• Journal of Hydrogen and New Energy
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• v.26 no.3
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• pp.221-226
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• 2015

Ru catalysts supported on $CeO_2$ were synthesized by an impregnation method and characterized by numerous analytical techniques including X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), transmission electron microscopy (TEM), and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS). Upon utilization of these catalysts for methane dry reforming with a $CH_4/CO_2$ ratio of 1:1 at different temperatures ranging from 550 to $750^{\circ}C$, the $Ru/CeO_2$ catalysts have shown to be active. In particular, Ru(0.55wt%) supported on $CeO_2$ (1) prepared by a hydrothermal method exhibited excellent activity with the conversion of > 75% at $750^{\circ}C$. In addition, the catalyst also proved to be highly stable for at least 47 h without catalyst deactivation under the dry reforming conditions.

• Journal of Powder Materials
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• v.27 no.5
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• pp.394-400
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• 2020

Molybdenum trioxide (MoO₃) is used in various applications including sensors, photocatalysts, and batteries owing to its excellent ionic conductivity and thermal properties. It can also be used as a precursor in the hydrogen reduction process to obtain molybdenum metals. Control of the parameters governing the MoO₃ synthesis process is extremely important because the size and shape of MoO₃ in the reduction process affect the shape, size, and crystallization of Mo metal. In this study, we fabricated MoO₃ nanoparticles using a solution combustion synthesis (SCS) method that utilizes an organic additive, thereby controlling their morphology. The nucleation behavior and particle morphology were confirmed using ultraviolet-visible spectroscopy (UV-vis) and field emission scanning electron microscopy (FE-SEM). The concentration of the precursor (ammonium heptamolybdate tetrahydrate) was adjusted to be 0.1, 0.2, and 0.4 M. Depending on this concentration, different nucleation rates were obtained, thereby resulting in different particle morphologies.

• Corrosion Science and Technology
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• v.19 no.1
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• pp.37-42
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• 2020

Even though 304 low-carbon (304L) stainless steel was developed to enhance the resistance to intergranular corrosion and stress corrosion cracking, it is occasionally subject to degradation in harsh environments. The degree of sensitization (DOS) of 304L stainless steel was studied as a function of sensitization using a double-loop electrochemical potentiokinetic reactivation (DL-EPR) method. Sensitizing heat treatment was performed in an Ar atmosphere at 500℃, 600℃, and 700℃, with heat treatment times varying from 0 to 96 h. DOS was measured by the ratio of the peak current density value of the forward scan to that of the reverse scan. After the EPR experiment, the specimen surface was observed by scanning electron microscopy and energy dispersive spectroscopy. The DOS of the specimens heat-treated at 600℃ increased with heat treatment times up to 48 h and then decreased due to a self healing effect. The DOS was higher in specimens heat-treated at 600℃ than those at 500℃ or 700℃. Corrosion of the sensitized specimens occurred mainly at the δ-γ phase boundary. The corrosion morphology at the δ-γ phase boundary changed with sensitizing heat-treatment conditions due to differences in chromium activity in γ austenite and δ ferrite.

• Journal of Powder Materials
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• v.28 no.5
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• pp.417-422
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• 2021

In the present work, Inconel 718 alloy is additively manufactured on the Ti-6Al-4V alloy, and a functionally graded material is built between Inconel 718 and Ti-6Al-4V alloys. The vanadium interlayer is applied to prevent the formation of detrimental intermetallic compounds between Ti-6Al-4V and Inconel 718 by direct joining. The additive manufacturing of Inconel 718 alloy is performed by changing the laser power and scan speed. The microstructures of the joint interface are characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and micro X-ray diffraction. Additive manufacturing is successfully performed by changing the energy input. The micro Vickers hardness of the additive manufactured Inconel 718 dramatically increased owing to the presence of the Cr-oxide phase, which is formed by the difference in energy input.

• Journal of Powder Materials
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• v.29 no.4
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• pp.309-313
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• 2022

In this study, additive manufacturing of a functionally graded material (FGM) as an alternative to joining dissimilar metals is investigated using directed energy deposition (DED). FGM consists of five different layers, which are mixtures of austenitic stainless steel (type 316 L) and low-alloy steel (LAS, ferritic steel) at ratios of 100:0 (A layer), 75:25 (B layer), 50:50 (C layer), 25:75 (D layer), and 0:100 (E layer), respectively, in each deposition layer. The FGM samples are successfully fabricated without cracks or delamination using the DED method, and specimens are characterized using optical and scanning electron microscopy to monitor their microstructures. In layers C and D of the sample, the tensile strength is determined to be very high owing to the formation of ferrite and martensite structures. However, the elongation is high in layers A and B, which contain a large fraction of austenite.

• Proceedings of the KIEE Conference
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• 1999.11d
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• pp.924-925
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• 1999

Bi-system high-$T_c$ superconductors with the nominal composition $(Bi_{0.7}Pb_{0.3})_2-Sr_{2}Ca_{2}Cu_{3}O_{x}$ have been prepared by PJL method. The critical temperature (offset temperature) of the sample annealed for 13 hours in air was 102K. And the results of X-ray diffraction(XRD) patterns, scanning electron microscope (SEM) images and energy dispersive X-ray (EDX) spectra analyses, it was found that PJL method is so effective to reduce the heat treatment period.

• Journal of the Korean GEO-environmental Society
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• v.20 no.11
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• pp.5-10
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• 2019

For the development of long-wavelength responding photocatalyst, Ag was applied to commercial $TiO_2$ to produce $Ag/TiO_2$ photocatalyst. Moreover, micro-emulsion method was used in order to increase the efficiency of the photocatalyst by enhancing the dispersion of Ag. Physical properties of the manufactured catalyst were analyzed by scanning electron microscopy (SEM), field emission transmission electron microscopy (FE-TEM) and diffuse reflectance spectroscopy (DRS). For the catalytic performance measurement, RO 16 (Reactive Orange 16) removal was performed with 25 ppm RO 16 under UV-A (365 nm) irradiation. In addition, ball milling and dip-coating method were used to synthesize the photocatalyst for the comparison of the outcomes of using different synthesis methods. In addition, catalytic performance was improved by varying the Ag content and surfactant content. The highest catalytic performance was shown at $Ag/TiO_2$ synthesized by micro-emulsion method with 2 wt% of Ag content, and 0.5 g of the surfactant.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.612-621
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• 2018

In this study, $TiO_2$ nanotube plate and metal electrodes(Copper, Nickel, Stainless Steel, Aluminum, Tin, Titanium) were compared on cathodic reduction of nitrate ($NO_3{^-}-N$) during electrolysis. The electrochemical characteristics were compared based on electrochemical impedance spectroscopy (EIS). The surface morphology was obtained using scanning electron microscopy (SEM) method. Brunauer-Emmett-Teller (BET) method was implemented for the specific surface area analysis of the cathodes. To study kinetics, 90 minute batch electrolysis of nitrate solution was performed for each cathodes. In conclusion, under the condition of relatively low ($0.04 A\;cm^{-2}$) current density, $TiO_2$ nanotube plate showed no surface corrosion during the electrolysis, and the reaction rate was measured the highest in the kinetic analysis.

• Nuclear Engineering and Technology
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• v.54 no.3
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• pp.1062-1070
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• 2022

In the present communication, pure and stable α-Bismuth Oxide (Bi₂O₃) nanoparticles (NPs) were synthesized by low temperature solution combustion method using urea as a fuel and calcined at 500℃. The synthesized sample was characterized by using powder X-ray Diffraction (PXRD), Scanning Electron Microscopy (SEM), Energy dispersive X-ray analysis (EDAX), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FTIR) and UV-Visible absorption spectroscopy. The PXRD pattern confirms the formation of mono-clinic, stable and low temperature phase α-Bi₂O₃. The direct optical energy band gap was estimated by using Wood and Tauc's relation which was found to be 2.81 eV. The characterized sample was studied for X-ray/gamma ray shielding properties in the energy range 0.081-1.332 MeV using NaI (Tl) detector and multi channel analyzer (MCA). The measured shielding parameters agrees well with the theory, whereas, slight deviation up to 20% is observed below 356 keV. This deviation is mainly due to the influence of atomic size of the target medium. Furthermore an accurate theory is necessary to explain the interaction of X-ray/gamma ray with the NPs.The present work opens new window to use this facile, economical, efficient, low temperature method to synthesize nanomaterials for X-ray/gamma ray shielding purpose.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1997.10a
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• pp.887-890
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• 1997

Recently micromachining using DPSSL(Diode Pumped Solid State Laser) with 3rd harmonic wavelength is actively studied in laser machining area. Micromachining using DPSSL have outstanding advantages as UV source comparing with excimer laser in various aspect such a maintenance cost, maskless machining, high repetition rate and so on. In this study micro-drilling of PCB type substrate which consists of Cu-PI-Cu layer was performed using DPSS Nd:YAG laser(355nm, wavelength) in vector scanning method. Experimental and numerical method(Matlab simulation, FEM) are used to optimize process parameter and control machining depth. The man mechanism of this process is laser ablation. It is known that there is large gap between energy threshold of copper and that of PI. Matlab simulation considering energy threshold of material is performed to effect of duplication of pulse and FEM thermal analysis is used to predict the ablation depth of copper. This study could be widely used in various laser micromachining including via hole microdrilling of PCB, and micromachining of semiconductor components, medical parts and printer nozzle and so on.