• Title/Summary/Keyword: energy storage and conversion

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Theory & Design of Electrocatalyst for Polymer Electrolyte Membrane Fuel Cell (고분자 연료전지용 전기촉매의 이론과 설계)

  • Yoo, Sung-Jong;Jeon, Tae-Yeol;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.12 no.1
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    • pp.11-25
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    • 2009
  • Fuel cells are expected to be one of the major clean new energy sources in the near future. However, the slow kinetics of electrocatalytic hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR), and the high loading of Pt for the anode and cathode material are the urgent issues to be addressed since they determine the efficiency and the cost of this energy source. In this review paper, a new approach was developed for designing electrocatalysts for the HOR and ORR in fuel cells. It was found that the electronic properties of Pt could be fine-tuned by the electronic and geometric effects introduced by the substrate alloy metal and the lateral effects of the neighboring metal atoms. The role of substrate was found reflected in a volcano plot for the HOR and ORR as a function of their calculated d-band centers. This paper demonstrated a viable way to designing the electrocatalysts which could successfully alleviate two issue facing the commercializing of the fuel cell-the cost of electrocatalysts and their efficiency.

Challenges and Design Strategies for Conversion-Based Anode Materials for Lithium- and Sodium-Ion Batteries

  • Kim, Hyunwoo;Kim, Dong In;Yoon, Won-Sub
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.32-53
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    • 2022
  • Although lithium-ion batteries are currently the most reliable power supply system for various mobile applications, further improvement in energy density is still required as the need for batteries in large energy-consuming devices is rapidly growing. However, in the anode, the most widely commercialized graphite-based anode materials almost face theoretical limitations. In addition, sodium-ion batteries have been actively studied to replace expensive charge carriers with cheaper ones. Accordingly, conversion-based materials have been extensively studied as high-capacity anode materials in both lithiumion batteries and sodium-ion batteries because their theoretical capacity is twice or thrice higher than that of insertion-based materials. This review will provide a comprehensive understanding of conversion-based materials, including basic charge storage behaviors, critical drawbacks that should be overcome, and practical material design for high-performance.

Development of Transformation-Core for Magnetic Field in Switchgear

  • Gwan-hyung Kim
    • Journal of information and communication convergence engineering
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    • v.21 no.4
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    • pp.316-321
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    • 2023
  • In this study, we developed a conversion core that produces power by utilizing the unused magnetic field in a switchboard. The conversion core makes it possible to utilize power that is normally wasted. The conversion core is composed of a core, filter, and battery. A prototype was installed in a switchboard to conduct tests on the output, battery storage, and output boosting of multiple batteries. Energy was harvested from the magnetic field generated by a busbar of the switchboard, and the power conversion ratio of the core yielded 1.08-1.01 mW per 1 A of bus current. Supplying this technology to the market after further R&D and commercialization is expected to greatly assist in the dissemination of energy harvesting, which has not yet spread widely to the general public.

An experimental study on heat transfer characteristics in the ice storage system of ice-on-coil type with rectangular finned tube during freezing process (직사각형 휜이 부착된 관외착빙형 빙축열조에서 응고과정시 열전달 특성에 관한 연구)

  • Kwon, H.Y.;Koh, J.Y.;Jeong, B.Y.;Yim, C.S.
    • Solar Energy
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    • v.20 no.4
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    • pp.61-67
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    • 2000
  • The purpose of this study is to improve heat transfer by attaching rectangular fins to tube. Experiments were carried out under the following conditions - Aspect ratio$(W_f/R_f)$ is 0.7, 1.2 and 1.8. Temperature conversion between high and low positions of water in the thermal storage appeared because maximum density point of water is about $4^{\circ}C$ and inlet direction of working fluid influenced conductive heat transfer Compared with the unfinned tube(bare tube), the rectangular tube increased the ice thermal storage energy and the ice thermal storage energy was increased as aspect ratio was increased.

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CdSe Quantum Dots Sensitized TiO2 Electrodes for Photovoltaic Cells

  • Yum, Jun-Ho;Choi, Sang-Hyun;Kim, Seok-Soon;Kim, Dong-Yu;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.257-261
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    • 2007
  • The electronic properties of quantum dots can be tuned by changing the size of particles without any change in their chemical composition. CdSe quantum dots, the sizes of which were controlled by changing the concentrations of Cd and Se precursors, were adsorbed on $TiO_2$ photoelectrodes and used as sensitizers for photovoltaic cells. For applications of CdSe quantum dot as sensitizers, $CdSe/TiO_2$ films on conducting glass were employed in a sandwich-type cell that incorporated a platinum-coated conductive glass and an electrolyte consisting of an $I^-/I_3^-$ redox. The fill factor (FF) and efficiency for energy conversion ($\c{c}$) of the photovoltaic cell was 62 % and 0.32 %, respectively.

Development of firing equipment and monitoring system for electric power conversion system for high voltage and large current (고압 대전류용 전력변환 점호장치 및 감시시스템 개발)

  • Lee Joo-Hyun;Lim Ick-Hun;Ryu Ho-Sun
    • Proceedings of the KIPE Conference
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    • 2006.06a
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    • pp.481-484
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    • 2006
  • A electric power conversion system in a pumped storage power plant is important equipment for converting electric motor kinetic energy into electric power. A electric power conversion monitoring system consists of high voltage thyristor firing equipment, fault detection module, data gathering module, real time data processing equipment and man machine interface system. This paper describes electric power conversion system overview, the developed SFC monitoring system configuration including system characteristics, and successful application result to San-Cheong pumped storage power plant.

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Predicting the Lifetime of Super-capacitor for DC Traction Regenerative Energy Storage System (직류철도 회생에너지 저장시스템용 슈퍼커패시터 수명예측)

  • Kim, Jong-Yoon;Park, Chan-Heung;Cho, Kee-Hyun;Jang, Su-Jin;Lee, Byoung-Kuk;Won, Chung-Yuen
    • Proceedings of the KIPE Conference
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    • 2007.11a
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    • pp.212-214
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    • 2007
  • Regenerative energy which is generated during brake periods of DC traction might cause malfunction or destruction of rectifier or any other power conversion devices caused the increment of DC line voltage. Regenerative energy storage system using super-capacitor is one of the method to control the DC line voltage safely. And super-capacitor is very important device as energy storage device. Therefore, In this paper, we designed the regenerative energy storage system using super-capacitor and propose the method about predicting the lifetime of super-capacitor established in storage system. According to the this research, we can estimate the proper replacement moment for the existed super-capacitor due to the safety of the system. And improve the reliability of regenerative energy storage system using super-capacitor.

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High Performance of Nano-sized LiFePO4 Positive Electrode Using Etched Al Current Collector

  • Lee, Gil-Won;Ryu, Ji-Heon;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.13 no.3
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    • pp.157-162
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    • 2010
  • The electrodes comprising nano-sized $LiFePO_4$, carbon black and binder are prepared with two different Al current collectors. One is the generally used normal Al foil and the other is the chemically etched Al foil. Surface characteristics of each Al foil and electrochemical performance of the cathodes using each foil are investigated. The electrode from the etched Al foil exhibits better physical and electrochemical properties as compared to those of the normal Al foil because the etched Al foil has rough surface with sub-micron pores which improve the adhesion between the electrode materials and the substrate. The electrode on the etched Al foil has such a strong peel strength that the impedance is smaller than that of normal one. Indeed the $LiFePO_4$ electrode from the etched Al foil exhibits a better rate capability and remains intact even after storage for 1 week at the charged state at the elevated temperature $60^{\circ}C$.

Designing Test Methods for IT-Enabled Energy Storage System to Evaluate Energy Dynamics

  • Kim, Young Gon;Kim, Dong Hoon;Lee, Eun-Kyu
    • Journal of Information Processing Systems
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    • v.13 no.6
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    • pp.1487-1495
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    • 2017
  • With increasing interests in renewables, more consumers are installing an energy storage system (ESS) in their backyards, and thus, the ESS will play a critical role in the emerging smart grid. Due to mechanical properties, however its operational dynamics must be well understood before connecting the ESS to the smart grid (and eventually to an IT system). To this end, we investigate charging and discharging processes in detail. This paper, then, proposes methods for four type tests (state of charge test, conversion efficiency test, response time test, and ramp rate test) that can assess the dynamics of the ESS. The proposed methods can capture accurate delay values of mechanical processes in the ESS, and it is expected for those values to help design real-time communication systems in the smart grid involving the ESS.

The photocatalytic water splitting into $H_2$ and $O_2$ mimicking a Z-scheme mechanism (광합성을 모사한 광촉매 물분해 수소 제조)

  • Jeon, Myung-Seok;Hong, Joon-Gi;Chun, Young-Gab;Choi, Ho-Suk
    • Journal of the Korean Solar Energy Society
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    • v.23 no.4
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    • pp.29-35
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    • 2003
  • We studied the water splitting into $H_2$ and $O_2$ using two different semiconductor photo catalysts and redox mediator, mimicking the Z-scheme mechanism of the photosynthesis, $H_2$ evolution took place on a Pt-$SrTiO_2$ (Cr-Ta doped) photocatalyst using $I^-$ electron donor under the visible light irradiation. The Pt-$WO_3$ photocatalyst showed an excellent activity of the $O_2$ evolution using $IO_3^-$ electron acceptor under visible light. $H_2$ and $O_2$ gases evolved in the stoichiometric ratio($H_2/O_2$=2) under visible light using a mixture of the Pt-$WO_3$ and Pt-$SrTiO_3$ (Cr-Ta doped) suspended in NaI aqueous solution. We proposed a two-step photo-excitation mechanism using redox mediator under the visible irradiation.