• Title/Summary/Keyword: halide

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The Study for Surface Activity of Alkylquinolinium Halide Ⅰ. The Critical Micelle Concentration of Solution of Dodecylquinolinium Bromide (Alkylquinolinium Halide의 계면활성에 관한 연구 Ⅰ. Dodecylquinolinium Bromide 수용액의 Critical Micelle Concentration)

  • Lee Chong-Man
    • Journal of the Korean Chemical Society
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    • v.16 no.4
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    • pp.205-207
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    • 1972
  • Dodecylquinolinium bromide has been synthesized and the critical micelle concentrations of it in the aqueous solution have been determined by the measurement of the surface tension and the electrical conductance. The values are $3.34 {\times} 10^{-3}mole/l$ and 3.41 {\times} $10^{-3}$mole/l, respectively. Since dodecylquinolinium bromide has the larger hydrophobic group than dodecylpyridinium bromide, it is considered that the former has the smaller critical micelle concentration than the latter.

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Determination of Arylmethyl Halides by Gas Chromatograph (Gas Chromatograph에 의한 Arylmethy Halides의 정량)

  • Oh, Dos Suk;Choi, Ho Chun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.4 no.1
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    • pp.25-32
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    • 1994
  • Arylmethyl halides(benzyl chloride, BZYC; benzal chloride, BZYA; benzotrichloride, BZTC) and related compounds(benzyl alcohol, BZYA; benzoyl chloride, BZOC) were determined by GC using capillary column. Detailed results are as follows. 1. Stability In methanol benzotrichloride slowly transferred to benzoyl chloride by hydrolysis(ca. 7.5% for 5 days), but the others were stable. Therefore, benzotrichloride solution should be prepared just before analysis. 2. GC analysis Tenax-GC was used to absorbent and desorption solvents were $CCl_4$ and MeOH. Arylmethyl halides were analyzed within 7.5min without interference with related compounds. The calibration curve(ca. 15-80 ppm in soln), repeatability(n=10) and the desorption efficiency were good. Limit of detection by NIOSH method was about 0.003 ppm for arylmethyl halide, respectively. To analyze arylmethyl halides and related compounds in working places GC using capillary column is anticipated to be used effectively.

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Characteristics Comparison of the Dimmable Electromagnetic and the Electronic Ballast for a Metal-Halide Lamp (MHL용 전자식 안정기와 자기식 안정기의 조도 제어 특성 비교)

  • Lee, Bong-Jin;Kim, Ki-Nam;Park, Chong-Yeon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1001-1002
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    • 2008
  • 본 논문에서는 MHL(Metal-Halide Lamp)용 자기식과 전자식 안정기에 의한 조도 제어 특성을 분석하였다. 실험에 사용된 자기식 안정기는 가변 인덕턴스를 이용한 조도 제어 기법을 적용하였으며 전자식 안정기는 스위칭 주파수를 가변하는 조도 제어 기법을 적용하였다. 실험을 통하여 얻은 데이터를 바탕으로 조도 제어시 특성을 비교 및 분석하였다.

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Optical Characterization of Cubic and Pseudo-cubic Phase Perovskite Single Crystals Depending on Laser Irradiation Time

  • Byun, Hye Ryung;Jeong, Mun Seok
    • Applied Science and Convergence Technology
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    • v.27 no.2
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    • pp.42-45
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    • 2018
  • Photovoltaic and optoelectronic devices based on hybrid metal halide perovskites ($MAPbX_3$; $MA=CH_3NH_3{^+}$, $X=Cl^-$, $Br^-$, or $I^-$) are rapidly improving in power conversion efficiency. Also, during recent years, perovskite single crystals have emerged as promising materials for high-efficiency photovoltaic and optoelectronic devices because of their low defect density. Here we show that the light soaking effect of mixed halide perovskite ($MAPbBr_{3-x}I_x$) single crystals can be explained using photoluminescence, time-resolved photoluminescence, and Raman scattering measurements. Unlike Br-based single crystal, Br/I mixed single crystal show a strong light soaking effect under laser irradiation condition that was related to the existence of multiple phases.

A Study for Optimal filling Condition in Outer Enclosure of Metal Halide Lamp (메탈 할라이드 램프 외관의 최적 봉착조건에 관한 연구)

  • Chee, Chol-Kon;Lee, Sung-Jin
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.296-299
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    • 1987
  • The purpose of this paper is to increase the lamp efficacy by filling the optimal Nitrogen gas pressure in the outer enclosure of metal halide lamp. This study presents a new model of Langmuir in the outer enclosure of discharge lamp. In this paper, in the first place, the diameter of Langmuir sheath and the total gab loss were calculated. Secondly, the each gas loss was computed if the arbitrary gas pressure is filled, With the calculated data, flash over which affects the lamp efficacy, lamp life and color rendering was considered. In case of the established discharge lamp, the gab pressure has been filled by experience only roughly. The gas loss is converted into the radiation output. Therefore, the lamp efficacy is improved by reducing the gas loss.

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Ion Migration in Organic Metal Halide Perovskites (유기 금속 할라이드 페로브스카이트에서 이온 이동)

  • Oh, Ilwhan
    • Journal of the Korean Electrochemical Society
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    • v.21 no.2
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    • pp.21-27
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    • 2018
  • In this review, recent researches on ion transport phenomena in organic metal halide perovskite materials, which have been popular all over the world, are summarized. Although different results have been reported depending on the perovskite material composition and applied voltage, iodide seems to migrate under actual solar cell operating conditions, and occasionally methylammonium migration is observed. Perovskite is a so-called mixed conductor in which electrons and ions move simultaneously at room temperature, which greatly influences the hysteresis of the perovskite solar cell current-voltage curve and the performance degradation due to long-term operation.

The Development of the Buck Type Electronic Dimming Ballast for 250W MHL

  • Jung, Dong-Youl;Park, Chong-Yeon
    • Journal of Electrical Engineering and Technology
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    • v.1 no.4
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    • pp.496-502
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    • 2006
  • In this paper, we studied the development of the electronic ballast for 250W MH (Metal-Halide) lamps. We were able to improve the input power factor by using a PFC IC. To provide the lamp with the rated voltage required, we used the buck-type dc-dc converter. The stress of the switching devices in the inverter could be reduced by this method. To eliminate the acoustic resonance phenomena of MH lamps, the voltage of the lamp added the high frequency sine-wave to the low frequency square-wave by using the full bridge typed inverter. We have developed a simple igniter using the L and C elements. We could control the dimness of the lamp by varying the output voltage of the buck converter. The buck converter output voltage could be controlled by using a microprocessor.

Nucleophilic Displacement of Sulfur Center, Part Ⅵ - Halide Exchange Kinetics of Methanesulfonyl Chloride in Acetone, Acetonirile and Methanol

  • Lee, Ikchoon;Yie, Jae-Eui
    • Nuclear Engineering and Technology
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    • v.6 no.1
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    • pp.23-26
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    • 1974
  • The rates and activation parameters for the halide exchange reactions of methanesulfonyl chloride in dry acetone, acetonitrile, and methanol have been determined. It was found that nucleophilic order is Cl->Br->I-. The rate of chloride exchange with methanesulfonyl chloride decreases in the order of solvent; ($CH_3$)$_2$CO>$CH_3$CN》MeOH. Results are intrpreted in terms of easiness of the initial state desolvation and solvation stabilization of the transition state.

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A Optimal Design method for Dimmable Magnetic Ballast Design for Metal Halide Lamps (메탈핼라이드 램프용 조도제어형 자기식 안정기의 최적 설계 방법)

  • Park, Chong-Yeon;Lee, Hyeon-Jin
    • Journal of Industrial Technology
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    • v.29 no.A
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    • pp.177-182
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    • 2009
  • The inductor which is used at low frequency as the main part of magnetic ballast consists of an iron core, a bobbin and coil. The conventional inductor design method is not suitable for the magnetic ballast because it has various variables and is not a unique method for the magnetic ballast. Thus, this paper presents the optimal design method for a lamination type inductor using a magnetic ballast for Metal Halide Lamps. Also, the optimal inductor design method is researched for inductors of dimming ballasts and ignitors that have a gate-triggered structure using a SCR thyristor. By the simulation and experimental results, we showed that the proposed design methods is valid.

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The Ignitor Development for Momentary Restarting of Metal Halide Lamps (메탈 핼라이드 램프의 순시 재점등을 위한 점화기 개발)

  • Park, Chong-Yeun;Bae, Su-Ho
    • Journal of Industrial Technology
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    • v.20 no.B
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    • pp.169-174
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    • 2000
  • The most of metalhalide lamps is what the momentary restarting cannot be realized when the arc tube is in the hot condition. The discharge starting voltage of arc tube in the hot condition is much higher than in the cold condition in proportion to the gaseous pressure. Therefore it takes about ten minutes to restart the metal Halide lamps, that is to say, it is possible to start when the pressure and the temperature are decreased. But, if the lamp is restarted in the hot condition, we must supply the high voltage pulse with 15kV between the both electrodes of lamp. The proposed ignitor has two ignitors. If we connect each ignitor at the both sides, the high voltages of two different frequencies are generated. If so, when the one of the ignitor generates the highest voltage and the other applied to elecrodes of the lamp. In this way, we can restart the lamp with the voltage 15kV, even if the lamp is in the hot condition.

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