• Title/Summary/Keyword: heat capacity

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Theoretical Prediction of the Thermodynamic Properties of Liquid-Crystalline p-Azoxyanisole (액정 p-Azoxyanisole의 열역학적 성질에 대한 이론적인 예측)

  • Youngkyu Do;Mu Shik Jhon;Taikyue Ree
    • Journal of the Korean Chemical Society
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    • v.20 no.2
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    • pp.118-128
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    • 1976
  • The significant structure theory of liquids and the Bragg-Williams approximation of phase transition theory have been applied to the calculation of the thermodynamic properties of p-azoxyanisole which exhibits a liquid crystal phase of the nematic type. The isotropic phase was treated as a normal liquid; and for the nematic phase, in addition to its liquidity, the effect due to the arrangement of molecular-dipoles was considered. The liquidity of the p-azoxyanisole was described by the significant structure theory of liquids, and the Bragg-Williams approximation was used to consider the effect due to the arrangement of molecular-dipoles. The molar volume, vapor pressure, heat capacity at constant pressure, thermal expansion coefficient, compressibility, entropy and enthalpy change at the nematic-isotropic phase transition point, absolute entropy, and absolute Helmholtz free energy were calculated over the temperature range of the nematic and isotropic phases. The calculated results of the thermodynamic properties were compared with the experimental data.

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Experimental Investigation on the Cryogenic Thermosiphon Using N$_2$ and CF$_4$ Mixture as the Working Fluid (N$_2$와 CF$_4$ 혼합물을 작동유체로 하는 극저온 열사이펀에 대한 실험적 연구)

  • Kim, Young-Kwon;Lee, Ji-Sung;Jeong, Sang-Kwon;Han, Young-Hee;Jung, Se-Yong;Park, Byung-Jun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.9
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    • pp.505-512
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    • 2009
  • A thermosiphon is utilized as a thermal shunt to reduce the cool-down time of a cryogenic system cooled by a two stage cryocooler. The cool-down time reduction by the thermosiphon is determined by the type of working fluid which is directly related to the operating temperature range of the thermosiphon. A mixed working fluid has a potential to widen the operation temperature range of the thermosipohon. In this study, the thermosiphon using N$_2$ and CF$_4$ mixture as the working fluid is fabricated and tested to verify its transient heat transfer performance. The thermosiphon with the mixed working fluid has no noticeable reduction of cool-down time compared with that of the thermosiphon with pure working fluid in this experiment. However, it seems that the thermosiphon with mixed working fluid may have an advantage according to the cooling capacity of a cryocooler, the cooling target temperature and the size of a cooling object.

Observation and Analysis of Long and Short-wave Radiation According to Types of Summer Shelters (하계 그늘쉼터 유형별 장·단파복사 관측과 해석)

  • Baek, Chang-Hyeon;Choi, Dong-Ho;Lee, Bu-Yong;Lee, In-Gyu
    • Journal of the Korean Solar Energy Society
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    • v.39 no.6
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    • pp.127-135
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    • 2019
  • In this study, we analyzed the relationship between five factors: long-wave radiation, short-wave radiation, cloudiness, SVF and summer shelters. In the previous study, we recognized the correlation between single building SVF and long-wave radiation. Furthermore, this study attempted to confirm the relationship at the summer shelter with high solar radiation blocking rate. The observations are as follows. ① Cooling in summer shelters was not the effect of temperature but the effect of radiation reduction due to short-wave radiation shielding. ② In the case of the canopy tent with low heat capacity, the long-wave radiation was observed to be 16.7% higher per hour than the comparison control point due to the increase in surface temperature. ③ The long-wave radiation increase rate was different according to SVF, but showed very similar pattern according to the material characteristics of the summer shelters. ④ Passive Cooling effect on the type of summer shelters are determined by the size of the total long and short-wave radiation at that point.

Suppression of performance degradation due to cold-head orientation in GM-type pulse tube refrigerator

  • Ko, Junseok;Kim, Hyobong;Park, Seong-Je;Hong, Yong-Ju;Koh, Deuk-Yong;Yeom, Hankil
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.4
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    • pp.50-53
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    • 2012
  • This paper describes experimental study on GM-type pulse tube refrigerator (PTR). In a PTR, the pulse tube is only filled with working gas and there exists secondary flow due to a large temperature difference between cold-end and warm-end. The stability of secondary flow is affected by orientation of cold-head and thus, the cooling performance is deteriorated by gas mixing due to secondary flow. In this study, a single stage GM-type pulse tube refrigerator is fabricated and tested. The cooing performance of the fabricated PTR is measured as varying cold-head orientation angle and the results are used as reference data. Then, we divided interior space of pulse tube into three segments, and fixed the various size of screen mesh at interface of each segment to suppress the performance degradation due to secondary flow. For various configuration of pulse tube, no-load test and heat load test are carried out with the fixed experimental condition of charging pressure, operating frequency and orifice valve turns. From experimental results, the fine screen mesh shows the effective suppression of performance degradation for the large orientation angle, but the use of screen mesh cause the loss of cooling capacity rather than the case of no insertion into pulse tube. It should be compromised whether the use of screen mesh in consideration of the installation limitation of a GM-type pulse tube refrigerator.

A Study on the Dynamic Charateristics for Control of Gas-Fueled industrial Gas Boiler(I) (산業용 GAS 보일러의 動特性에 관한 硏究 (I))

  • 임종한;이종원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.5
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    • pp.965-973
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    • 1992
  • Boilers, which are considered to be one of the basic equipment in industry, consume large potion of nation's petroleum and their demand is growing everyday. In recent, the technology improvement in production of high efficiency boilers and their effective utilization is needed for design of boiler which steam condition is the large capacity of high temperature and high pressure. It is necessary that boiler control system be studied for high efficiency, high reliability and smooth operation. The control of drum pressure and water level particularly becomes an important task for greater accuracy with the avail ability of boiler operation. To achieve this aim, dynamic analysis of a boiler is accomplished by choosing a boiler as a model. Transfer function thus obtained is made a comparison of measurement with reckoning to technical design data. The results of comparison makes it possible to verify thermodynamical analysis on the dynamic behavior of the overall system.

Development and Test of a Cooling System for a 154 kV Superconducting Fault Current Limiter

  • Kim, Heesun;Han, Young Hee;Yang, Seong-Eun;Yu, Seung-Duck;Park, Byung Jun;Park, Kijun;Yoo, Jaeun;Kim, Hye-Rim;In, Sehwan;Hong, Yong Joo;Yeom, Hankil
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.141-144
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    • 2015
  • The superconducting fault current limiter (SFCL) is an electric power device that limits the fault current immediately in a power grid. Korea Electric Power Corporation (KEPCO) has been developing a 154 kV, 2 kA SFCL since 2011 to protect power grids from increasing fault current and improve the stability and quality of electric power. This SFCL adopts 2G YBCO wires and operates at 71 K and 5 bars. In this paper, a cooling system for the 154 kV SFCL and its cooling test results are reported. This cooling system uses a Stirling-type cooler to make sub-cooled liquid nitrogen ($LN_2$), which cools the superconductor modules of the SFCL. The $LN_2$ is circulated between the cooler and the cryostat that contains superconductor modules. The $LN_2$ also plays the role of a high voltage insulator between the modules and the cryostat, so the pressure was maintained at 5 bars for high insulation performance. After installation in a test site, the cooling characteristics of the system were tested. In this operation test, some important data were measured such as temperature distribution in $LN_2$, pressure change, performance of the heat exchanger, and cooling capacity of the total system. Consequently, the results indicate that the cooling system operates well as designed.

Development of a Refrigeratory-Based Dehumidifier for Humidity Environment Control in Greenhouse (시설원예 습도환경 제어를 위한 냉각식 제습기 개발)

  • Kang, G.C.;Yon, K.S.;Ryou, Y.S.;Kim, Y.J.;Kang, Y.K.;Paek, Y.
    • Journal of Biosystems Engineering
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    • v.32 no.4
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    • pp.247-255
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    • 2007
  • During the winter season in Korea, the relative humidity of greenhouse at night often exceeds 90% because air temperature inside the greenhouse is usually controlled using a heater with all of windows closed to minimize heat loss, thereby requiring the use of a dehumidifier that can maintain optimum humidity levels of $70{\sim}80%$ to provide a good growth condition of crops. Also, such a high humid condition can cause the development of a pest, such as insects, fungi or diseases. However, the use of most conventional dehumidifiers for low temperature dehumidification is limited because their performance is degraded due to frost accumulation on the evaporator coil. This study was carried out to develop a refrigeratory-based dehumidifier suitable for low temperature dehumidification in greenhouse cultivation. The developed dehumidifier consists of a condenser and an evaporator installed separately so that relative and absolute humidity levels can be reduced when air passed through the condenser and evaporator, respectively. The prototype dehumidifier showed a dehumidification capacity of $5{\sim}7kg/h$ when air with a temperature of $15{\sim}25^{\circ}C$ and a relative humidity of $70{\sim}95%$ came into the dehumidifier. Under the condition that either temperature or relative humidity was fixed, the amount of condensed water was proportional to the levels of both temperature and relative humidity.

A Study of On-line Cleaning Method for Increasing Efficiency in a Combustor (연소로 효율증진을 위한 on-line 세정 방법에 관한 연구)

  • Jang, Hyun-Tae;Han, Seung-Dong;Park, Tae-Sung;Cha, Wang-Seong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.3
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    • pp.1016-1022
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    • 2010
  • An Experimental study of cleaning solution has been performed on a high capacity steam boiler burning heavy fuel oil to on-line cleaning of deposit. The deposit is mixture of soot, slag, ash, metal oxide and clinker. The traditional technology of deposit cleaning was carried hand-crafted. The conventional technology of boiler cleaning method is mechanical removal by the worker while the boiler shut down operation. In this experiment, the deposit of mixture of soot, slag, ash, metal oxide and clinker has been removed by the cleaning agents without shut down of boiler burning. This study found out the optimum cleaning solution composition. The best results have been obtained when the mixture of ammonium nitrate and $MgNO_3$ were used in cleaning solution. The various transition metal effect was investigated for optimum mixing condition. In this research, the metal compound additive of the clean solution compoition was obtained. The combustion efficiency was improved by on-line cleaning with derived clean solution compoition. On-line cleaning method prevents the fouling and corrosion in the boiler and heat exchanger.

Studies on Physico-chemical Properties of Chicken Meat Cooked in Electric Oven Combined with Superheated Steam (전기오븐에서 과열증기주입에 따른 열처리가 닭고기의 이화학적 특성변화에 미치는 영향)

  • Chun, Ji-Yeon;Kwon, Bong-Gu;Lee, Su-Hyun;Min, Sang-Gi;Hong, Geun-Pyo
    • Food Science of Animal Resources
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    • v.33 no.1
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    • pp.103-108
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    • 2013
  • This study was carried out to observe the effect of superheated steam combined with oven heating on the physico-chemical and sensory properties of chicken meat. Specially, chicken breasts and thighs were heated for 40 min in various heating formulations such as oven heating, superheated steam heating or a combination of two kinds of heating. In the physical properties measurement, the shear force was increased as superheated steam heating time and chicken thighs were higher than chicken breasts in all treatments (p<0.05). The highest level of water holding capacity was solely superheated steam treated chicken for 40 min (p<0.05). The $L^*$ value was decreased but $a^*$ value or $b^*$ value were increased after cooking. Chicken breast exhibited a higher colour value than chicken thigh. Superheated heating was effective to reduce heating loss as 22.64% (p<0.05). However, pH was not different depending on the heating formulation or part of the chicken meat (p>0.05). In the sensory test, the combination of 10 min oven heating and 30 min superheated steam heating was effective to create a good flavour of chicken meat. In this study, an optimum formulation was developed which was a combination of 10 min oven heating and 30 min superheated steam heating. It was more effective to improve the quality of chicken meat than the single heat treatment of chicken meat.

Ohmic Thawing of a Frozen Meat Chunk (Ohmic Heating을 이용한 동결육의 해동)

  • Yun, Cheol-Goo;Lee, Do-Hyun;Park, Ji-Yong
    • Korean Journal of Food Science and Technology
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    • v.30 no.4
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    • pp.842-847
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    • 1998
  • Ohmic thawing in combination with conventional water immersion thawing was investigated. Frozen meat chunks $(10{\times}10{\times}10{\;}cm)$ were immersed in a water reservoir $(12{\times}12{\times}12{\;}cm)$ which temperature was maintained at $10^{\circ}C{\;}or{\;}20^{\circ}C$, and were positioned between two stainless-steel electrodes $(10{\times}10{\;}cm)$ having no direct contact with the samples. Alternating current $(60{\;}V{\sim}210{\;}V)$ at various frequency $(60{\;}Hz{\sim}60{\;}kHz)$ was used to generate internal heat by the electrical resistance. When the frequency was fixed to 60Hz, thawing time was reduced as the voltage increased. Frequency changes gave no significant effect on thawing time. Ohmically-thawed samples treated with lower voltage showed lower drip loss and higher water holding capacity.

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