• Title/Summary/Keyword: effective grain size

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The improvement in the properties of $(Ba, Sr)TiO_3$films by the application of amorphous layer (비정질 $(Ba, Sr)TiO_3$층의 도입을 통한 $(Ba, Sr)TiO_3$박막의 특성 향상)

  • 백수현;이공수;마재평;박치선
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.221-226
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    • 1998
  • Amorphous (Ba, Sr)$TiO_3$[BST] layer(30, 70 nm) was introduced between crystalline BST and $RuO_2$electrode to realize double-layered BST structure in order to improve the properties of BST film. The structure and surface morphology of double-layered BST film were modified by the application of amorphous BST layer; that is, surface became smoother and grain size increased abruptly. Amorphous layer thicker than 30 nm was effective to hinder the influence of $RuO_2$surface on the structure of as-grown BST films by in-situ process. Dielectric constant of double-layered BST film was improved dramatically from 152 to 340 and leakage current was lowered from $1.25{\times}10^{-5}A/{\textrm}{cm}^2);to;6.85{\times}10^{-7}A/{\textrm}{cm}^2$, respectively.

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Effect of Nb Doping on the Dielectric and Strain Properties of Lead-free 0.94(Bi1/2Na1/2)TiO3-0.06BaTiO3 Ceramics

  • Han, Hyoung-Su;Hong, In-Ki;Kong, Young-Min;Lee, Jae-Shin;Jo, Wook
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.145-149
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    • 2016
  • $(Bi_{1/2}Na_{1/2})_{0.94}Ba_{0.06}(Ti_{1-x}Nb_x)O_3$ (BNBTxNb) ceramics were investigated in terms of the crystal structure as well as the ferroelectric, dielectric, and piezoelectric properties. While little change was observed in the microstructure except for a slight decrease in the average grain size, a significant change was noticed in the temperature dependence of dielectric and piezoelectric properties. It was shown that the property changes are closely related to the downward shift in the position of the ferroelectric-to-relaxor transition temperature with increasing amount of Nb doping. A special emphasis is put on the fact that Nb doping is so effective at decreasing the ferroelectric-to-relaxor transition temperature that even at no more than 2 at.% Nb addition, the transition temperature was already brought down slightly below room temperature, resulting in the birth of a large strain at 0.46 %, equivalent to $S_{max}/E_{max}=767pm/V$.

Preparation and Evaluation of the Properties of Al-doped Zinc Oxide (AZO) Films Deposition by Rapid Thermal Annealing (급속 열처리 방법에 의한 Al-doped Zinc Oxide (AZO) Films의 제조 및 특성 평가)

  • Kim, Sung-Jin;Choi, Kyoon;Choi, Se-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.7
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    • pp.543-551
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    • 2012
  • In this study, transparent conducting Al-doped Zinc Oxide (AZO) films with a thickness of 150 nm were prepared on corning glass substrate by the RF magnetron sputtering with using a Al-doped zinc oxide (AZO), ($Al_2O_3$: 2 wt%) target at room temperature. This study investigated the effect of rapid thermal annealing temperature and oxygen ambient on structural, electrical and optical properties of Al-doped zinc oxide (AZO) thin films. The films were annealed at temperatures ranging from 400 to $700^{\circ}C$ by using Rapid thermal equipment in oxygen ambient. The effect of RTA treatment on the structural properties were studied by x-ray diffraction and atomic force microscopy. It is observed that the Al-doped zinc oxide (AZO) thin film annealed at $500^{\circ}C$ at 5 minute oxygen ambient gas reveals the strongest XRD emission intensity and narrowest full width at half maximum among the temperature studied. The enhanced UV emission from the film annealed at $500^{\circ}C$ at 5 minute oxygen ambient gas is attributed to the improved crystalline quality of Al-doped zinc oxide (AZO) thin film due to the effective relaxation of residual compressive stress and achieving maximum grain size.

Structure and Magnetic Properties of Cr2O3/CrO2 Nanoparticles Prepared by Reactive Laser Ablation and Oxidation under High Pressure of Oxygen

  • Si, P.Z.;Wang, X.L.;Xiao, X.F.;Chen, H.J.;Liu, X.Y.;Jiang, L.;Liu, J.J.;Jiao, Z.W.;Ge, H.L.
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.211-214
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    • 2015
  • $Cr_2O_3$ nanoparticles were prepared via one-step reactive laser ablation of Cr in oxygen. The metastable $CrO_2$ phase was obtained through the subsequent oxidation of $Cr_2O_3$ nanoparticles under $O_2$ with gas pressures of up to 40 MPa. The as-prepared $Cr_2O_3$ nanoparticles are spherical or rectangular in shape with sizes ranging from 20 nm to 50 nm. High oxygen pressure annealing is effective in producing meta-stable $CrO_2$ from as-dried $Cr_2O_3$ nanoparticles, and the $Cr_2O_3$ nanoparticles exhibit a weak ferromagnetic behavior with an exchange bias of up to 11 mT that can be ascribed to the interfacial exchange coupling between uncompensated surface spins and the antiferromagnetic core. The $Cr_2O_3/CrO_2$ nanoparticles exhibit an enhanced saturation magnetization and a reduced exchange bias with an increasing faction of $CrO_2$ due to the elimination of uncompensated surface spins over the $Cr_2O_3$ nanoparticles when exposed to a high pressure of $O_2$ and/or possible phase segregation that results in a smaller grain size for both $Cr_2O_3$ and $CrO_2$.

Evaluation of CPTU Cone Factor of Silty Soil with Low Plasticity Focusing on Undrained Shear Strength Characteristics (저소성 실트지반의 비배수 전단강도 특성을 고려한 CPTU 콘계수 평가)

  • Kim, Ju-Hyun
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.1
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    • pp.73-83
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    • 2017
  • Laboratory and in-situ tests were conducted to evaluate the cone factors for the layers with low plasticity containing a lot of silty and sand soils from the west coast (Incheon, Hwaseong and Gunsan areas) and its applicability was evaluated based on these results. The cone factors were evaluated from 19 to 23 based on unconfined compression strengths (qu), from 13 to 13.8 based on simple CU strengths and from 11.6 to 13.1 based on field vane strengths, respectively. The unconfined compression strengths of undisturbed silty soil samples with low plasticity were considerably underestimated due to the change of in-situ residual effective stress during sampling. Half of unconfined compression strength (qu/2) based cone factors of silty soils with low plasticity fluctuated and were approximately 1.8 times higher than simple CU based values of these soils. When evaluating cone factors of these soils, it should be judged overall on the physical properties such as the grain size distribution and soil plasticity and on the fluctuation of the corrected cone resistance and the sleeve friction due to the distribution of sandseam in the ground including pore pressure parameter.

The Study on the Engineering Characteristics by Self-Hardening of Coal Ash (석탄회의 자경성에 따른 공학적 특성연구)

  • Sang, Jung-Hyuk;Shin, Woong-Gi;Kim, Ji-Won;Chun, Byung-Sik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09b
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    • pp.81-87
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    • 2010
  • As enormous construction projects of land development are carried out around Korea, useful construction materials are needed to perform the construction projects. However, there are no more enough of fill and reclamation materials in our country. That is why the coal ash is expected to be utilized as an alternative material. Since the coal ash has the characteristics of a pozzolan and a selfhardening material, it is adjudged that coal ash has a great possibility to be used as a fill and reclamation material. In this study, grain size analysis, Atterberg limit test, and specific gravity test were performed to examine the physical characteristics of the coal ash about a self-hardening material before utilizing the coal ash in the construction. Compaction test, unconfined compression test were conducted to investigate the engineering characteristics according to mixture ratios of fly ash and bottom ash. As a result of the tests, it was confirmed that the mixing ratio 1:1 of fly ash and bottom ash is the most effective to use as a fill and reclamation material. If the mixture of coal ash is used as a backfill material with light weight around structure, it is expected to play a significant role in reducing earth pressure on the back of the structure. As described above, the coal ash should be considered as an alternative material of fill and reclamation materials since the result of the tests indicates that the coal ash is suitable to a useful material on the construction design.

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Cyclic Voltammetry Study on Electrodeposition of CuInSe2 Thin Films (Cyclic Voltammetry를 이용한 CuInSe2 박막의 전기화학적 전착 연구)

  • Hong, Soonhyun;Lee, Hyunju;Kim, Yangdo
    • Korean Journal of Materials Research
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    • v.23 no.11
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    • pp.638-642
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    • 2013
  • Chalcopyrite $CuInSe_2$(CIS) is considered to be an effective light-absorbing material for thin film photovoltaic solar cells. CIS thin films have been electrodeposited onto Mo coated and ITO glass substrates in potentiostatic mode at room temperature. The deposition mechanism of CIS thin films has been studied using the cyclic voltammetry (CV) technique. A cyclic voltammetric study was performed in unitary Cu, In, and Se systems, binary Cu-Se and In-Se systems, and a ternary Cu-In-Se system. The reduction peaks of the ITO substrate were examined in separate $Cu^{2+}$, $In^{3+}$, and $Se^{4+}$ solutions. Electrodeposition experiments were conducted with varying deposition potentials and electrolyte bath conditions. The morphological and compositional properties of the CIS thin films were examined by field emission scanning electron microscopy (FE-SEM) and energy dispersive spectroscopy (EDS). The surface morphology of as-deposited CIS films exhibits spherical and large-sized clusters. The deposition potential has a significant effect on the film morphology and/or grain size, such that the structure tended to grow according to the increase of the deposition potential. A CIS layer deposited at -0.6 V nearly approached the stoichiometric ratio of $CuIn_{0.8}Se_{1.8}$. The growth potential plays an important role in controlling the stoichiometry of CIS films.

Study on the Core Loss Improvement of SiFe Plate in Relation with Laser Pulse Width in the Laser Scribing (레이저 스크라이빙에 있어서 레이저의 펄스폭에 따른 규소강판의 코어손실 개선 연구)

  • Ahn, Seung-Joon;Park, Chul-Geun;Ahn, Seong-Joon
    • Journal of the Korean Magnetics Society
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    • v.15 no.6
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    • pp.320-324
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    • 2005
  • The core loss of $3\%$ SiFe is strongly dependent on silicon content, impurities, permeability, and domain structure of the SiFe. Domain refining has been proved to be very good method for reduction of core loss in high permeability grain oriented SiFe, and laser scribing is well-blown as an effective and industrially important method of domain refinement. In this work, magnetic domain refinement has been carried out by using a pulsed Nd : YAG laser, and the core losses have been measured and analyzed to and optimal parameters of the laser treatment. The laser hem was focused with a spot size of $100{\mu}m$ and pulse energy of 10${\~}$35mJ and the lines were scribed with a period of ${\~}$5mm. The core loss was improved up to $17\%$ with 30 ns-Nd : YAG laser beam in $3\%$ SiFe.

Seasonal Variation of Surface Sediments in the Kwangseungri Beach, Gochanggun, Korea (고창군 광승리 해빈 표층 퇴적물의 계절 변화)

  • So, Kwang-Suk;Ryang, Woo-Hun;Choi, Sin-Lee;Kwon, Yi-Kyun
    • Journal of the Korean earth science society
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    • v.33 no.6
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    • pp.497-509
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    • 2012
  • The Gochanggun Kwangseungri macro-tide open-coast beach, located in the southwestern coast of Korea, was investigated in terms of the seasonal variations of surface sediment facies and sedimentary environment. Surface sediments of 45 sites in four seasons (May 2006 - February 2007) were sampled along three survey lines (15 sites in each survey line). The surface sediments of the Kwangseungri Beach are mainly composed of fine-grained sands, and its mean grain size is the coarsest in winter. Mud facies partly exists in summer, whereas it is nearly absent in winter. The spatial distribution of surface sediments shows a coast-parallel band of fine and medium sands during spring, fall, and winter. In the northern part, the study area is dominated by fine sands during summer, whereas by coarse sands during winter. These results can be interpreted that tide is more effective than wave on the surface sediment distribution of the Kwangseungri Beach during the summer season.

A Study on the Engineering Properties of Micro Fine Hybrid Silicate Grout Materials (마이크로 복합실리카 그라우트재의 공학적 특성에 관한 연구)

  • Chun, Byung-Sik;Kim, Jin-Chun;Choi, Young-Chul;Jung, Jong-Ju;Yoon, Nam-Sik;Shin, Sang-Jae
    • Journal of the Korean GEO-environmental Society
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    • v.2 no.1
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    • pp.67-79
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    • 2001
  • The objective of this study is to determine the engineering properties of micro fine hybrid silicate grout materials that were developed recently. In this study, MSG-N type was mainly used as grout materials, and the chemical components, grain size distribution, mineral characteristics were analyzed. Moreover, the properties of active silica and ordinary portland cement acting as coagulating agent were analyzed and compared with each other. To determine the engineering properties, the bleeding test, viscosity test, coagulation test, examination with naked eye, photographing by using SEM, uniaxial compression test and in-situ application test for reclaimed ground were carried out. A series of test results showed that the strength of micro fine hybrid silicate grout materials was about twice that of ordinary sodium silicate grout materials, and alkali leakage decreased dramatically when MSG method was utilized. Especially, based on the evaluation of the application of the MSG method to field, this method would be very effective in reducing coefficient of permeability due to its excelent permeability.

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