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Thermal properties in strong hydrogen bonding systems composed of poly(vinyl alcohol), polyethyleneimine, and graphene oxide

  • Choi, Sua;Hwang, Duck Kun;Lee, Heon Sang
    • Carbon letters
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    • v.15 no.4
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    • pp.282-289
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    • 2014
  • Blends of poly(vinyl alcohol) (PVA), polyethyleneimine (PEI), and graphene oxide (GO) were prepared by solution casting method. Calorimetric thermal properties of the blends were investigated. The $T_gs$ of PVA/PEI blends were higher than the $T_gs$ of either of the component polymers at low concentrations of PEI. These abnormal increases of $T_gs$ may be due to the negative entropy of mixing which is associated with strong hydrogen bonding between PVA and PEI. The degree of depression of $T^0_ms$ was not reduced by the negative entropy of mixing, since strong hydrogen bonding also causes an increase in the magnitude of negative ${\chi}$ between PVA and PEI. The $T_g$ of PVA was increased significantly by adding 0.7 wt.% GO into PVA. The magnitude of negative ${\chi}$ was increased by adding GO into the blends of PVA and PEI.

A Stop-and-Go Dual-Mode Modified Constant Modulus Algorithm for Adaptive Blind Equalization of High-Order QAM Signals (고밀도 광 기록 채널을 위한 터보 코드와 터보 등화기를 연접한 데이터 복호 방법)

  • 임창현;김기윤;김동규;최형진
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.6B
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    • pp.1074-1081
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    • 2000
  • In this paper, in order to speed up the convergence process and improve the steady mean square error simultaneously, we propose the Stop-and-Go Dual Mode Modified Constant Modulus Algorithm(SAG DM MCMA) for adaptive blind channel equalization of high order QAM. The proposed algorithm is a hybrid scheme of the Modified CMA that treat error signals with real and imaginary components of the equalizer output, the concept of dual mode CMA, and Stop-and-Go algorithm. As a result it can prevent blind equalization from converging to incorrect direction and simultaneously operates reliably for tap weight adaptation. We demonstrate via simulation that the proposed algorithm achieves lower steady state mean square error and residual ISI than the conventional algorithms under high order QAM signals and severe channel environment.

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Constructing Effective Code Analyzer to Measure the Quality of Blockchain Code based on Go Language (Go 언어 기반 블록체인 코드의 품질 검증을 위한 효율적인 정적분석기 개발)

  • An, Hyun-sik;Park, Jihoon;Park, Bokyung;Kim, R. Young-chul
    • Proceedings of the Korea Information Processing Society Conference
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    • 2019.10a
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    • pp.694-696
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    • 2019
  • 현재 4차 산업 혁명과 가상화폐에 대한 전 세계적인 관심으로 블록체인 시스템이 급부상하고 있다. 현재 구현중심인 국내외 블록체인 시장에서 무수히 많은 블록체인 기반 플랫폼들이 등장과 함께 오류가 발생하고 있다. 하지만 블록체인 시스템의 신뢰성, 확장성, 안정성 등에 대한 검증은 누구도 하고 있지 않다. 이런 문제 해결을 위해 Go language로 구성된 블록체인 코드를 분석할 수 있는 정적분석기를 통한 품질 가시화 방법을 제안한다. 이를 통하여 Blockchain Code의 내부 복잡도를 식별하고자한다. 즉, 코드 내부를 가시화하고 개발자가 보다 쉽게 코드를 유지보수 할 수 있으며 블록체인 시스템의 소프트웨어 공학적인 고품질화가 가능하다.

GO$_2$/Kerosene를 추진제로 하는 동축 인젝터의 화염 부상 특성에 관한 실험적 연구

  • Moon, Il-Yoon;Kim, Yoo;Park, Hee-Ho;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1999.04a
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    • pp.4-4
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    • 1999
  • 최근 충남대에서는 다양한 추진제와 연소 조건으로 액체로켓 연소 실험이 진행되고 있으며 그에 비례하여 많은 사고들이 발생하고 있다. 한 예로 GO$_2$/kerosene을 추진제로 하는 노즐삭마 시험용 로켓엔진(추력 1001bf, 연소실 압력 600psia) 개발 중에 화염이 인젝터면에 형성되어 인젝터면을 손상시키는 사고를 여러 번 경험하게 되었다. 본 연구는 인젝터 손상의 원인을 규명하여 안정적인 인젝터 설계에 도움을 주기 위한 목적으로 실험용 동축 인젝터를 제작하여 화염 부상 특성을 실험적으로 연구하였다. 사용된 인젝터는 연료인 Kerosene을 접선형 선회기로부터 90$^{\circ}$의 원뿔 각을 가지고 분무되도록 설계하였으며, 그 주위로 산하제인 GO$_2$가 연소실의 축방향에 수평하게 분무되도록 설계하였다. 2-유체 동축 인젝터의 난류 확산 화염에서 연료와 산화제의 혼합은 화염 특성을 결정하는 주요 변수이므로 인젝터로부터 분무되는 추진제간의 유량을 변화시켜 화염 부상 특성을 연구하였다.

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A Case Report of Intervention Strategy Applied ICF Tool about Patient with Cerebellar Hemorrhage (소뇌 출혈 환자에 대한 ICF Tool을 적용한 중재전략의 증례)

  • Kang, Tae-Woo;Park, Young-See
    • PNF and Movement
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    • v.11 no.2
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    • pp.1-7
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    • 2013
  • Purpose : The purpose of this study was to describe the Intervention strategy applied ICF Tool about patient with cerebellar hemorrhage. Methods : The data was collected by patient with cerebellar hemorrhage. We applied the ICF Tool for patient with cerebellar hemorrhage. Parameters of result were collected for using the Timed up and go test, Berg balance scale and ICF assessment sheet. Results : Significant differences were observed the patient for Timed up and go test, Berg balance scale and ICF assessment sheet. patient with cerebellar hemorrhage improved all test. Conclusion : ICF Tool applied Intervention about patient with cerebellar hemorrhage is very useful and effective. It is effective in clinical practice.

Highly sensitive gas sensor using hierarchically self-assembled thin films of graphene oxide and gold nanoparticles

  • Ly, Tan Nhiem;Park, Sangkwon
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.417-428
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    • 2018
  • In this study, we fabricated hierarchically self-assembled thin films composed of graphene oxide (GO) sheets and gold nanoparticles (Au NPs) using the Langmuir-Blodgett (LB) and Langmuir-Schaefer (LS) techniques and investigated their gas-sensing performance. First, a thermally oxidized silicon wafer ($Si/SiO_2$) was hydrophobized by depositing the LB films of cadmium arachidate. Thin films of ligand-capped Au NPs and GO sheets of the appropriate size were then sequentially transferred onto the hydrophobic silicon wafer using the LB and the LS techniques, respectively. Several different films were prepared by varying the ligand type, film composition, and surface pressure of the spread monolayer at the air/water interface. Their structures were observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM), and their gas-sensing performance for $NH_3$ and $CO_2$ was assessed. The thin films of dodecanethiol-capped Au NPs and medium-sized GO sheets had a better hierarchical structure with higher uniformity and exhibited better gas-sensing performance.

I Can't Believe Online: A Study on How Negative Reviews Move Online Shoppers to the Offline Channel

  • Kim, Hyo-jeong;Han, Sang man
    • Asia Marketing Journal
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    • v.24 no.1
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    • pp.13-28
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    • 2022
  • Despite the benefits of online shopping, we easily observe consumer behaviour when making purchases through offline channels. Why do they choose to go offline by taking the effort to go there? As a factor influencing decision-making, this study assumes that distrust of online shopping increases webrooming intentions that online consumers move to offline channels. Consumers check online reviews as well as seller information to increase their purchasing confidence. There are few studies on the effect of negative online reviews on consumers' purchasing decisions. Contrary to the pessimistic results of previous studies, the results of this study explain the mechanism by which consumers who saw negative online reviews feel distrust of online shopping and go to offline stores. It provides implications for understanding the migration phenomenon of online shoppers to offline channels and what strategies should be prepared to retain and attract customers to each channel.

Mechanical Properties of Epoxy Paints Containing Oxidized Graphene Nanoplatelet (산화 그래핀 나노플레이트릿을 혼입한 에폭시 도료의 역학적 특성)

  • Seo, Won-Woo;Kim, Gyu-Yong;Yoon, Min-Ho;Hwang, Eui Chul;Baek, Jae Uk;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.153-154
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    • 2017
  • Graphene is a nanomaterial and is known to have very high mechanical strength, thermal and electrical properties. However, graphene is known to be difficult to disperse among carbon-based materials due to van der Waals force. In this study, to solve the dispersion problem of graphene nanoplatelet, oxidized graphene nanoplatelet was prepared by oxidizing GNP in nitric acid. The prepared GO was dispersed in ethanol and distilled water before incorporation into the epoxy paint to confirm dispersibility. In addition, GNP/Epoxy and GO/Epoxy tensile specimens were prepared by mixing GNP and GO at 0.1, 0.3, 0.5 and 1.0 wt.% In epoxy coatings and tensile stress-strain characteristics were investigated.

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Transcriptomic Analysis of Triticum aestivum under Salt Stress Reveals Change of Gene Expression (RNA sequencing을 이용한 염 스트레스 처리 밀(Triticum aestivum)의 유전자 발현 차이 확인 및 후보 유전자 선발)

  • Jeon, Donghyun;Lim, Yoonho;Kang, Yuna;Park, Chulsoo;Lee, Donghoon;Park, Junchan;Choi, Uchan;Kim, Kyeonghoon;Kim, Changsoo
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.67 no.1
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    • pp.41-52
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    • 2022
  • As a cultivar of Korean wheat, 'Keumgang' wheat variety has a fast growth period and can be grown stably. Hexaploid wheat (Triticum aestivum) has moderately high salt tolerance compared to tetraploid wheat (Triticum turgidum L.). However, the molecular mechanisms related to salt tolerance of hexaploid wheat have not been elucidated yet. In this study, the candidate genes related to salt tolerance were identified by investigating the genes that are differently expressed in Keumgang variety and examining salt tolerant mutation '2020-s1340.'. A total of 85,771,537 reads were obtained after quality filtering using NextSeq 500 Illumina sequencing technology. A total of 23,634,438 reads were aligned with the NCBI Campala Lr22a pseudomolecule v5 reference genome (Triticum aestivum). A total of 282 differentially expressed genes (DEGs) were identified in the two Triticum aestivum materials. These DEGs have functions, including salt tolerance related traits such as 'wall-associated receptor kinase-like 8', 'cytochrome P450', '6-phosphofructokinase 2'. In addition, the identified DEGs were classified into three categories, including biological process, molecular function, cellular component using gene ontology analysis. These DEGs were enriched significantly for terms such as the 'copper ion transport', 'oxidation-reduction process', 'alternative oxidase activity'. These results, which were obtained using RNA-seq analysis, will improve our understanding of salt tolerance of wheat. Moreover, this study will be a useful resource for breeding wheat varieties with improved salt tolerance using molecular breeding technology.