Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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The Study for Surface Activity of Alkylquinolinium Halide Ⅰ. The Critical Micelle Concentration of Solution of Dodecylquinolinium Bromide

Alkylquinolinium Halide의 계면활성에 관한 연구 Ⅰ. Dodecylquinolinium Bromide 수용액의 Critical Micelle Concentration

  • 이종만 (고려대학교 이공대학 화학과)
  • Published : 1972.08.30
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Abstract

Dodecylquinolinium bromide has been synthesized and the critical micelle concentrations of it in the aqueous solution have been determined by the measurement of the surface tension and the electrical conductance. The values are $3.34 {\times} 10^{-3}mole/l$ and 3.41 {\times} $10^{-3}$mole/l, respectively. Since dodecylquinolinium bromide has the larger hydrophobic group than dodecylpyridinium bromide, it is considered that the former has the smaller critical micelle concentration than the latter.

새로히 합성한 dodecylquinolinium bromide의 수용액에서 표면장력과 전기전도도 측정치로 부터 critical micelle concentration을 결정하였다. 표면장력법으로 결정한 c.m.c.의 값은 $3.34 {\times} 10^{-3}mole/l$이고 전기전도도법으로 결정한 값은 3.41 {\times} $10^{-3}$mole/l이었다. 이값들은 dodecylpyridinium bromide의 그것보다 작은데 이는 dodecylquinolinium bromide의 소수성 group이 큰데서 오는 것으로 생각된다.

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