the TRIZ Methodology for Problem Solving. By utilizing the TRIZ Methodology, this study derives a method to design a variable mold, which is more efficient and can reduce costs compared with having to use several molds. To verify the suitability of the methods derived using the TRIZ technique, a forging analysis is performed on a transition nozzle using DEFORMⓇ, a commercial program for plasticity analysis, and the nozzle material is evaluated for damage as a result of deformation of the transition nozzle thickness. The derived methods can be applied to transition nozzle formation equipment to improve the efficiency of the formation process.

Evaluation of Effective Thermal Conductivity and Thermal Resistance in Ground Heat Exchanger Boreholes (지중 열교환기 보어홀에서의 유효 열전도도 및 열저항 산정)

  • Sohn Byong Hu;Shin Hyun-Joon;Park Seong-Koo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.8
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    • pp.695-703
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    • 2005
  • The objective of this study is to determine the effective thermal conductivity and thermal resistance values in test boreholes with three different fill materials. To evaluate these heat transfer properties, in-situ tests on four vertical boreholes were conducted by adding a monitored amount of heat to water over various test lengths. Two parameter estimation models, line-source and numerical one-dimensional models, for evaluation of thermal response test data were compared when applied on the same four data sets. Results show that the average thermal conductivity deviation between measured data and these two models is in the range of $3.03\%$ to $4.45\%$. The effect of increasing grout thermal conductivity from 1.34 to 1.82 $W/m^{\circ}C$ resulted in overall increases in effective formation thermal conductivity by $11.1\%$ to $51.9\%$ and reductions in borehole thermal resistance by $11.6\%$ to $26.1\%$.

The Effect of Hybrid Reburning on NOx Reduction in Oxygen-Enriched LPG Flame (산소부화 LPG 화염에서 혼합형 재연소 방법에 의한 NOx 저감 효과)

  • Lee, Chang-Yeop;Baek, Seung-Wook
    • Journal of the Korean Society of Combustion
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    • v.12 no.4
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    • pp.14-21
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    • 2007
  • In order to enhance combustion efficiency, oxygen-enriched combustion is used by increasing the oxygen ratio in the oxidizer. However, since the flame temperature increases, NOx formation in the furnace seriously increases for low oxygen enrichment ratio. In this case, reburning is a useful technology for reducing nitric oxide. In this research, experimental studies have been conducted to evaluate the hybrid effects of reburning/selective non-catalytic reaction (SNCR) and reburning/air staging on NOx formation and also to examine heat transfer characteristics in various oxygen-enriched LPG flames. Experiments were performed in flames stabilized by a co-flow swirl burner, which were mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and NOx generation were observed to increase by low level oxygen-enriched combustion, but due to its hybrid effects of reburning, SNCR and Air staging, NOx concentration in the exhaust have decreased considerably.

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Lattice Deformation and Improvement Oxidation Resistance of Ti-6Al-4V Alloy Powders Prepared by Hydrogen Added Argon Heat Treatment (수소 첨가 열처리에 따른 Ti-6Al-4V 합금 분말의 격자 변형 및 내산화성 향상)

  • Cho, Gye-Hoon;Oh, Jung-Min;Lim, Jae-Won
    • Journal of Powder Materials
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    • v.26 no.2
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    • pp.126-131
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    • 2019
  • In the present work, a new hydrogen added argon heat treatment process that prevents the formation of hydrides and eliminates the dehydrogenation step, is developed. Dissolved hydrogen has a good effect on sintering properties such as oxidation resistance and density of greens. This process can also reduce costs and processing time. In the experiment, commercially available Ti-6Al-4V powders are used. The powders are annealed using tube furnace in an argon atmosphere at $700^{\circ}C$ and $900^{\circ}C$ for 120 min. Hydrogen was injected temporarily during argon annealing to dissolve hydrogen, and a dehydrogenation process was performed simultaneously under an argon-only atmosphere. Without hydride formation, hydrogen was dissolved in the Ti-6Al-4V powder by X-ray diffraction and gas analysis. Hydrogen is first solubilized on the beta phase and expanded the beta phases' cell volume. TGA analysis was carried out to evaluate the oxidation resistance, and it is confirmed that hydrogen-dissolved Ti-6Al-4V powders improves oxidation resistance more than raw materials.

Formation of Al3Ti From Mechanically Alloyed Hyper-Peritectic Al-Ti Powder (기계적 합금화법으로 제조된 과포정 Al-Ti 합금에서 Al3Ti 형성에 관한 연구)

  • Kim, Hye-Sung;Suhr, Dong-Soo;Kim, Gyeung-Ho;Kum, Dong-Wha
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.1
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    • pp.1-11
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    • 1996
  • Mechanical alloying is an effective process to finely distribute inert dispersoids in an Al-TM(TM is a transition metal) system. It has been considered that high melting point aluminides are formed by precipitation from supersaturated Al(Ti) powder. This analysis is based on the fact that much higher content of TM than the solubioity can be dissolved in alpha aluminum during the high energy ball milling. Thus, decomposition behavior of Ti in the Al(Ti) was considered very important. But it is confirmed that the higher portion of Ti than Al(Ti) solid solution is existed as nano-sized Ti particles in the MA powders by high energy ball nilling from the XRD spectrum and TEM analysis in this study. Therefore, the role of undissolved TM particles affect the formation of aluminides should be suitably considered. In this study, we present experimental observation on the formation of $Al_3Ti$ fron mechanical alloyed Al-Ti alloys in the hyperperitectic region. This study showed that, in the mechanically alloyed Al-20wt%Ti specimen, intermediate phase of cubic $Al_3Ti$ and tetragonal $Al_{24}Ti_8$ formed at $300{\sim}400^{\circ}C$ and $400{\sim}500^{\circ}C$, respectively, before the MA state reaches to equilibrium at higher temperatures. The formation behavior of $Ll_2-Al_3Ti$ is interpreted by interdiffusion of Al and Ti in solid state based on the fact that large amount of nano-sized Ti particles exist in the milled powder. Present analysis indicated undissolved Ti particles of nanosize should have played an important role initiation the formation of $Al_3Ti$ phase during annealing.

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Effect of Carbon Potential on the Carbide Formation and Pitting Fatigue Strength of Supercarburized Steel (고농도 침탄강의 탄화물 형성과 피팅 피로강도에 미치는 탄소 포텐셜의 영향)

  • So, Sangjin;Shin, Jungho;Lim, Jae-Won;Lee, Seok-Jae
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.3
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    • pp.113-123
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    • 2016
  • In the present work, we investigated the effects of the carbon potential on the formation of carbide at the carburized surface and anti-pitting fatigue strength in the supercarburized steels. Two low carbon steels with different Cr concentrations were adopted and the repeated supercarburizing treatment carried out with the different carbon potential conditions. The microstructure and carbides at the supercarburized surface were observed by using optical microscope and scanning electron microscope. The microhardness test was performed and the hardness distribution and the effective case depth at the supercarburized surface were discussed. The roller pitting fatigue test was carried out and the fatigue strength was evaluated with different the carbon potential conditions. The microstructure of the fatigue specimen surface was observed by means of scanning electron microscope and scanning transmission electron microscope. Depending on the chemical composition of the steels and the carbon potential condition, the resistance of temper softening and pitting failure was influenced due to the carbide distribution and the formation of coarse network carbide. Thus, it was confirmed that the control of the carbide formation is a key factor to improve the anti-pitting fatigue strength in the supercarburized steels.