• Title/Summary/Keyword: gel materials

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Manufacturing and Characterization of Organic-Inorganic Hybrid Coating Film Using Sol-Gel Method (Sol-Gel법을 이용한 유무기 하이브리드 코팅막 제조 및 특성평가)

  • Seungwon Cho;Dabin Kim;Ji-Sun Lee;Dongwook Shin;Jinho Kim
    • Korean Journal of Materials Research
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    • v.34 no.9
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    • pp.439-447
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    • 2024
  • Organic-inorganic hybrid coating films have been used to increase the transmittance and enhance the physical properties of plastic substrates. Sol-gel organic-inorganic thin films were fabricated on polymethylmethacrylate (PMMA) substrates using a dip coater. Metal alkoxide precursor tetraethylsilicate (TEOS) and alkoxy silanes including decyltrimethoxysilane (DTMS), 3-glycidoxypropyltrimethoxysilane (GPTMS), phenyltrimethoxysilane (PTMS), 3-(trimethoxysilyl)propyl methacrylate (TMSPM) and vinyltrimethoxysilane (VTMS) were used to synthesize sol-gel hybrid coating solutions. Sol-gel synthesis was confirmed by the results of FT-IR. Cross-linking of the Si-O-Si network during synthesis of the sol-gel reaction was confirmed. The effects of each alkoxy silane on the coating film properties were investigated. All of the organic-inorganic hybrid coatings showed improved transmittance of over 90 %. The surface hardness of all coating films on the PMMA substrate was measured to be 4H or higher and the average thickness of the coating films was measured to be about 500 nm. Notably, the TEOS/DTMS coating film showed excellent hydrophobic properties, of about 97°.

Viologen Based All-in-one Flexible Electrochromic Devices (바이올로진 기반의 일체형 유연 전기변색소자)

  • Park, Bo-Seong;Kim, Hyun-Jeong;Shin, Hyeonho;Park, Seongmin;Lee, Jaeun;Jeon, Sunggun;Nah, Yoon-Chae
    • Korean Journal of Materials Research
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    • v.31 no.3
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    • pp.132-138
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    • 2021
  • Electrochromic devices (ECDs) have been drawing great attention due to their high color contrast, low power consumption, and memory effect, and can be used in smart windows, automatic dimming mirrors, and information display devices. As with other electronic devices such as LEDs (light emitting diodes), solar cells, and transistors, the mechanical flexibility of ECDs is one of the most important issue for their potential applications. In this paper, we report on flexible ECDs (f-ECDs) fabricated using an all-in-one EC gel, which is a mixture of electrolyte and EC material. The f-ECDs are compared with rigid ECDs (r-ECDs) on ITO glass substrate in terms of color contrast, coloration efficiency, and switching speed. It is confirmed that the f-ECDs embedding all-in-one gel show strong blue absorption and have competitive EC performance. Repetitive bending tests show a degradation of electrochromic performance, which must be improved using an optimized device fabrication process.

Luminescence properties of Er/PbS encapsulated by phenyl modified silica via Sol-Gel Process (Phenyl modified silica에 졸-겔 캡슐화 된 Er/PbS의 발광 특성)

  • Ham, Gyeong-Guk;Ahn, Bok-Yeop;Seok, Sang-Il
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.146-146
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    • 2003
  • If rare earth ions could be activated by electrical means after introducing into an appropriate semiconductor host, it might be possible to achieve the electrically-driven optical amplifier. Futhermore, some groups report that rare earth doped semiconductor nanoparticls show the sensitized emission. In this study, we try to prepare the Er/PbS nanoparticles encaupsulated by phenyl modified silica shell via sol-gel process. Er/PbS nanoparticles were characterized by UV-vis absorption, XRD, FT-IR and TEM etc. Finally we will present the luminescence properties of Er doped PbS nanoencapsulation.

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Spectroscopic characterization of electroluminescent ZnS:Cu,Cl phosphor coated by sol-gel process

  • Lee, You-Hui;Han, Chi-Hwan;Han, Sang-Do;Chang, Mi-Youn;Sharma, Gaytri.;Park, Youn-Bong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1323-1326
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    • 2005
  • The photoluminescence, electroluminescence and surface properties of ZnS:Cu,Cl phosphor coated by sol-gel process were studies. Na-silicate was used as precursor coating material. pH of solution and the concentration of Na-silicate are the important conditions to obtain the uniform coating on the phosphors. Also, the electroluminescent devices were made with Na-silicate coated phosphor. The spectroscopic characterization is performed by photospectrometer.

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Sol-Gel Derived Nitrogen-Doped TiO2 Photoanodes for Highly Efficient Dye-Sensitized Solar Cells

  • Kim, Sang Gyun;Ju, Myung Jong;Choi, In Taek;Choi, Won Seok;Kim, Hwan Kyu
    • Rapid Communication in Photoscience
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    • v.3 no.1
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    • pp.20-24
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    • 2014
  • N-doped anatase $TiO_2$ nanoparticles were prepared by the sol-gel process followed by a hydrothermal treatment and successfully used as the photoanodes in organic dye-sensitized solar cells (DSSCs). As expected, the power conversion efficiency (PCE) of 8.44% was obtained for the NKX2677/HC-A-sensitized DSSC based on the 30 mol% N-doped $TiO_2$ photoanode, which was an improvement of 23% relative to that of the DSSC based on the NKX2677/DCA.

Influence of Compositions on Sol-Gel Derived Amorphous In-Ga-Zn Oxide Semiconductor Transistors

  • Kim, Dong-Jo;Koo, Chang-Young;Song, Keun-Kyu;Jeong, Young-Min;Moon, Joo-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1586-1589
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    • 2009
  • We investigated the influence of chemical compositions of gallium and indium cations on the performance of solgel derived amorphous gallium indium zinc oxide (a-GIZO) based thin-film transistors (TFTs). Systematical composition study allows us to understand the solutionprocessed a-GIZO TFTs. Understanding of the compositional influence can be utilized for tailoring the solution processed amorphous oxide TFTs for the specific applications.

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Shape-Stabilized Phase Change Materials : Frozen Gels From Polypropylene and n-Paraffin for Latent Heat Storage

  • Ko, Jae-Wang;Son, Tae-Won
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2010.03a
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    • pp.80-81
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    • 2010
  • We prepared polymer-PCM gels such as prepared frozen gel from polypropylene and n-Paraffin for thermal storage and release materials, their basic properties and possible applications especially in latent heat storage. The preparation methods are used to melting method and absorption method respectively. The composition and properties of prepared frozen gels from polypropylene and n-Paraffin were observed by DSC, FT-IR spectra, ARES and Elemental analysis. We can prepare frozen gels in different temperature for latent heat storage materials as controlling composition of phase change material as well as using different incorporating phase change materials. These frozen gels can be used to latent heat storage materials for several applications.

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