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Hydration Properties of Ordinary Portland Cement Using Mixture of Limestone and Blast Furnace Slag as Minor Inorganic Additives (소량 혼합재로서 석회석과 고로슬래그를 복합 사용한 보통 포틀랜드 시멘트의 수화특성)

  • Lee, Seung-Heun;Lim, Young-Jin;Cho, Jae-Woo
    • Journal of the Korea Concrete Institute
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    • v.27 no.1
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    • pp.3-9
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    • 2015
  • In this study, hydration properties of ordinary Portland cement were examined, shown from a limestone and blast furnace slag alone or their mixture up to 10% as a minor mineral additives. As of setting time, it was identified that final setting became faster as the amount of limestone mixture increased, which showed limestone accelerated early hydration faster than blast furnace slag. This is because limestone did accelerate the hydration of alite. At the age of 3 days, limestone 5%-blast furnace slag 5% mixture had the highest compressive strength of mortar. It is because hydration acceleration of alite by limestone, and $Ca(OH)_2$ that was additionally formed by hydration acceleration of alite reacted with blast furnace slag, and as a result, additionally created C-S-H hydrate. Regarding the hydration properties by the age of 7 and 28 days, limestone 3%-blast furnace slag 7% of composited mixture showed the largest compressive strength, and in comparison with the 3 days in curing age. This period is when hydration reaction of blast furnace slag is active and the amount of hydrate depends on the amount of blast furnace slag mixture more than that of the limestone mixture. And in order to vitalize hydration reaction of blast furnace slag the amount of $Ca(OH)_2$ created has to increase, and thus, a small amount of limestone is necessary that can accelerate the hydration of alite. Therefore, after the age of 7 days, the fact that there were a large amount of blast furnace slag mixture and small amount of limestone mixture was effective to the strength development of ordinary Portland cement.

A Photoreflectance Study of ArF Excimer Laser Annealing and Furnace Annealing (n-GaAs 구조에서의 ArF excimer laser annealing에 따른 Photoreflectance 특성 연구)

  • Kim, Ki-Hong;Yu, Jae-In;Sim, Jun-Hyoung;Bae, In-Ho;Lim, Jin-Hwan;Kim, Jin-Hi;Yu, Jae-Yong
    • Journal of the Korean Vacuum Society
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    • v.16 no.2
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    • pp.141-144
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    • 2007
  • We investigated variation of the photoreflectance(PR) signals for n-GaAs furnace and laser annealed. The samples were annealed by using ArF excimer laser(5 min, $30{\sim}50\;W$) and furnace(5 min $400{\sim}700^{\circ}C$). The PR signals(top point) measured from the ArF excimer laser annealed sample showed 1.42 eV and furnace annealed sample showed 1.43 eV. This result is ArF excimer laser annealed sample was uniform annealed surface and inter state.

Harmonics Analysis for Electric Arc Furnace According to the Operation Condition (전기 아크로 운전 상태에 따른 고조파 해석)

  • Kim, Jae-Chul;Park, Kyung-Ho;Park, Hyun-Teak;Moon, Jong-Fil;Im, Sang-Kug;Son, Hag-Sig
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.5
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    • pp.118-125
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    • 2004
  • The use of electric arc furnace has been increasing as the steel consumption is increasing and the operation technique of electric arc furnace are developing. But as the use of electric arc furnace is increased, the furnace have produced the adverse effects of power quality: voltage and current harmonics, voltage and current imbalances, low power factor, and voltage flicker. One of the power quality problems, the harmonic have the characteristics of the time-varying and non-linear. This paper analyzed the harmonics for the various operation conditions of electric arc furnace. The power system model with electric arc furnace have been made, and the harmonic's effects on the power system has been analyzed according to the various operating conditions, first melting, second melting, so on. Also, the filter reducing the harmonic components have been designed and its effects on the power system have been examined.

Numerical Simulation of 3-Dimensional Fluid Flow and Dust Concentrations in a Steel Foundry (제강 작업장내 삼차원 유동장 및 먼지농도의 수치 모사)

  • Cho, Hyun-Ho;Hong, Mi-Ok;Cho, Seog-Yeon
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.35-41
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    • 2006
  • The steel foundries with electric arc furnaces handling metal scraps have recently gained an attention as a potential source of dusts. The present study focuses on the analysis of dust emissions and removals during furnace charging and melting processes by commercial CFD software named FLUENT. A body fitted grid system consisting of 880,000 meshes was first generated by Gambit for the electric arc furnace with the capacity of 60 ton/cycle and then FLUENT was invoked to solve the corresponding NavierStokers equation for the momentum, temperature and dust concentration. The entire processes from metal charging to metal melting were simulated to investigate the unsteady behaviors of fluid flows and dust concentrations. The model simulation results showed that as the top of the electric arc furnace opened for metal charging, hot plumes bursted out from the furnace rose strongly by buoyance and escaped mostly through the main hood. Therefore, the capacity of main hoods determined the vent efficiency in the metal charging process. As the furnace was closed after the metal charging and the metal melting processes was followed, the hot flow stream stretching from the furnace to the main hood was dissipated fast and the flow from the inlet of the bottom of the left hand side to the main and monitoring hoods constituted the main stream. And there was only a slow flow in the right hand side of the furnace. Therefore, the dust concentrations were calculated higher in the left hand side of the furnace, which was consistent with observations.

The Effects of Various Burner Array on Workpiece and Gas Temperature in a Continuous Reheating Furnace (연속식 가열로에서 버너배열에 따른 소재 및 가스온도의 영향)

  • Kim, Kang-Min;Jeon, Chung-Hwan;Yoo, In;Kim, Gyu-Bo
    • Journal of Energy Engineering
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    • v.26 no.2
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    • pp.23-31
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    • 2017
  • Numerical study was conducted for the effects of various burner array on the workpiece and the gas temperature in a continuos reheating furnace. Under the same conditions which were the total heat of combustion, the heat capacity of unit burner, the number of burner and burner array were changed to be applied the furnace. The behavior of workpiece temperature and gas temperature in a furnace were evaluated for the effects as function of the changed conditions. A continuous reheating furnace designed for 110 tons/day of production capacity was applied in this study. The furnace which has several gas burners is designed to heat a workpiece. By this study, the better condition was confirmed than the existing designed condition.

The basic study for the proposal standard of Nano-Slag on an alternation material for Silica-fume (실리카퓸 대체 재료로서 나노슬래그의 규격제안을 위한 기초적 연구)

  • Heo, Jae-Won;Im, Nam-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.67-71
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    • 2008
  • Blast Furnace slag a pigiron waste that is produced more than 800 thousand tons per year, and micronized double quenching blast furnace slag improves flexibility of concrete, and even shows improvement effect of long-term intensity. However, the concrete that used micronized double quenching blast furnace slag is restricted in its use because of many problems to assure early intensity. Even micronized blast furnace slag can assure its early intensity of concrete when maximizing, and is considered that can be applied in high strength of blast furnace slag as an alternation material for Silica-fume that depends on overall import. Hereby this paper is revised activity index and fluidity of mortar that used Nano Slag that is produced by rotten Nano crush equipment to propose its size, and possible utility of Nano Slag that was produced by blast furnace slag made in Korea as an alternation material, with the conclusion as following. 1. To measure micronized Nano slag, it is judged that it should be in progress with BET method that is based on micronized Silica-fume for concrete. 2. As a result, the test based on KS L ISO 679 is shown to satisfy the basic additive size of KS F 2563 and of KS F 2567, and to determine new combination of stipulations. 3. The strength development of Nano Slag was shown excellent in the daily initial installment of 1, 3, 7 days against the basic additive. This is judged that contains CaO controlling initial strength against Silica-fume, and contributes to higher fineness than the basic blast furnace slag 1 type.

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Study on the In-Furnace Desulfurization for Oxy-Fuel Combustion Flue Gases Using Drop Tube Furnace (Drop Tube Furnace를 이용한 순산소연소 배가스 로내탈황에 관한 연구)

  • An, Young-Mo;Jo, Hang-Dae;Choi, Won-kil;Park, Yeong-Sung;Keel, Sang-In;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.512-517
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    • 2009
  • $SO_2$ concentrations in oxy-fuel combustion flue gases increases about three times as high as that of conventional air combustion system owing to the flue gas recirculation for the control of combustion temperature. So the desulfurization reaction is different from that of the conventional air combustion system due to exceptionally high $CO_2$ and $SO_2$ concentration. In this study, drop tube furnace(DTF) system was used to investigate the desulfurization characteristics of limestone in oxy-fuel combustion furnace. The experiments were performed under $O_2/CO_2$ atmosphere to examine the effect of operating variables such as reaction temperatures, Ca/S ratios and inlet $SO_2$ concentrations on the $SO_2$ removal efficiencies. $SO_2$ removal efficiency increased with reaction temperature, Ca/S ratio and inlet $SO_2$ concentration. And the addition of water vapor resulted in about 4~6% of increase in $SO_2$ removal efficiency.

Statistical Analysis of the Physical Properties in a Slag-OPC-Gypsum System as a Compound Mixing Ratio

  • You, Kwang-Suk;Lee, Kyung-Hoon;Han, Gi-Chun;Kim, Hwan;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.44 no.9
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    • pp.477-482
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    • 2007
  • The effect of the mixing ratio of compounds in a slag-OPC-Gypsum system on the physical properties of Slag cement is investigated in this study. $Na_2SO_4$ was used as an alkali activator. Blast furnace slag cement was prepared from a mixture of blast furnace slag, ordinary Portland cement and anhydride gypsum. The fluidity and the compressive strength according to the ratio of each mixture were analyzed in statistical analyses in order to discover the parameters influencing the fluidity and compressive strength. The results showed that the hydration of blast furnace slag took place with the addition of $Na_2SO_4$ and that column-crystalline ettringite was created as the main hydration product of the blast furnace slag. In addition, it was found that the compressive strength of blast furnace slag cement tends to increase when the ordinary Portland cement content is higher up to three days. However, it is known that the compressive strength tends to increase as the blast furnace slag content becomes higher with increases in the level of OPC after 28 days. As a result of this analysis, it is believed that the ordinary Portland cement content influences the initial compressive strength of blast furnace slag cement, and that in later days this is highly influenced by the slag content.

Properties of Reaction Rim on Blast Furnace Slag Grain with Alkali Activator according to Hydration Reaction (알칼리 자극제(刺戟劑)에 의해 고로(讀爐) 수쇄(水碎) 슬래그의 주위(周圍)에 형성(形成)된 Reaction Rim의 특성(特性))

  • Lee, Seung-Heun;Mun, Young-Bum
    • Resources Recycling
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    • v.18 no.3
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    • pp.42-48
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    • 2009
  • Since there are $OH^-,\;[SiO_4]^{4-}$ ion of high concentration at early hydration in the system added with activator (NaOH+$Na_2OSiO_2$) in the blast furnace slag, different from cement hydration, hydration progresses fast without induction period and forms reaction rim around the blast furnace slag grain. $0.6{\mu}m$ reaction rim was formed around the blast furnace slag grain from the 1 day of reaction period, and the thickness of reaction rim increases over the reaction time, growing to $1{\mu}m$ on the 28 days. Unreacted blast furnace slag grain deformed from angular shape to the spherical shape. Mole ratio of Ca/Si tends to decrease from inside of blast furnace slag grain to reaction rim. Difference of Ca/Si mole ratio between reaction rim and inside the blast furnace slag grain decreased and generated hydrate was a poor crystalline CSH(I) with Ca/Si mole ratio less than 1.5.

A Study on Kinetic of Volatilization Behavior of Metal Elements Contained in Electric Arc Furnace Dust (전기로 제강분진에 함유된 금속원소의 휘발거동에 대한 속도론적 연구)

  • Yoon, Jaehong;Yoon, Chihyun;Lee, Myungwon
    • Resources Recycling
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    • v.26 no.3
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    • pp.17-25
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    • 2017
  • Electric arc furnace steelmaking dust has various physicochemical properties as volatile components generated in the melting process of steel scraps in an electric arc furnace, which is captured in oxide form as fine powder by reacting with oxygen in the air. In order to efficiently recycle these electric arc furnace dust, a kinetic basic experiment and a pilot production test were carried out in parallel. As a result, it was found that the electric arc furnace dust contain a large amount of Cl and alkali components, thus it was expected that the compounds have a great adverse effect on the actual operation for the recycling. It was confirmed that the volatilization behavior was progressing actively at $1100^{\circ}C$ and the electric arc furnace dust was melted at $1250^{\circ}C$. These results are the same as a result of pilot test for the formation behavior of zinc oxide and reduced iron. These results should be useful as basic data for designing the recycling plant of the electric arc furnace dust and establishing the operating conditions.