• Journal of the Korean Electrochemical Society
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• v.14 no.1
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• pp.38-43
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• 2011

Because the ionic liquid added with Propylene carbonate(PC) at room temperature has lower viscosity than original, we considered electrochemical behavior of it in EDLC. The ionic liquid without PC which does not have ions has no problem in capacity since it has enough ions. The electrolyte resistance was decreased with decreasing viscosity. As a result of identifying high current discharge capacity, we observed that the ionic liquid had capacity of 73.12% at current density of $80\;mA/cm^{-2}$, but it increased to 81.94% at PC content of 40 vol%.

• Journal of the Korean Electrochemical Society
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• v.6 no.4
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• pp.255-260
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• 2003

The complex capacitance analysis was performed in order to examine the potential-dependent EDLC characteristics of porous carbon electrodes. The imaginary capacitance profiles $(C_{im}\;vs.\;log\lf)$ were theoretically derived for a cylindrical pore and further extended to multiple pore systems. Two important electrochemical parameters in EDLC can be estimated from the peak-shaped imaginary capacitance plots: total capacitance from the peak area and $\alpha_0$ from the peak position. Using this method, the variation of capacitance and ion conductivity in pores can be traced as a function of electric potential. The electrochemical impedance spectroscopy was recorded on the mesoporous carbon electrode as a function of electric potential and analyzed by complex capacitance method. The capacitance values obtained from the peak area showed a maximum at 0.3V (vs. SCE), which was in accordance with cyclic voltammetry result. The ionic conductivity in pores calculated from the peak position showed a maximum at 0.2 V (vs. SCE), then decreased with an increase in potential. This behavior seems due to the enhanced electrostatic interaction between ion and surface charge that becomes enriched at more positive potentials.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.11a
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• pp.683-686
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• 2004

In recent years, the supercapacitor and hybrid capacitor have related with substitutional energy source focused of many scientists because of their usage in power sources for electric vehicles, computers and other electric devices. The storage energy of electrical charge is based on electrostatic interactions in the electric double layer at the electrode/electrolyte interface, resulting in high rate capability and long cycle performance compared with batteries based on Faradaic electrode reactions. So we have been considered to carbon nanofibers as the ideal material for supercapacitors due to their high utilization of specific surface area, good conductivity, chemical stability and other advantages. In this work, we aimed to find out that the capacitance have increased because of electrochemical capacitance to provide by carbon nanofibers. Also carbon nanofibers based on chemical method and water treatment have been resulted larger capacitances and also exhibit better electrochemical behaviors about 15% than before of nontreated state. And also optical observations with treated and nontrteated carbon nanofibers discussed by the TEM, SEM, EDX, BET works and specific surface area analyzer. Their results also focused on the surface area of electrode and electrical capacitance was also improved by the effect of surface treatments.

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.407-412
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• 2008

As an activation procedure, in this study, the oxidation treatment of needle cokes with a dilute nitric acid and sodium chlorate $(NaClO_3)$, combined with heat treatment, was attempted. The structures of acid-treated and pyrolyzed coke were examined with XRD, FESEM, elemental analyzer, BET, and Raman spectroscopy. The behavior of double layer capacitance was investigated with the analysis of charge and discharge. The structure of needle coke treated with acid was revealed to a single phase of (001) diffraction peak after 24 h. On the other hand, thecoke oxidized by heat treatment was reduced to a graphite structure of (002) at $300^{\circ}C$. The distorted graphene layer structure, derived from the process of oxidation and reduction of the inter-layer, makes the pores by the electric field activation at the first charge, and generates the double layer capacitance from the second charge. The cell using pyrolyzed coke with 24 h acid treatment and $300^{\circ}C$ heat treatment exhibited the maximum capacitance per weight and volume of 33 F/g and 30 F/mL at the two-electrode system in the potential range of 0~2.5 V.

• Proceedings of the KIEE Conference
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• 2008.04c
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• pp.227-229
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• 2008

태양광/풍력 복합발전시스템은 친환경적인 에너지원의 대표적인 복합발전시스템이다. 본 논문에서는 독립형 태양광/풍력 발전시스템을 이용한 가로등 시스템을 구성하여 출력특성을 고찰하였다. 풍력에서 발전된 교류전력을 DC로 변환하여 태양광발전에서 출력된 DC 전력과 공통 DC버스로 전달되도록 하였으며, 공통 직류단 병렬운전을 위해 출력전압을 일치시켰다. 또한 슈퍼캐패시터를 적용하여 발전된 전력의 배터리 충전매체로 활용하여 시스템의 안정성을 높이고 충방전 효율을 증가시키고자 하였다.

• Journal of the Korean Electrochemical Society
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• v.6 no.2
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• pp.141-144
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• 2003

Proton conducting polymeric gels as the electrolytes of electrochemical capacitors have been prepared by two different methods: 1) swelling a polymethacrylate-based polymer matrix in aqueous solutions of inorganic and organic acids, and 2) polymerizing complexes of anhydrous acids and prepolymers with organic plasticizer. The FT-IR spectra strongly suggest that the carbonyl groups in the polymer matrix interact with protons from the doped acids. High ionic (proton) conductivity in the range of $6\times10^{-4}-4\times10^{-2}\;S\;cm^{-1}$ was obtained at room temperature for the aqueous gels. The non-aqueous polymer complexes showed rather low ionic conductivity, but it was about $10^{-3}\;S\;cm^{-1}\;at\;70^{\circ}C$ for the $H_3PO_4$ doped polymer electrolyte. The mechanisms of ion (proton) conduction in the polymeric systems are discussed.

• Proceedings of the KIEE Conference
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• 2011.07a
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• pp.1292-1293
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• 2011

Electric double layer capacitor (EDLC) is used to overcome power quality problem caused by output power oscillation of wind turbines. A novel EDLC application for permanent magnet synchronous generator type wind power generation system is proposed in this paper. The structure of the proposed system is cost-effective and efficient. The proposed system including an EDLC is modeled and analyzed by PSCAD/EMTDC. The simulation results show the effectiveness and major features of the proposed system.

• Journal of the Korean Applied Science and Technology
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• v.28 no.2
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• pp.225-231
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• 2011

The electrochemical characteristics of electric double layer capacitor(EDLC) were investigated using various carbon materials. The physical properties such as specific surface area and mean pore size of activated carbon were analyzed by BET. The results of the activated carbon used for electrode material showed that the specific surface areas varied from 600 to 1500 $m^2$/g and mean pore sizes from 1.74 to 2.88 nm. A maximum specific capacitance of 0.30 F/$cm^2$ was obtained for the activated carbon with the highest specific surface area and ionic conductivity. Also, it was found that the electrochemical results of the cyclic charge-discharge tests were stable.

• Proceedings of the KIPE Conference
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• 2013.07a
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• pp.388-389
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• 2013

This paper presents the method for the fluctuation smoothing control by using relaxation time variable control of battery. When the output power of wind farm is changed suddenly, it is necessary to control the output power of wind farm. The smoothing relaxation time is changed within limits of battery output power. Using the hybrid energy storage system (HESS) combined with battery energy storage system and electric double layer capacitor, it is possible to control the output power of wind farm. The capacity of battery is determined by considering the case of the disconnecting wind farm from the grid. To verify the proposed method, simulations are carried out by using PSCAD/EMTDC with actual data of wind farm in the Jeju Island.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.1099-1101
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• 2007

In this paper, a study has been performed for development of dynamic voltage restorer(DVR) system using EDLC (Electric Double Layer Capacitor) to solve voltage sags which are considered the dominant disturbances affecting power quality. With the prolific use of semiconductor devices in electrical equipment, modern-day loads are becoming increasingly sensitive to the sags and the disturbances prove to be costly to industries. As a technology-driven custom power installation, the Dynamic Voltage Restorer (DVR) is recognized to be most effective equipment that can be used to counter the voltage sag problem. Hence, this paper proposes the high-performance optimal design of On-Line type DVR system which can efficiently compensate the instantaneous voltage sag and instantaneous interruption of the utility voltage source.