• Title/Summary/Keyword: fuel cell stack

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Analysis of the Homogenization of the Elastic Behavior for a Sheet with Sheared Protrusions using Hexahedral Mesh Coarsening (육면체 요소 재구성을 통한 개방형 사다리꼴이 성형된 판재의 탄성 거동 균질화에 대한 연구)

  • Lee, C.W.;Yang, D.Y.;Park, J.S.;Kang, D.W.
    • Transactions of Materials Processing
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    • v.23 no.3
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    • pp.171-177
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    • 2014
  • The current collector for the molten carbonate fuel cell (MCFC) which has sheared protrusions is manufactured by the three-stage forming process that integrates slitting, preforming and final forming. Due to the repetition of sheared protrusions, an effective simulation method is required to predict the mechanical behavior. In the current study, a sheet with sheared protrusions was assumed to be an orthotropic plate, which has the same length, width and height. FEM simulations were conducted to evaluate the homogenized properties of the current collector, which has 4 (longitudinal direction) x 4 (transverse direction) sheared protrusions. The simulation model was constructed using hexahedral mesh coarsening. From the verification examples, it was found that the proposed simulation method was efficient within reasonable accuracy. The calculated homogenized properties can be applied to the design of a stack for molten carbonate fuel cells and the prediction of mechanical behavior for other applications.

Finite Element Analysis of Surface Pressure of Hydrogen Fuel Cell Gasket (수소 연료전지 개스킷의 면압에 대한 유한요소 해석)

  • Jeon, Hyeong-Ryeol;Park, Soo-Hyun;Zoo, Woo-jung;Hur, Jang-Wook
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.6
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    • pp.60-66
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    • 2022
  • The optimal strain energy function was obtained by comparing the results of the analysis using the strain energy functions obtained by uniaxial tensile and equibiaxial tensile tests on gasket materials used in hydrogen fuel cells, with the results measured using a contact pressure measurement sensor. At this time, even when only the uniaxial tensile test was conducted, Yeoh could obtain the most accurate results even by conducting only the uniaxial tensile test. Using this, an analysis of the cross section of the gasket used in stack confirmed a safe contact pressure and no deformation on the separator. In the future, research will be conducted to verify the gasket durability by reliability evaluation.

A Basic Study on the Stress Field in the Electrode Interface of the Planar SOFC Single Cell (평판형 SOFC 단전지 전극계면에서 발생되는 응력장에 관한 기초적 연구)

  • Park, Chul Jun;Kwon, Oh Heon;Kang, Ji Woong
    • Journal of the Korean Society of Safety
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    • v.28 no.5
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    • pp.5-9
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    • 2013
  • Recently, eco-friendly sources of energy by fuel cells that use hydrogen as an energy source has emerged as the next generation of energy to solve the problem of environmental issues and exhaustion of energy. A solid oxide fuel cell(SOFC) classified based on the type of ion transfer mediator electrolyte has actively being researched. However, the reliability according to the thermal cycle is low during the operation of the fuel cell, and deformation problem comes from the difference in thermal expansion coefficient between the electrode material, the components made of ceramic material is also brittle, which means disadvantages in terms of the strength. Therefore, in this study, considering the states of the manufacturing and operating of SOFC single cells, the stress analyses in the each of the interfacial layer between the anode, electrolyte and the cathode were performed to get the basic data for reliability assessment of SOFC. The obtained results show that von Mises stress according to the thickness direction on operating state occurred maximum stress value in the electrolyte layer. And also the stresses inside the active area on a distance of 1 ${\mu}m$ from the electrode interface were estimated. Futhermore the evaluation was done for the variation of the stress according to the stage of the operation divided into three stages of manufacturing, stack, and operating.

Compounding and Test of Gasket Rubber for Fuel Cell Stack Application (연료전지 스택 가스켓용 고무재료의 제조와 평가)

  • Hur, Byung-Ki;Kang, Dong-Gug;Kim, Hye-Young;Seo, Kwan-Ho;Park, Lee-Soon
    • Elastomers and Composites
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    • v.42 no.4
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    • pp.232-237
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    • 2007
  • We examined the properties of compound and made compound of the optimum state using the properties of each material to evaluate suitability of FKM, VMQ, EPDM, NBR with gasket for fuel cell which is in general use with the material of gasket. It could be found from the compound made with setting the optimum state that NBR is worse than FKM in the chemical property of matter for a long term, and VMQ is worse than FKM in the elution of a metal ion, and EPDM is worse than FKM in the permeability of gas. As a result of leak evaluation of gasket for fuel cell with using FKM, it appeared leak in short time when contracting pressure is getting lower and sealing pressure is getting higher. And as a result of the life prediction with using Arrhenius model, we could predict that it is possible to continuously drive for 60,000 hours.

Well-to-Wheel Greenhouse Gas Emissions Analysis of Hydrogen Fuel Cell Vehicle - Hydrogen Produced by Naphtha Cracking (나프타 기반 수소 연료전지 자동차의 전과정 온실가스 발생량 분석)

  • Kim, Myoungsoo;Yoo, Eunji;Song, Han Ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.2
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    • pp.157-166
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    • 2017
  • The Fuel Cell Electric Vehicle(FCEV) is recently evolving into a new trend in the automobile industry due to its relatively higher efficiency and zero greenhouse gas(GHG) emission in the tailpipe, as compared to that of the conventional internal combustion engine vehicles. However, it is important to analyze the whole process of the hydrogen's life cycle(from extraction of feedstock to vehicle operation) in order to evaluate the environmental impact of introducing FCEV upon recognizing that the hydrogen fuel, which is used in the fuel cell stack, is not directly available from nature, but instead, it should be produced from naturally available resources. Among the various hydrogen production methods, ${\sim}54.1%^{8)}$ of marketed hydrogen in Korea is produced from naphtha cracking process in the petrochemical industry. Therefore, in this study, we performed a well-to-wheels(WTW) analysis on the hydrogen fuel cycle for the FCEV application by using the GREET program from the US Argonne National Laboratory with Korean specific data. As a result, the well-to-tank and well-to-wheel GHG emissions of the FCEV are calculated as 45,638-51,472 g $CO_2eq/GJ$ and 65.0-73.4 g $CO_2eq/km$, respectively

Stability of Metal-supported SOFC using Diesel Reformate (디젤 개질 가스로 운전되는 금속지지체형 고체산화물 연료전지의 운전 안정성에 관한 연구)

  • Jeong, Jihoon;Baek, Seung-Wook;Bae, Joongmyeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.78.1-78.1
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    • 2010
  • The metal-supported solid oxide fuel cell (SOFC) was studied. Hydrocarbon fueled operation is necessary to make SOFC system. Different operating characteristics for metal-supported SOFC are used than for conventional ones as hydrocarbon fueled operation. Metal-supported SOFC was successfully fabricated by a high temperature sinter-joining method and the cathode was in-situ sintered. Synthetic gas, which is compounded as the diesel reformate gas composition and low hydrocarbons was completely removed by the diesel reformer. Metal-supported SOFC with synthetic gas was operated and evaluated and its characteristics analyzed. Button cell and $5{\times}5cm^2$ single stack were mainly operated and analyzed. Long-term operation using diesel reformate shows degradation, and degradation analysis was completed in the view of metal oxidation. Solution to increase stability of long-term operation was tried in the way of materials and operating conditions. Finally, $5{\times}5cm^2$ metal-supported single stack using synthetic gas was operated for 1000 hours under the modified condition.

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A Study of Monitoring and Operation for PEM Water Electrolysis and PEM Fuel Cell Through the Convergence of IoT in Smart Energy Campus Microgrid (스마트에너지캠퍼스 마이크로그리드에서 사물인터넷 융합 PEM 전기분해와 PEM 연료전지 모니터링 및 운영 연구)

  • Chang, Hui Il;Thapa, Prakash
    • Journal of the Korea Convergence Society
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    • v.7 no.6
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    • pp.13-21
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    • 2016
  • In this paper we are trying to explain the effect of temperature on polymer membrane exchange water electrolysis (PEMWE) and polymer membrane exchange fuel cell (PEMFC) simultaneously. A comprehensive studying approach is proposed and applied to a 50Watt PEM fuel cell system in the laboratory. The monitoring process is carried out through wireless LoRa node and gateway network concept. In this experiment, temperature sensor measure the temperature level of electrolyzer, fuel cell stack and $H_2$ storage tank and transmitted the measured value of data to the management control unit (MCU) through the individual node and gateway of each PEMWE and PEMFC. In MCU we can monitor the temperature and its effect on the performance of the fuel cell system and control it to keep the lower heating value to increase the efficiency of the fuel cell system. And we also proposed a mathematical model and operation algorithm for PEMWE and PEMFC. In this model, PEMWE gives higher efficiency at lower heating level where as PEMFC gives higher efficiency at higher heating value. In order to increase the performance of the fuel cell system, we are going to monitor, communicate and control the temperature and pressure of PEMWE and PEMFC by installing these systems in a building of university which is located in the southern part of Korea.

Identification of Internal Resistance of Microbial Fuel Cell by Electrochemical Technique and Its Effect on Voltage Change and Organic Matter Reduction Associated with Power Management System (전기화학적 기법에 의한 미생물연료전지 내부저항 특성 파악 및 전력관리시스템 연계 전압 변화와 유기물 저감에 미치는 영향)

  • Jang, Jae Kyung;Park, Hyemin;Kim, Taeyoung;Yang, Yoonseok;Yeo, Jeongjin;Kang, Sukwon;Paek, Yee;Kwon, Jin Kyung
    • Journal of Biomedical Engineering Research
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    • v.39 no.5
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    • pp.220-228
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    • 2018
  • The internal resistance of microbial fuel cell (MFC) using stainless steel skein for oxidizing electrode was investigated and the factors affecting the voltage generation were identified. We also investigated the effect of power management system (PMS) on the usability for MFC and the removal efficiency of organic pollutants. The performance of a stack microbial fuel cell connected with (PMS) or PMS+LED was analyzed by the voltage generation and organic matter reduction. The maximum power density of the unit cells was found to be $5.82W/m^3$ at $200{\Omega}$. The maximum current density was $47.53A/m^3$ without power overshoot even under $1{\Omega}$. The ohmic resistance ($R_s$) and the charge transfer resistance ($R_{ct}$) of the oxidation electrode using stainless steel skein electrode, were $0.56{\Omega}$ and $0.02{\Omega}$, respectively. However, the sum of internal resistance for reduction electrode using graphite felts loaded Pt/C catalyst was $6.64{\Omega}$. Also, in order to understand the internal resistance, the current interruption method was used by changing the external resistance as $50{\Omega}$, $300{\Omega}$, $5k{\Omega}$. It has been shown that the ohm resistance ($R_s$) decreased with the external resistance. In the case of a series-connected microbial fuel cell, the reversal phenomenon occurred even though two cells having the similar performance. However, the output of the PMS constantly remained for 20 hours even when voltage reversal occurred. Also the removal ability of organic pollutants (SCOD) was not reduced. As a result of this study, it was found that buffering effect for a certain period of time when the voltage reversal occurred during the operation of the microbial fuel cell did not have a serious effect on the energy loss or the operation of the microbial fuel cell.

A Study on Manufacture and Design of Low Voltage.Low Electric Power System by PEMFC Single cell (PEMFC 단위 셀의 제작 및 저전압.저전력 시스템 설계에 관한 연구)

  • Ryu, Yun-Sim;Ahn, Ho-Gyun;Seo, Jung-Rang;Kim, Sung-Hoon;Lee, Chang-Ho
    • Proceedings of the KIPE Conference
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    • 2007.11a
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    • pp.193-195
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    • 2007
  • These days, to change the new & renewable energy change the subject because environmental pollution and exhausted fossil power. The most notable Fuel cells by one of the new & renewable energies are one of very useful power conversion sources. Their advantages are low environmental pollution, highly efficient power generation, diversity of fuels (natural gas, LPG, methanol and naphtha), and reusability of exhaust heat, modularity, and faster installation. PEMFC by one of the Fuel Cells is the energy of new technology which is produced by the electric chemical reaction directly. The essential composition elements of PEMFC stack are membrane electrode assembly (MEA), catalyst, Bipolar Plate. Under the this study, know-how is manufacturing single cell of PEMFC and Study design of Low Voltage, Low Electric Power System by PEMFC Single Cell.

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Surface Characteristic of Graphene Coated Stainless Steel for PEMFC Bipolar Plate (그래핀이 코팅된 스테인리스강의 고분자전해질 연료전지 분리판 적용을 위한 표면 특성)

  • Lee, Su-Hyung;Kim, Jung-Soo;Kang, Nam-Hyun;Jo, Hyung-Ho;Nam, Dae-Guen
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.226-231
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    • 2011
  • Graphene was coated on STS 316L by electro spray coating method to improve its properties of corrosion resistance and contact resistance. Exfoliated graphite (graphene) was made of the graphite by chemical treatment. Graphene is distributed using dispersing agent, and STS 316L was coated with diffuse graphene solution by electro spray coating method. The structure of the exfoliated graphite was analyzed using XRD and the coating layer of surface was analyzed by using SEM. Analysis showed that multi-layered graphite structure was destroyed and it was transformed into fine layers graphene structure. And the result of SEM analysis on the surface and the cross section, graphene layer was uniformly formed with 3~5 ${\mu}m$ thickness on the surface of substrate. Corrosion resistance test was applied in the corrosive solution which is similar to the PEM fuel cell stack inside. And interfacial contact resistance test was measured to simulate the internal operating conditions of PEM fuel cell stack. The results of measurements show that stainless steel coated with graphene was improved in corrosion resistance and surface contact resistance than stainless steel without graphene coating layer.