• 제목/요약/키워드: halide

검색결과 444건 처리시간 0.019초

Optical Characterization of Cubic and Pseudo-cubic Phase Perovskite Single Crystals Depending on Laser Irradiation Time

  • Byun, Hye Ryung;Jeong, Mun Seok
    • Applied Science and Convergence Technology
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    • 제27권2호
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    • pp.42-45
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    • 2018
  • Photovoltaic and optoelectronic devices based on hybrid metal halide perovskites ($MAPbX_3$; $MA=CH_3NH_3{^+}$, $X=Cl^-$, $Br^-$, or $I^-$) are rapidly improving in power conversion efficiency. Also, during recent years, perovskite single crystals have emerged as promising materials for high-efficiency photovoltaic and optoelectronic devices because of their low defect density. Here we show that the light soaking effect of mixed halide perovskite ($MAPbBr_{3-x}I_x$) single crystals can be explained using photoluminescence, time-resolved photoluminescence, and Raman scattering measurements. Unlike Br-based single crystal, Br/I mixed single crystal show a strong light soaking effect under laser irradiation condition that was related to the existence of multiple phases.

메탈 할라이드 램프 외관의 최적 봉착조건에 관한 연구 (A Study for Optimal filling Condition in Outer Enclosure of Metal Halide Lamp)

  • 지철근;이성진
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
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    • pp.296-299
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    • 1987
  • The purpose of this paper is to increase the lamp efficacy by filling the optimal Nitrogen gas pressure in the outer enclosure of metal halide lamp. This study presents a new model of Langmuir in the outer enclosure of discharge lamp. In this paper, in the first place, the diameter of Langmuir sheath and the total gab loss were calculated. Secondly, the each gas loss was computed if the arbitrary gas pressure is filled, With the calculated data, flash over which affects the lamp efficacy, lamp life and color rendering was considered. In case of the established discharge lamp, the gab pressure has been filled by experience only roughly. The gas loss is converted into the radiation output. Therefore, the lamp efficacy is improved by reducing the gas loss.

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유기 금속 할라이드 페로브스카이트에서 이온 이동 (Ion Migration in Organic Metal Halide Perovskites)

  • 오일환
    • 전기화학회지
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    • 제21권2호
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    • pp.21-27
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    • 2018
  • 본 총설에서는 최근 전세계적으로 각광 받고 있는 유기 금속 할라이드 페로브스카이트 소재에서 일어나는 이온 이동 현상에 대한 최신 연구에 대해 정리하였다. 페로브스카이트 물질 조성, 인가전압에 따라 다른 결과들이 보고되었지만, 실제 태양전지 작동 조건에서 iodide 가 이동하는 것으로 보이며, 때로는 methylammonium의 이동도 관찰된다. 페로브스카이트는 상온에서 전자와 이온이 동시에 이동하는 이른바 mixed conductor이고, 이는 페로브스카이트 태양전지 전류-전압곡선의 hysteresis, 장시간 작동에 따른 성능 저하 등에 지대한 영향을 미친다.

The Development of the Buck Type Electronic Dimming Ballast for 250W MHL

  • Jung, Dong-Youl;Park, Chong-Yeon
    • Journal of Electrical Engineering and Technology
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    • 제1권4호
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    • pp.496-502
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    • 2006
  • In this paper, we studied the development of the electronic ballast for 250W MH (Metal-Halide) lamps. We were able to improve the input power factor by using a PFC IC. To provide the lamp with the rated voltage required, we used the buck-type dc-dc converter. The stress of the switching devices in the inverter could be reduced by this method. To eliminate the acoustic resonance phenomena of MH lamps, the voltage of the lamp added the high frequency sine-wave to the low frequency square-wave by using the full bridge typed inverter. We have developed a simple igniter using the L and C elements. We could control the dimness of the lamp by varying the output voltage of the buck converter. The buck converter output voltage could be controlled by using a microprocessor.

Nucleophilic Displacement of Sulfur Center, Part Ⅵ - Halide Exchange Kinetics of Methanesulfonyl Chloride in Acetone, Acetonirile and Methanol

  • Lee, Ikchoon;Yie, Jae-Eui
    • Nuclear Engineering and Technology
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    • 제6권1호
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    • pp.23-26
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    • 1974
  • 염화 메탄 슬포닐의 할로겐 교환반응을 무수아세톤, 아세토니트릴, 메타놀 용매중에서 행하여 반응속도상수와 활성화파라메터를 구하였다. 친핵성도는 Cl->Br>I- 순서로 감소하였으며, 용매변화에 따른 염소이온과의 반응 속도는 ($CH_3$)$_2$CO>$CH_3$CN》$CH_3$OH의 순서로 감소하였다. 실험결과를 초기상태 탈용매화의 용이함과 천이상태 용매화의 안정성으로 설명하였다.

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메탈핼라이드 램프용 조도제어형 자기식 안정기의 최적 설계 방법 (A Optimal Design method for Dimmable Magnetic Ballast Design for Metal Halide Lamps)

  • 박종연;이현진
    • 산업기술연구
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    • 제29권A호
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    • pp.177-182
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    • 2009
  • The inductor which is used at low frequency as the main part of magnetic ballast consists of an iron core, a bobbin and coil. The conventional inductor design method is not suitable for the magnetic ballast because it has various variables and is not a unique method for the magnetic ballast. Thus, this paper presents the optimal design method for a lamination type inductor using a magnetic ballast for Metal Halide Lamps. Also, the optimal inductor design method is researched for inductors of dimming ballasts and ignitors that have a gate-triggered structure using a SCR thyristor. By the simulation and experimental results, we showed that the proposed design methods is valid.

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메탈 핼라이드 램프의 순시 재점등을 위한 점화기 개발 (The Ignitor Development for Momentary Restarting of Metal Halide Lamps)

  • 박종연;배수호
    • 산업기술연구
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    • 제20권B호
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    • pp.169-174
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    • 2000
  • The most of metalhalide lamps is what the momentary restarting cannot be realized when the arc tube is in the hot condition. The discharge starting voltage of arc tube in the hot condition is much higher than in the cold condition in proportion to the gaseous pressure. Therefore it takes about ten minutes to restart the metal Halide lamps, that is to say, it is possible to start when the pressure and the temperature are decreased. But, if the lamp is restarted in the hot condition, we must supply the high voltage pulse with 15kV between the both electrodes of lamp. The proposed ignitor has two ignitors. If we connect each ignitor at the both sides, the high voltages of two different frequencies are generated. If so, when the one of the ignitor generates the highest voltage and the other applied to elecrodes of the lamp. In this way, we can restart the lamp with the voltage 15kV, even if the lamp is in the hot condition.

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무전극 HID 램프의 색온도 감성평가에 관한 연구 (A Study on the Sensibility Evaluation on the Color Temperatures of Electrodeless HID Lamp)

  • 박현수;박병주;장우진
    • 조명전기설비학회논문지
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    • 제28권4호
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    • pp.9-15
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    • 2014
  • An experiment was carried out to evaluate the emotion and sensibility evoked from the different color temperatures(CCT) of electrodeless HID (ELHID) lamp. For this purpose, three ELHID lamps and a metal halide lamp were used as the experimental light sources and thirty Korean adjectives related to the lighting affectiveness were selected for the evaluation. The results showed that ELHID lamps induced different sensibilities according to their color temperature. In particular, 6500 K ELHID was similar to metal halide which has the CCT of 5600 K in the evaluation. Based on the results, we suggested some Korean adjectives and their corresponding English ones which are thought to be suitable for the verbal descriptions of ELHID lamps.

HID 램프 수명 연장을 위한 점화기 개발 (Development of the Igniter to Expand HID Lamp Life)

  • 조계현;송명석;박종연
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권7호
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    • pp.370-376
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    • 2004
  • The metal halide lamps are now widely used in the application and commercial lighting due to their attracting properties such as good color rendering and high efficiency. But, they have the serious problem of acoustic resonance for high frequency operation and they need the high voltage to ignite. So, they have not been applied to indoors. Over the past few years, a considerable number of studies have been conducted on the electronic ballast together with hot restarting and resonance phenomenon. But, Very few attempts have been made with the adaptive ignition method according to the lamp state. In this paper, electronic ballast is proposed for metal halide lamps with an igniter for adaptive ignition. The proposed electronic ballast can generate different ignition voltages according to the arc tube state.