• Title/Summary/Keyword: equilibrium conditions

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Thermodynamic promoter effects on the phase equilibrium of BFG(Blast Furnace Gas) hydrate (촉진제 첨가에 따른 철강공정 배기가스 하이드레이트 상평형 영향)

  • Lee, Bo Ram;Sa, Jeong-Hoon;Park, Da-Hye;Kwak, Kye-Hoon;Lee, Kun-Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.125.1-125.1
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    • 2011
  • $CO_2$ separation from a flue gas by using the gas hydrate technology was suggested by Kang et al. They reported phase equilibrium conditions of mixed gases composed of $CO_2$ and N2 with THF as a thermodynamic promoter. In this study, we reported the phase equilibrium conditions of a mixed gas which had a realistic composition of the blast furnace gas (BFG) emitted from the steel-making process. The phase equilibrium measurements were done by using the "continuous" QCM method, and the results demonstrate that this method is efficient and as accurate as the conventional temperature search method.

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A Study on the Phase Equilibrium Conditions of Mixture Gas Hydrates using CSMHYD (CSMHYD를 이용한 혼합가스 하이드레이트의 상평형에 대한 연구)

  • Seo, Hyang-Min;Park, Yun-Beom;Chun, Won-Gee;Kim, Nam-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.585-589
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    • 2007
  • Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. When referred to standard conditions, $1m^3$ solid hydrates contain up to $172Nm^3$ of methane gas, depending on the pressure and temperature of production, Such large volumes make natural gas hydrates can be used to store and transport natural gas. In this study, three-phase equilibrium conditions for forming methane hydrate were theoretically obtained in aqueous single electrolyte solution containing 3wt% Nacl. The results show that Nacl acts as a inhibitor, but help gases such as ethan, propane, i-butane, and n-butane reduce the hydrate formation pressure at the same temperature.

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Equilibrium Conditions of Methane Hydrate added Help Gases (보조가스가 첨가된 메탄 하이드레이트 상평형 조건에 대한 연구)

  • Kim, Nam-Jin;Lim, Sang-Hoon;Chun, Won-Gee
    • Journal of the Korean Solar Energy Society
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    • v.27 no.4
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    • pp.51-58
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    • 2007
  • Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. When referred to standard conditions, $1m^3$ solid hydrates contain up to $172Nm^3$ of methane gas, depending on the pressure and temperature of production. Such large volumes make natural gas hydrates can be used to store and transport natural gas. In this study, three-phase equilibrium conditions for forming methane hydrate were theoretically obtained in aqueous single electrolyte solution containing 3wt% NaCl. The results show that the predictions match the previous experimental values very well, and it was found that NaCl acts as an inhibitor.

SOME ITERATIVE ALGORITHMS FOR THE GENERALIZED MIXED EQUILIBRIUM-LIKE PROBLEMS

  • Liu, Zeqing;Chen, Zhengsheng;Kang, Shin-Min
    • Journal of applied mathematics & informatics
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    • v.26 no.3_4
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    • pp.481-491
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    • 2008
  • In this paper, we introduce and analyze a new class of generalized mixed equilibrium-like problems. By using the auxiliary principle technique, we suggest three iterative algorithms for the generalized mixed equilibrium-like problem. Under certain conditions, we establish the convergence of the iterative algorithms. Our results extend, improve and unify several known results in this field.

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NONLINEAR ALGORITHMS FOR A COMMON SOLUTION OF A SYSTEM OF VARIATIONAL INEQUALITIES, A SPLIT EQUILIBRIUM PROBLEM AND FIXED POINT PROBLEMS

  • Jeong, Jae Ug
    • Korean Journal of Mathematics
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    • v.24 no.3
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    • pp.495-524
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    • 2016
  • In this paper, we propose an iterative algorithm for finding a common solution of a system of generalized equilibrium problems, a split equilibrium problem and a hierarchical fixed point problem over the common fixed points set of a finite family of nonexpansive mappings in Hilbert spaces. Furthermore, we prove that the proposed iterative method has strong convergence under some mild conditions imposed on algorithm parameters. The results presented in this paper improve and extend the corresponding results reported by some authors recently.

Equilibrium Thermodynamics of Chemical Reaction Coupled with Other Interfacial Reactions Such as Charge Transfer by Electron, Colligative Dissolution and Fine Dispersion: A Focus on Distinction between Chemical and Electrochemical Equilibria

  • Pyun, Su-Il;Lee, Sung-Jai;Kim, Ju-Sik
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.227-241
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    • 2008
  • This article involves a unified treatment of equilibrium thermodynamics of the chemical reaction coupled with other interfacial (phase boundary) reactions. The modified (restrictive) chemical potential ${\mu}_k^+$, such as electrochemical potential, hydrostatic-chemical (mechanochemical) potential (exceptionally in the presence of the pressure difference) and surface-chemical potential, was first introduced under the isothermal and isobaric conditions. This article then enlightened the equilibrium conditions in case where the release of chemical energy is counterbalanced by the supply of electrical energy, by the supply of hydrostatic work (exceptionally in the presence of ${\Delta}p$), and finally by the release of surface energy, respectively, at constant temperature T and pressure p in terms of the modified chemical potential ${\mu}_k^+$. Finally, this paper focussed on the difference between chemical and electrochemical equilibria based upon the fundamentals of the isothermal and isobaric equilibrium conditions described above.

AN APPROACH TO THE PROBLEM OF COMMON POOL RESOURCES THROUGH AN EXTENSION OF THE EQUILIBRIUM CONCEPT

  • Bae, Jaegug;Kim, Jongseok;Kang, Eun Sook
    • Honam Mathematical Journal
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    • v.35 no.2
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    • pp.225-234
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    • 2013
  • Many studies of experimental economics have produced outcomes which contradict the predictions of Nash equilibrium, which relies heavily upon the premise of selfishness of an individual. In the games involving contexts of social conflicts represented by the prisoners' dilemma game, the experiments yields outcomes quite different from what are predicted by the conventional wisdom. In order to fill this gap between the conventional Nash Equilibrium and experimental outcomes, non-selfish (or other-regarding) motives of human behavior are introduced and then a new equilibrium concept, RAE-equilibrium is developed. It is also proved that an RAE-equilibrium exists under quite general conditions. Then it is applied to the prisoners' dilemma game that some of the experimental outcomes can be explained.

Study on the Equilibrium Point of Heat and Mass Transfer between Liquid Desiccant and Humid Air with in the Solar Air Conditioning System

  • Sukmaji, I.C.;Rahmanto, H.;Agung, B.;Choi, K.H.;Kim, J.R.
    • 한국태양에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.161-167
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    • 2009
  • The liquid solar air conditioning system is introduced as an alternative solution to control air condition and to save electrical energy consumption. The heat and mass transfer performances of dehumidifier/regenerator in liquid solar air conditioning system are influenced by air and desiccant condition. The application of this system, the thermal energy from the sun and inlet air are unable to control, but operation parameter of other components such as pump, fan and sensible cooling unit are able to control. The equilibrium point of heat and mass transfer are the liquid desiccant and inlet air conditions, where, the heat and mass are not transferred between the liquid desiccant and vapor air. By knowing equilibrium point of heat and mass transfer, the suitable optimal desiccant conditions for certain air condition are funded. This present experiment study is investigated the equilibrium point heat and mass transfer in various air and desiccant temperature. The benefit of equilibrium point heat and mass transfer will be helpful in choose and design proper component to optimize electrical energy consumption.

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Automatic generation of equilibrium and flexibility matrices for plate bending elements using Integrated Force Method

  • Dhananjaya, H.R.;Nagabhushanam, J.;Pandey, P.C.
    • Structural Engineering and Mechanics
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    • v.30 no.4
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    • pp.387-402
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    • 2008
  • The Integrated Force Method (IFM) has been developed in recent years for the analysis of civil, mechanical and aerospace engineering structures. In this method all independent or internal forces are treated as unknown variables which are calculated by simultaneously imposing equations of equilibrium and compatibility conditions. The solution by IFM needs the computation of element equilibrium and flexibility matrices from the assumed displacement, stress-resultant fields and material properties. This paper presents a general purpose code for the automatic generation of element equilibrium and flexibility matrices for plate bending elements using the Integrated Force Method. Kirchhoff and the Mindlin-Reissner plate theories have been employed in the code. Paper illustrates development of element equilibrium and flexibility matrices for the Mindlin-Reissner theory based four node quadrilateral plate bending element using the Integrated Force Method.

Meshless equilibrium on line method (MELM) for linear elasticity

  • Sadeghirad, A.;Mohammadi, S.;Kani, I. Mahmoudzadeh
    • Structural Engineering and Mechanics
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    • v.35 no.4
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    • pp.511-533
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    • 2010
  • As a truly meshfree method, meshless equilibrium on line method (MELM), for 2D elasticity problems is presented. In MELM, the problem domain is represented by a set of distributed nodes, and equilibrium is satisfied on lines for any node within this domain. In contrary to conventional meshfree methods, test domains are lines in this method, and all integrals can be easily evaluated over straight lines along x and y directions. Proposed weak formulation has the same concept as the equilibrium on line method which was previously used by the authors for enforcement of the Neumann boundary conditions in the strong-form meshless methods. In this paper, the idea of the equilibrium on line method is developed to use as the weak forms of the governing equations at inner nodes of the problem domain. The moving least squares (MLS) approximation is used to interpolate solution variables in this paper. Numerical studies have shown that this method is simple to implement, while leading to accurate results.