• Journal of Korean Society on Water Environment
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• v.21 no.1
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• pp.14-20
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• 2005

A feasibility study has been conducted regarding the application of waste coffee grounds as an adsorbent for the treatment of nickel ion containing wastewater. The major variables which considered to influence the adsorbability of nickel ion were its initial concentration, reaction temperature, pH, and coexisting ion. The specific surface area of coffee grounds used in the experiment was found to be ca. $39.67m^2/g$, which suggesting its potential applicability as an adsorbent due to its relatively high surface area. In the experimental conditions, more than 90% of the initial amount of nickel ion was shown to adsorb within 15 minutes and equilibrium in adsorption was attained after 3 hours. The adsorption behavior of nickel ion was well explained by Freundlich model and kinetics study showed that the adsorption reaction was second-order. Adsorption was reduced with temperature and its change of enthalpy in standard state was estimated to be -807.05 kJ/mol. Arrhenius equation was employed for the calculation of the activation energy of adsorption and nickel ion was observed to adsorb on coffee grounds exoentropically based on thermodynamic estimations. As pH rose, the adsorption of nickel ion was diminished presumably due to the formation of cuboidal complex with hydroxide ion and the coexistence of cadmium ion was found to decrease the amount of nickel ion adsorption, which was proportional to the concentration of cadmium ion.

• Journal of Mechanical Science and Technology
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• v.18 no.5
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• pp.820-829
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• 2004

The In-Containment Refueling Water Storage Tank (IRWST), one of the design improvements applied to the APR -1400, has a function to condense the high enthalpy fluid discharged from the Reactor Coolant System (RCS). The condensation of discharged fluid by the tank water drives the tank temperature high and causes oscillatory condensation. Also if the tank cooling water temperature approaches the saturated state, the steam bubble may escape from the water uncondensed. These oscillatory condensation and bubble escape would burden the undue load to the tank structure, pressurize the tank, and degrade its intended function. For these reasons simple analytical modeling and experimental works were performed in order to predict exact tank temperature distribution and to find the effective cooling method to keep the tank temperature below the bubble escape limit (93.3$^{\circ}C$), which was experimentally proven by other researchers. Both the analytical model and experimental results show that the temperature distributions are horizontally stratified. Particularly, the hot liquid produced by the condensation around the sparger holes goes up straight like a thermal plume. Also, the momentum of the discharged fluid is not so strong to interrupt this horizontal thermal stratification significantly. Therefore the layout and shape of sparger is not so important as long as the location of the sparger hole is sufficiently close to the bottom of the tank. Finally, for the effective tank cooling it is recommended that the locations of the discharge and intake lines of the cooling system be cautiously selected considering the temperature distribution, the water level change, and the cooling effectiveness.

• Journal of Power Electronics
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• v.11 no.4
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• pp.591-598
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• 2011

This paper investigates a power supply of medium voltage with enhanced ignition characteristics for plasma torches. A series resonant half-bridge topology is presented as a suitable ignition circuitry. The ignition circuitry is integrated into the main power conversion system of a multi-phase staggered three-level dc-dc converter with a diode front-end rectifier. A plasma torch rated at 3MW, 2kA and having a physical size of 1m is selected to be the high enthalpy source for a waste disposal system. The steady-state and transient operations of a plasma torch are simulated. The parameters of a Cassie-Mary arc model are calculated based on 3D magneto-hydrodynamic simulations. The circuit simulation waveform shows that the ripple of the arc current can be maintained within ${\pm}10%$ of its rated value under the presence of a load disturbance. This power conversion configuration provides a high enough ignition voltage, around 5KA, during the ignition phase and high arc stability under the existence of arc disturbance noise resulting in a high-performance plasma torch system.

• Journal of the Korean Ceramic Society
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• v.37 no.3
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• pp.271-279
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• 2000

5 m/o Yb-doped SrCeO3 proton conductor was prepared by a solid state reaction method and its total electriccal conductivity measured as a function of both oxygen partial pressure and water vapor partial pressure in the temperature range of 500~100$0^{\circ}C$. From the total conductivity have been deconvoluted the partial conductivities of oxide ions, protons, and holes, respectively, on the basis of the defect model proposed. The equilibrium constant of hydrogen-dissolution reaction, proton concentration, and mobilities of oxygen vacancies and protons have subsequently been evaluated. It is verified that SrCe1-xYbxO3 is a mixed conductor of holes, protons and oxide ions and the proton conduction prevails as temperature decreases and water vapor pressure increases. The heat of water dissolution takes a representative value of $\Delta$HoH=-(140$\pm$20) kJ/mol-H2O, but tends to be less negative with increasing temperature. Migration enthalpies of proton and oxygen vacancy are extracted as 0.83$\pm$0.10 eV and 0.81$\pm$0.01 eV, respectively.

• Advances in environmental research
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• v.4 no.1
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• pp.49-68
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• 2015

Chemically activated and carbonized adsorbents were prepared from Moringa oleifera pod husks (MOP), characterized and evaluated for their ability to remove a common antibiotic - ofloxacin (OFX) from aqueous solution. The pulverized precursor was steeped in a saturated ammonium chloride solution for a day to give the chemically activated adsorbent (AMOP). A portion of AMOP was pyrolyzed in a muffle furnace at 623 K for 30 min to furnish its carbonized analogue (CMOP). The adsorbents showed favorable physicochemical attributes. The effects of operational parameters such as initial OFX solution pH and concentration, adsorbent dosage, temperature and contact time on OFX removal were investigated. At equilibrium, optimal removal efficiencies of 90.98% and 99.84% were achieved at solution pH 5 for AMOP and CMOP, respectively. The equilibrium adsorption data fitted into both the Langmuir and Freundlich isotherms. Gibbs free energy change (${\Delta}G^o$), enthalpy change (${\Delta}H^o$) and entropy change (${\Delta}S^o$) indicated that the adsorption of OFX was feasible, spontaneous, exothermic and occurred via the physisorption mode. Adsorption kinetics obeyed the Blanchard pseudo-second-order model. The results may find applications in the adsorptive removal of micro-contaminants of pharmaceutical origin from wastewater.

• Applied Chemistry for Engineering
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• v.30 no.5
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• pp.536-545
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• 2019

An experiment was conducted to evaluate the adsorptive removal of Pb(II) from an aqueous solution using a mixture of spent coffee grounds and chitosan on beads (CC-beads). Various parameters affecting the adsorption process of Pb(II) using CC-beads were investigated. Based on the experimental data, the adsorption kinetics and adsorption isotherms were analyzed for their adsorption rate, maximum adsorption capacity, adsorption energy and adsorption strength. Moreover, the entropy, enthalpy and free energy were also calculated by thermodynamic analysis. According to the FT-IR analysis, a CC-bead has a very suitable structure for easy heavy metal adsorption. The process of adsorbing Pb(II) using CC-beads was suitable for pseudo-second order kinetic and Langmuir model, with a maximum adsorption capacity of 163.51 (mg/g). The adsorption of Pb(II) using CC-beads was closer to chemical adsorption than physical adsorption. In addition, the adsorption of Pb(II) on CC-beads was exothermic and spontaneous in nature. CC-beads are economical because they are inexpensive and also the waste can be recycled, which is very significant in terms of the continuous circulation of resources. Thus, CC-beads can compete with other adsorbents.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.419-426
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• 2008

As pulse detonation engine(PDE) does not need compression mechanisms such as compressors because self-sustained detonation waves are able to compress propellant gases by their incident shock waves, the PDE can have a simple straight-tube structure. In this study, we propose an autonomous driving valve system of the PDE, which fill premixed gases into the PDE tubes at high frequency with high mass flow rate. The proposed valve is composed of only three parts: a piston, a cylinder, and a spring. This valve system can produce intermittent flow at high mass flow rate, and also can keep stable reciprocal motion by using the propellant-gas enthalpy. When the cylinder content product is assumed to be constant, experimental results of the mass flow rate were approximately equal to the calculation model. We confirmed the autonomous driving valve performance by experiments, and concluded that this extremely simple valve with no electrical power and controller can be used as the PDE propellant supply system.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.397-402
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• 2012

The objective of this study is the estimation of the two unknown thermal conductivity and thermal diffusivity by an inverse heat conduction analysis using the Levenberg-Marguardt method. One dimensional formulation of heat conduction problem in the model was applied. Two point transient temperature of test pieces and heat flux of inflow were measured under the high enthalpy flow environment. Estimated thermal conductivity and thermal diffusivity by an inverse analysis were compared with the known values of graphite test piece. It showed the effectiveness of proposed experimental inverse analysis.

• Nuclear Engineering and Technology
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• v.47 no.7
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• pp.907-914
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• 2015

The energetic steam explosion caused by contact between the high temperature molten core and water is one of the phenomena that may threaten the integrity of the containment vessel during severe accidents of light water reactors (LWRs). We examined the dependence of steam explosion loads in a typical reactor cavity geometry on selected model parameters and initial/boundary conditions by using a steam explosion simulation code, JASMINE, developed at Japan Atomic Energy Agency (JAEA). Among the parameters, we put an emphasis on the water pool depth that has significance in terms of accident mitigation strategies including cavity flooding. The results showed a strong correlation between the load and the premixed mass, defined as the mass of the molten material in low void zones (void fraction < 0.75). The jet diameter and velocity that comprise the flow rate were the primary factors to determine the premixed mass and the load. The water pool depth also showed a significant impact. The energy conversion ratio based on the enthalpy in the premixed mass was in a narrow range ~4%. Based on this observation, we proposed a simplified method for evaluation of the steam explosion load. The results showed fair agreement with JASMINE.

• International Journal of High-Rise Buildings
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• v.8 no.1
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• pp.71-82
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• 2019

The purpose of this study is to evaluate the indoor air quality (IAQ) and energy benefits of a dedicated outdoor air system (DOAS) and compare them with a conventional variable air volume (VAV) system. The DOAS is a decoupled system that supplies only outdoor air, while reducing its consumption using an enthalpy wheel. The VAV system supplies air that is mixed outdoor and transferred indoor. The VAV has the issue of unbalanced ventilation in each room in multiple zones because it supplies mixing air. The DOAS does not have this problem because it supplies only outdoor air. That is, the DOAS is a 100% outdoor air system and the VAV is an air conditioning system. The transient simulations of carbon dioxide concentration and energy consumption were performed using a MATLAB program based on the thermal loads from the model predicted by the TRNSYS 18 program. The results indicated that when the air volume is large, such as in summer, the distribution of air is not appropriate in the VAV system. The DOAS however, supplies the outdoor air stably. Moreover, in terms of annual primary energy consumption, the DOAS consumed approximately 40% less energy than the VAV system.