• 한국재료학회지
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• 제21권12호
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• pp.685-689
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• 2011

The goal of this investigation was to produce a zirconia-family black ceramics that has enhanced functionality and reliability. Color zirconia ceramics have been produced by adding pigments. Pigments cause structural defects within zirconia and result in a drop in physical properties. Using environmentally friendly rice husk, we produced a black zirconia that is free of structural defects. In optimal firing conditions for black zirconia the calcining temperatures of the molding product are changed from $400^{\circ}C$ to $1200^{\circ}C$, and the firing temperatures are changed from $1400^{\circ}C$ to $1600^{\circ}C$. Color of testing the specimens was analyzed using Ultraviolet (UV) spectroscopy. Scanning Electron Microscope (SEM), EDAX (EDX), and Fourier transform infrared spectroscopy (FT-IR) analyses were carried out in order to examine impregnation properties and crystal phases. Universial Test Machine (UTM) was used to measure the flexual strength as well as the compressive strength. From experimental results, it was found that in optimal firing conditions the sample was calcined from $1000^{\circ}C$ to $1500^{\circ}C$. Commission internationalde I'Edairage (CIE) values of manufactured black zirconia color were $L^*$ = 29.73, $a^*$ = 0.23, $b^*$ = -2.68. The bending strength was 918 MPa and the compressive strength was 2676 MPa. These strength values are similar to typical strength values of zirconia, which confirms that carbon impregnation did not influence physical properties.

• 한국세라믹학회지
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• 제18권4호
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• pp.229-236
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• 1981

This study deals with the high temperature (600-135$0^{\circ}C$) properties of Kaolin-Phosphate-Water systems. Phosphoric acid, mono aluminum phosphate, mono ammonium phosphate, the mixture of phosphoric acid and mono aluminum phosphate, and the mixture of phosphoric acid and mono ammonium phosphate were used to characterize the M.O.R of the systems with to quantity of phosphates and firing temperature. Firing shrinkage, creeptest, DTA, TGA, and X-ray diffraction patterns were also measured in order to investigate the factors of strengthening. The resules of the experiments are as follows: 1. Linear shrinkage of kaolin-phosphate systems become larger as the firing temperature rise, and generally in the firing temperature of $600^{\circ}C$ and 100$0^{\circ}C$ the test pieces with phosphate binder show larger then Kaolin-Water system in linear shrinkage and reversed trends were found at 120$0^{\circ}C$ and 135$0^{\circ}C$. 2. Cold M.O.R. of kaolin-phosphate systems show higher trends in strength as the firing temperature rise. Comparing M.O.R. of test pieces after firing at 135$0^{\circ}C$, the mixture of phosphoric acid-mono aluminum phosphate, and phosphoric acid mono ammonium phosphate systems show higher strength than kaolin-mono aluminum phosphate system which widely used, and it shows highest strength when the mole ratio of phosphoric acid and mono ammonium phosphate is 1:1 among the test pieces of kaolin-phosphate systems. 3. The refractoriness of kaolin-phosphate systems are more deteriorated than Kaolin-Water system, and generally, the more addition of phosphate, the lower the refractoriness, however in the range of 4-8% phosphate addition, the difference of the fusion temperature is about 7$0^{\circ}C$. 4. The test pieces of T1 and T2 in creep test were same or even higher than kaolin-water system when 6% of phosphoric acid-mono ammonium phosphate was added to kaolin. 5. In case where the phosphoric acid-mono ammonium phosphate was added to kaolin in mole ratio 1:1 the cold M.O.R., after firing at 135$0^{\circ}C$, refractoriness and $T_2$ in creep test show better results than kaolin-mono-aluminum phosphate system which is widely used. 6. Phosphoric acid and mono ammonium phosphate react with kaolin in temperature over 100$0^{\circ}C$, and it forms aluminum phosphate.

• 건축역사연구
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• 제25권3호
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• pp.37-45
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• 2016

This study was to investigate the firing method of limestone in Joseon Dynasty, and analyze the physical chemical properties of lime mortars in Joseon Dynasty. This study was to manufacture and evaluate the firing experiment and mortar of Limestone by each sort in order to reproduce the traditional lime mortars in Joseon Dynasty, and investigate the behavior to improve physical properties according to the firing method of Limestone. This study has found out that there were screening criteria and standard of appropriate firing temperature about the Limestone in Joseon Dynasty. Accordingly, this study was to improve its strength through various additives and mixture. In particular, in case of Limestone, the black and blue Limestone were preferred, and most of domestic Limestones were low grade Limestone including the clay and took ivory white or blue with low whiteness. This study has shown that the low grade Limestone was mined by the surface mining compared with the high grade Limestone as underground mining method, and could be used because it was easy to mine relatively and there was possibility that Natural Hydraulic Lime(NHL) was used with the traditional lime mortars in Joseon Dynasty.

• 자원리싸이클링
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• 제8권1호
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• pp.23-28
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• 1999

적점토와 밀스케일, 물유리를 원료로한 축열용 난방재를 개발하기 위해 제반 기초적 실험을 수행하였다. 원료배합 및 소성 조건에 따른 축열재 시료의 소성특성, 열용량, 항절력, 미세조직 등을 분석하였다. 소성체의 수축은 적점토의 비율이 높을수록 증가하였다. $300^{\circ}C$까지는 건조수축이, $300~700^{\circ}C$ 영역에서는 산화철의 상변화에 의한 완만한 팽창, $1200^{\circ}C$ 이상에서는 급격한 팽창을 나타내었다. 항절력은 밀스케일 : 적점토 비가 1:1에서 3:1로 변함에 따라 5.6MPa에서 2.35MPa로 감소하였다. 열용량은 밀스케일 : 적점토의 비율이 1:1~3:1인 경우, $1.25~1.35J/g^{\circ}C$의 값을 나타내었다. 시험편과 공기와의 접촉을 제한함으로써, 시료 내 밀스케일 성분이 소성과정에서 용융하여 시편 표면으로 용출되는 현상을 억제시킬 수 있었고, 이에 따라 균일한 표면의 시료를 제작할 수 있다. 밀스케일의 첨가는 소성체를 다공질화시켜, 축열재의 축열 후 냉각속도를 낮추는데 기여할 것으로 판단된다.

• 한국추진공학회지
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• 제15권1호
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• pp.69-75
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• 2011

한국형발사체 엔진에 사용될 예정인 75톤급 연소기 채널냉각형 기술검증시제에 대한 연소시험을 수행하였다. 설비 공급 능력과 구조물 강도 제한으로 정상 유량의 50% 수준에서 시험이 수행되었다. 75톤급 채널냉각 연소기의 저압연소시험을 통해 점화구간과 연소구간에서의 작동성과 안정성이 확인되었다. 더불어 75톤 연소기의 성능요구조건을 만족시킬 수 있을 것으로 추정할 수 있었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제34회 춘계학술대회논문집
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• pp.71-74
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• 2010

한국형발사체 엔진에 사용될 것으로 예상되는 75톤급 연소기의 기술검증시제를 이용하여 2회 연소시험을 수행하였다. 설비 공급 능력과 구조물 강도 제한으로 정상 유량의 50% 수준에서 시험이 수행되었다. 채널냉각 연소기를 이용한 저압연소시험을 통해 점화구간과 연소구간에서의 신뢰도와 안정성이 확인되었다. 더불어 75톤 연소기가 성능요구조건을 만족시킬 수 있을 것으로 추정할 수 있었다.

• 한국세라믹학회지
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• 제33권9호
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• pp.1003-1011
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• 1996

Hydroxyapatite powder was synthesized by a citrate method, . Char-like precursor composed of Ca8(HPO4)2(PO4)4.5H2O (OCP) and CaCo3 was found via viscous resin-like intermediate by heating the mixed aqueous solution of Ca(NO3)2.4H2O(NH4)2HPO4 and citric acid. Resulted powder was transformed into hydroxyapatite phase by firing over 120$0^{\circ}C$-135$0^{\circ}C$ for 4 hr using the powder calcined at 90$0^{\circ}C$ for 10 hr composed of mostly single hydroxyapatite phase. The sintered densities increased with firing temperature up to 130$0^{\circ}C$ but the highest relative density was about 94% of theoritical value. indicating the presence of closed pores. The maximum 96 MPa of flexural strength was obtained at 120$0^{\circ}C$ firing but the flexural strength showed lower values over the above sintering condition. Vitro test was performed by immersing of two jointed specimens in SBF for seven days and adhesion was observed between two specimens.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.673-676
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• 1999

We fabricated green sheet by tape casting method with fluormica glass-ceramic powders for fabrication of low temperature co-firing substrate. After ball milling with organic additives, we investigated green strength and density of green sheets which were casted by doctor blade machine. Green sheets were sintered at 700 ~ 1,00$0^{\circ}C$ for 1 ~3hrs. Microstructure, linear shrinkage and dielectric constant of substrates were surveyed.

• 대한건축학회논문집:구조계
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• 제35권10호
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• pp.199-206
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• 2019

This study aims to recycle redmud which is a byproduct in the alumina industry. Redmud ceramics were prepared according to the type of raw materials by blending redmud with the raw materials used in the conventional clay bricks. In this paper, the compressive strength, water absorption ratio, and shrinkage of redmud ceramics prepared by mixing clay bricks were evaluated. Compressive strength and absorption ratio of redmud ceramics were compared with the clay brick criteria of KS L 4201. At the firing temperature of $1200^{\circ}C$, the specimens containing redmud only and the redmud with sandy loam and black clay were found to satisfy the 1st class of clay brick. The quality standard of compressive strength and absorption ratio was obtained by firing redmud with black clay and sandy loam at $1200^{\circ}C$. Also, when the redmud was mixed with black clay and feldspar, the 2nd class was satisfied when the sample was fired at $1100^{\circ}C$.

• 한국세라믹학회지
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• 제27권6호
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• pp.755-762
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• 1990

The tungsten paste was printed on the surface of 92% alumina sheet which was made by type casting process. The printed tungsten was bonded on the Al2O3 by co-firing in reducing atmosphere. During the co-firing, the binder burn-out was easier in wet H2 atmosphere than in dry H2, which affected sintered density. In practically, the use of wet H2 above 100$0^{\circ}C$ was beneficial for density of alumina and bond strength. This phenomena occured more distinctly when atmosphere varied from dry H2 to wet H2 than varied dew point in wet H2. In wet H2, the improvement in bonding strength can be attributed to good glass migration into the metal layer due to inhibition of the tungsten particle growth, with increase of alumina density, at the temperatrue higher than 100$0^{\circ}C$.