• Title/Summary/Keyword: electrochemical devices

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Fabrication of petroleum pitch/polymer composite binder for anode material in lithium-ion battery (리튬이온 배터리용 음극 합금/폴리머 복합체 바인더 패브릭)

  • Hyeon Taek Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.40 no.6
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    • pp.1191-1200
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    • 2023
  • The lithium ion battery has applied to various fields of energy storage systems such as electric vehicle and potable electronic devices in terms of high energy density and long-life cycle. Despite of various research on the electrode and electrolyte materials, there is a lack of research for investigating of the binding materials to replace polymer based binder. In this study, we have investigated petroleum pitch/polymer composite with various ratios between petroleum pitch and polymer in order to optimize the electrochemical and physical performance of the lithium-ion battery based on petroleum pitch/polymer composite binder. The electrochemical and physical performances of the petroleum pitch/polymer composite binder based lithium-ion battery were evaluated by using a charge/discharge test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and universal testing machine (UTM). As a result, the petroleum pitch(MP-50)/polymer(PVDF) composite (5:5 wt % ratio) binder based lithium-ion battery showed 1.29 gf mm-1 of adhesion strength with 144 mAh g-1 of specific dis-charge capacity and 93.1 % of initial coulombic efficiency(ICE) value.

Field-induced Resistive Switching in Ge-Se Based ReRAM

  • Lee, Gyu-Jin;Eom, Jun-Gyeong;Jeong, Ji-Su;Jang, Hye-Jeong;Kim, Jang-Han;Jeong, Hong-Bae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.342-342
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    • 2012
  • Resistance-change Random Access Memory (ReRAM), which utilizes electrochemical control of nanoscale quantities of metal in thin films of solid electrolyte, shows great promise as a future solid state memory. The technology utilizes the electrochemical formation and removal of metallic pathways in thin films of solid electrolyte. Key attributes are low voltage and current operation, excellent scalability, and a simple fabrication sequence. In this study, we investigated the nature of thin films formed by photo doping of Ag+ ions into chalcogenide materials for use in solid electrolyte of programmable metallization cell devices. We measured the I-V characteristics by field-effect of the device. The results imply that a Ag-rich phase separates owing to the reaction of Ag with free atoms from chalcogenide materials.

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The State of the Art of the Fuel Cells (연료전지 기술현황)

  • Lee, Jin-Hong;ShunWoo, Hyun-Bum
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.3-12
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    • 1991
  • Fuel cells are electrochemical devices that convert the chemical reaction energy directly into the electrical energy. In a typical fuel cell, gaseous fuel is fed continuously to the anode(negative electrode) compartment and the oxidant(i.e, oxygen from air) is fed continuously to the cathode(positive electrode) compartment; the electrochemical reactions take place at the electrodes to produce an electric current. Many of the operational characteristics of fuel cell systems are superior to those of conventional power generation system because of good efficiency, environmental protection, safty, modularity etc. From those reasons, the fuel cells are considered to be the solution to the future problem of energy conversion. The objective of this paper is to introduce the technical status of fuel cell technologies and our national project for the development of the phosporic acid fuel cell.

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Resistive Switching Characteristics of Ag Doped Ge0.5Se0.5 Solid Electrolyte

  • Kim, Jang-Han;Nam, Ki-Hyun;Chung, Hong-Bay
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.478-478
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    • 2013
  • Resistance-change Random Access Memory (ReRAM) memory, which utilizes electrochemical control of metal in thin films of solid electrolyte, shows great promise as a future solid state memory. The technology utilizes the electrochemical formation and removal of metallic pathways in thin films of solid electrolyte. Key attributes are low voltage and current operation, excellent scalability, and a simple fabrication sequence. In this work, we investigated the nature of thin films formed by photo doping of Ag+ ions into chalcogenide materials for use in solid electrolyte of Resistance-change RAM devices and switching characteristics.

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The Fabrication of SOB SOI Structures with Buried Cavity for Bulk Micro Machining Applications

  • Kim, Jae-Min;Lee, Jong-Chun;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.739-742
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    • 2002
  • This paper described on the fabrication of microstructures by DRIE(deep reactive ion etching). SOI(Si-on-insulator) electric devices with buried cavities are fabricated by SDB technology and electrochemical etch-stop. The cavity was fabricated the upper handling wafer by Si anisotropic etch technique. SDB process was performed to seal the fabricated cavity under vacuum condition at -760 mmHg. In the SDB process, captured air and moisture inside of the cavities were removed by making channels towards outside. After annealing($1000^{\circ}C$, 60 min.), The SDB SOI structure was thinned by electrochemical etch-stop. Finally, it was fabricated microstructures by DRIE as well as an accurate thickness control and a good flatness.

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The Electrochemical Reaction Mechanism and Applications of Quinones

  • Kim, R. Soyoung;Chung, Taek Dong
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3143-3155
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    • 2014
  • This tutorial review provides a general account of the electrochemical behavior of quinones and their various applications. Quinone electrochemistry has been investigated for a long time due to its complexity. A simple point of view is developed that considers the relative stability of the reduced quinone species and the values of the first and second reduction potentials. The 9-membered square scheme in buffered aqueous solutions is explained and semiquinone radical stability is discussed in this context. Quinone redox reaction has also been employed in various studies. Diverse examples are presented under three broad categories defined by the roles of quinone: molecular tool for physical chemistry, versatile electron mediator, and charge storage for energy conversion devices.

Current Status and Roles of Proton Exchange Membrane in Direct Methanol Fuel Cell Systems (직접메탄올연료전지 시스템에서의 수소이온고분자전해질막의 역할 및 현황)

  • Kim, Hae-Kyoung
    • Journal of the Korean Electrochemical Society
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    • v.12 no.3
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    • pp.219-233
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    • 2009
  • Mobile devices in the next generation such as camera, cell phone, network, Note PC, etc. require higher power and energy sources due to convergences of various functions. Direct methanol fuel cell (DMFC) has been focused as an attractive power source, but there are critical issues involved in its commercialization with regard to the core technologies of materials, components, and system. The requirements of key technologies are differentiated from applications and fuel supply methods. Here, the roles of the proton-conducting membrane are discussed and the current status of DMFC systems is discussed in terms of proton conductivity, methanol permeability, and water management. Materials such as perfluorinated and partially fluorinated membranes, hydrocarbon membranes, composite membranes, and other modified ionomers have been studied. These would explain the critical issues of DMFC and the role of membranes for commercialization.

Solar-hydrogen Production by a Monolithic Photovoltaic-electrolytic Cell

  • Jeon, Hyo Sang;Min, Byoung Koun
    • Journal of Electrochemical Science and Technology
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    • v.3 no.4
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    • pp.149-153
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    • 2012
  • Among the various solar-hydrogen production techniques a combination of a photovoltaic (PV) and an electrolytic cell into one single system, a monolithic PV-electrolytic cell, has been suggested as a promising one in terms of efficiency and stability. In this mini-review, we describe our recent efforts on the fabrication of the monolithic PV-electrolytic cell. Particularly, we focus on the electrocatalysts for water oxidation and its fabrication method suitable for a monolithic PV-electrolytic cell. We also introduce proto-type devices with a dye-sensitized solar cell module and an InGaP/GaAs photoelectrodes.

Electrical Characteristics of n-GaN Schottky Diode fabricated by using Electrochemical Metallization (Electrochemical Metallization방법을 이용한 GaN Schottky Diode의 제작과 전기적 특성 향상 및 분석)

  • ;Daejun Fu
    • Proceedings of the IEEK Conference
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    • 2001.06b
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    • pp.205-208
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    • 2001
  • Schottky barrier diodes are fabricated on a intrinsic GaN(4${\mu}{\textrm}{m}$) epitaxial structure grown by rf plasma molecular beam epitaxy (MBE) on sapphire substrates. First, We make Ohmic electrodes (Ti/Al/Ti/Au) by evaporator. Next, we contact RuO$_2$ by dipping in the solution (RuCl$_3$.HClO$_4$), and then we deposit Ni/Au on the surface of RuO$_2$ by evaporator. We study the electrical characteristics of GaN Schottky barrier diodes made by these methods. Measurements are C-V, I-V, SEM, EDX, and XRD for the characteristics of devices. Thickness of RuO$_2$ layer depends on supplied voltage and dipping time. Device of thinner RuO$_2$ layer have a good Schottky characteristics compare with device of thicker RuO$_2$ layer

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