• Title/Summary/Keyword: fuel cell system

Search Result 1,369, Processing Time 0.033 seconds

Electricity Generation and De-contamination Effect for Characteristic Electrode Material in a Microbial Fuel Cell System Using Bay Sediment (MFC의 금속 및 탄소전극에 의한 전기생산 특성과 오염저감 효과)

  • Kwon, Sung-Hyun;Song, Hyung-Jin;Lee, Eun-Mi;Cho, Dae-Chul;Rhee, In-Hyoung
    • Journal of Environmental Science International
    • /
    • v.19 no.8
    • /
    • pp.951-960
    • /
    • 2010
  • Sediment works as a resource for electric cells. This paper was designed in order to verify how sediment cells work with anodic material such as metal and carbon fiber. As known quite well, sediment under sea, rivers or streams provides a furbished environment for generating electrons via some electron transfer mechanism within specific microbial population or corrosive oxidation on the metal surfaces in the presence of oxygen or water molecules. We experimented with one type of sediment cell using different anodic material so as to attain prolonged, maximum electric power. Iron, Zinc, aluminum, copper, zinc/copper, and graphite felt were tested for anodes. Also, combined type of anodes-metal embedded in the graphite fiber matrix-was experimented for better performances. The results show that the combined type of anodes exhibited sustainable electricity production for ca. 600 h with max. $0.57\;W/m^2$ Al/Graphite. Meanwhile, graphite-only electrodes produced max. $0.11\;W/m^2$ along with quite stationary electric output, and for a zinc electrode, in which the electricity generated was not stable with time, therefore resulting in relatively sharp drop in that after 100 h or so, the maximum power density was $0.64\;W/m^2$. It was observed that the corrosive reaction rates in the metal electrodes might be varied, so that strength and stability in the electric performances(voltage and current density) could be affected by them. In addition to that, COD(chemical oxygen demand) of the sediment of the cell system was reduced by 17.5~36.7% in 600 h, which implied that the organic matter in the sediment would be partially converted into non-COD substances, that is, would suggest a way for decontamination of the aged, anaerobic sediment as well. The pH reduction for all electrodes could be a sign of organic acid production due to complicated chemical changes in the sediment.

A Study on Power Trading Methods for in a Hydrogen Residential Model (수소주거모델의 전력 거래 참여 방안 고찰)

  • KISEOK JEONG;TAEYOUNG JYUNG
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.34 no.2
    • /
    • pp.91-99
    • /
    • 2023
  • Participation in power trading using surplus power is considered a business model active in the domestic energy trade market, but it is limited only if the legal requirements according to the type, capacity, and use of the facilities to be applied for are satisfied. The hydrogen residential demonstration model presented in this paper includes solar power, energy storage system (ESS), fuel cell, and water electrolysis facilities in electrical facilities for private use with low-voltage power receiving system. The concept of operations strategy for this model focuses on securing the energy self-sufficiency ratio of the entire system, securing economic feasibility through the optimal operation module installed in the energy management system (EMS), and securing the stability of the internal power balancing issue during the stand-alone mode. An electric facility configuration method of a hydrogen residential complex demonstrated to achieve this operational goal has a structure in which individual energy sources are electrically connected to the main bus, and ESS is also directly connected to the main bus instead of a renewable connection type to perform charging/discharging operation for energy balancing management in the complex. If surplus power exists after scheduling, participation in power trading through reverse transmission parallel operation can be considered to solve the energy balancing problem and ensure profitability. Consequentially, this paper reviews the legal regulations on participation in electric power trading using surplus power from hydrogen residential models that can produce and consume power, gas, and thermal energy including hybrid distributed power sources, and suggests action plans.

Unraveling Biohydrogen Production and Sugar Utilization Systems in the Electricigen Shewanella marisflavi BBL25

  • Sang Hyun Kim;Hyun Joong Kim;Su Hyun Kim;Hee Ju Jung;Byungchan Kim;Do-Hyun Cho;Jong-Min Jeon;Jeong-Jun Yoon;Sang-Hyoun Kim;Jeong-Hoon Park;Shashi Kant Bhatia;Yung-Hun Yang
    • Journal of Microbiology and Biotechnology
    • /
    • v.33 no.5
    • /
    • pp.687-697
    • /
    • 2023
  • Identification of novel, electricity-producing bacteria has garnered remarkable interest because of the various applications of electricigens in microbial fuel cell and bioelectrochemical systems. Shewanella marisflavi BBL25, an electricity-generating microorganism, uses various carbon sources and shows broader sugar utilization than the better-known S. oneidensis MR-1. To determine the sugar-utilizing genes and electricity production and transfer system in S. marisflavi BBL25, we performed an in-depth analysis using whole-genome sequencing. We identified various genes associated with carbon source utilization and the electron transfer system, similar to those of S. oneidensis MR-1. In addition, we identified genes related to hydrogen production systems in S. marisflavi BBL25, which were different from those in S. oneidensis MR-1. When we cultured S. marisflavi BBL25 under anaerobic conditions, the strain produced 427.58 ± 5.85 µl of biohydrogen from pyruvate and 877.43 ± 28.53 µl from xylose. As S. oneidensis MR-1 could not utilize glucose well, we introduced the glk gene from S. marisflavi BBL25 into S. oneidensis MR-1, resulting in a 117.35% increase in growth and a 17.64% increase in glucose consumption. The results of S. marisflavi BBL25 genome sequencing aided in the understanding of sugar utilization, electron transfer systems, and hydrogen production systems in other Shewanella species.

Hydrogen Supply to PEMFC for Unmanned Aero Vehicles Using Hydrolysis Reaction of NaBH4 (NaBH4 가수분해 반응에 의한 무인항공기용 PEMFC 수소공급)

  • Jung, Hyeon-Seong;Jo, Byung-Joo;Lee, Jung-Hoon;Lee, Han-Jong;Na, Il-Chai;Chu, Cheun-Ho;Park, Kwon-Pil
    • Korean Chemical Engineering Research
    • /
    • v.54 no.1
    • /
    • pp.11-15
    • /
    • 2016
  • Proton Exchange Membrane Fuel Cells (PEMFC) instead of batteries is appropriate for long time flight of unmanned aero vehicles (UAV). In this work, $NaBH_4$ hydrolysis system supplying hydrogen to PEMFC was studied. In order to decrease weight of $NaBH_4$ hydrolysis system, enhancement of hydrogen yield, recovery of condensing water and maintenance of stable hydrogen yield were studied. The hydrogen yield of 3.4% was increased by controlling of hydrogen pressure in hydrolysis reactor. Condensing water formed during air cooling of hydrogen was recovered into storage tank of $NaBH_4$ solution. In this process the condensing water dissolved $NaBH_4$ powder and then addition of $NaBH_4$ solution decreased system weight of 14%. $NaBH_4$ hydrolysis system was stably operated with hydrogen yield of 96% by 2.0g Co-P-B catalyst for 10 hours at 2.0L/min hydrogen evolution rate.

An Experimental Study on the Combustion Characteristics of a Catalytic Combustor for an MCFC Power Generation System (MCFC 발전시스템용 촉매연소기의 연소 특성에 관한 실험적 연구)

  • Hong, Dong-Jin;Ahn, Kook-Young;Kim, Man-Young
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.36 no.4
    • /
    • pp.405-412
    • /
    • 2012
  • In the MCFC power generation system, the combustor supplies a high temperature mixture of gases to the cathode and heat to the reformer by using the off-gas from the anode; the off-gas includes high concentrations of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and avoid local heating, a catalytic combustor is usually adopted. Catalytic combustion is also generally accepted as one of the environmentally preferred alternatives for generation of heat and power from fossil fuels because of its complete combustion and low emissions of pollutants such as CO, UHC, and $NO_x$. In this study, experiments were conducted on catalytic combustion behavior in the presence of Pd-based catalysts for the BOP (Balance Of Plant) of 5 kW MCFC (Molten Carbonate Fuel Cell) power generation systems. Extensive investigations were carried out on the catalyst performance with the gaseous $CH_4$ fuel by changing such various parameters as $H_2$ addition, inlet temperature, excess air ratio, space velocity, catalyst type, and start-up schedule of the pilot system adopted in the BOP.

Numerical Analysis of Molten Carbonate Fuel Cell Stack Using Computational Fluid Dynamics (CFD를 이용한 용융탄산염 연료전지 스택의 수치모사)

  • Lee, Kab-Soo;Cho, Hyun-Ho
    • Journal of the Korean Electrochemical Society
    • /
    • v.8 no.4
    • /
    • pp.155-161
    • /
    • 2005
  • In this paper, commercial CFD program FLUENT v5.3 is used for simulation of MCFC stack. Besides using conservation equations included in FLUENT by default, mass change, mole fraction change and heat added or removed due to electrochemical reactions and water gas shift reaction are considered by adding several equations using user defined function. The stacks calculated are 6 and 25 kW class coflow stack which are composed of 20 and 40 unit cells respectively. Simulation results showed that pressure drop took place in the direction of gas flow, and the pressure drop of cathode side is more larger than that of anode side. And the velocity of cathode gas decreased along with the gas flow direction, but the velocity of anode gas increased because of the mass and volume changes by the chemical reactions in each electrodes. Simulated temperature profile of the stack tended to increase along with the gas flow direction and it showed similar results with the experimental data. Water gas shift reaction was endothermic at the gas inlet side but it was exothermic at the outlet side of electrode respectively. Therefore water gas shift reaction played a role in increasing temperature difference between inlet and outlet side of stack. This results suggests that the simulation of large scale commercial stacks need to consider water gas shift reaction.

Transmission Characteristics on Wire-Driven Links of a Bridge Transported Servo Manipulator for the ACP Equipment Maintenance (사용후핵연료 차세대관리 공정장치 유지보수용 천정이동 서보 매니퓰레이터 와이어 구동부 동작특성)

  • 박병석;진재현;송태길;김성현;윤지섭
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.2 no.3
    • /
    • pp.189-199
    • /
    • 2004
  • A bridge transported servo manipulator (BTSM) system for the advanced spent fuel conditioning process (ACP) has been developed to overcome the limitation of access, which is a drawback of mechanical master-slave manipulators (MSM) for the equipment maintenance. The servo manipulator is composed of a slave manipulator attached to the telescoping tubesets equipped with the overhead bridge installed at a hot cell and a master manipulator installed at an out-of-hot cell. Each manipulator has 7 degrees-of-freedom (DOF): a body rotation, an upper-arm tilt, a lower-arm tilt, a lower-arm rotation, a wrist pan & tilt, and a grasp motion. A wire-driven mechanism for a lower-arm rotation, a wrist pan and tilt, and a grasp motion of the manipulator has been adopted to increase the handling capacity compared to the manipulator weight and decrease the friction. The main disadvantage of the wire-driven mechanism is that if one link is in motion, other links can be affected. In this paper, the transmission characteristics among the wire-driven links have been formulated to overcome this drawback. The unexpected behaviors are confirmed by analyses of transmission characteristics as well as experiments. Also, the experimental results show that the unexpected behaviors are greatly decreased by the proposed compensation equations.

  • PDF

A study on the smoke control performance of the damper exhaust system at FCEV fire in tunnel for small vehicles (소형차 전용터널 내 수소연료전지차 화재시 집중배기방식의 제연성능에 관한 연구)

  • Hong, Seo-Hee;Baek, Doo-San
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.24 no.6
    • /
    • pp.745-756
    • /
    • 2022
  • The road tunnel is a semi-closed space that is blocked on all sides except the entrance and exit, and in the event of a fire, the smoke of the fire spreads longitudinally due to heat buoyancy caused by the fire and air currents that always exist in the tunnel. To solve this problem, smoke removal facilities are installed in road tunnels to secure a safe evacuation environment by controlling the direction of movement of smoke or directly smoking at fire points. In urban areas, the service level of urban roads decreases due to the increase in traffic due to the increase in population, and as a solution, the construction of underground roads in urban areas is increasing. When a fire occurs during hydrogen leakage through TPRD of a hydrogen fuel cell vehicle (FCEV), the fire intensity depends on the amount of leakage, and the maximum fire intensity depends on the orifice diameter of the TPRD. Considering the TPRD orifice diameter of 1.8 mm, this study analyzed the diffusion distance of fire smoke according to the wind speed of the roadway and the opening interval of the large exhaust port when the maximum fire intensity was 15 MW. As a result, it was analyzed that air flow in the tunnel could be controlled if the wind speed of the road in the tunnel was less than 1.25 m/s, and smoke could be controlled within 200 m from the fire if the damper interval was 50 m and 100 m.

FEA(Finite Element Analysis) Study for Electronic Hydrogen Regulator of Confidentiality Improvement (전자식 수소레귤레이터 기밀성 향상을 위한 FEA 연구)

  • Son, Won-Sik;Song, Jae-Wook;Jeon, Wan-Jae;Kim, Seung-Mo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.20 no.9
    • /
    • pp.175-181
    • /
    • 2019
  • In the case of a conventional single stage decompression regulator used for large depressurization in the hydrogen fuel cell system of a fuel cell electric vehicle (FCEV), problems can arise, such as pulsation, slow response, hydrogen brittleness, leakage, high weight, and high cost due to high decompression. Most of these problems can be overcome easily using two decompression mechanisms (two-stage structures). In addition, a wide outlet-pressure control range can be secured if an electronic solenoid is applied to the second decompression. Accordingly, it is necessary to improve the precision of the outlet pressure of a two-stage pressure-reducing regulator and develop techniques, such as leakage prevention, durability, light weight, and price reduction. Therefore, to improve the outlet pressure accuracy and prevent leakage, the structural part before and after decompression to improve the air tightness were divided and the analysis was carried out assuming that the valve part was closed (open ratio: 0%) after each initial internal pressure application.

A New Anti-Islanding Method for Utility Interconnection of Distributed Power Generation System (분산전원시스템의 계통연계를 위한 새로운 단독운전 방지기법)

  • Hwang In-Ho
    • The Transactions of the Korean Institute of Power Electronics
    • /
    • v.9 no.6
    • /
    • pp.568-576
    • /
    • 2004
  • This paper presents a new anti-islanding method for distributed power generation system (DPGS) using renewable energy. Based on the concept of real and reactive power mismatch, three different islanding conditions are analyzed. It is shown via analysis that islanding voltage is a function of real power alone, where as its frequency is a function of both real and reactive power. Using this analysis, a new anti-islanding method is developed. The proposed protection algorithm continuously perturbs ($\pm$5%) the reactive power supplied by DPGS while simultaneously monitoring the utility voltage and frequency. If a measurable frequency deviation took place by islanding, the real power of DPGS is further reduced to 80%. This detection method is shown to be fast acting under resonant loads. Possible islanding conditions are simulated and verified with analysis. Experimental results on a 0.5kW utility-interactive fuel cell system are suggested.