• Bulletin of the Korean Chemical Society
• /
• v.25 no.5
• /
• pp.609-616
• /
• 2004

Complexation of cesium ion by p-tert-butylcalix[6]arene ethyl ester was studied by NMR spectroscopy in nonpolar $CDCl_3$ and polar acetone-$d_6$ and the results were compared with each other. Analysis of temperature dependent $^1H$ spectra and titration curves reveals that both solvents result in a 1 : 1 cone-form complex with nonpolar $CDCl_3$yielding a more tightly bound one than acetone-$d_6$. Unexpectedly, at very low temperature, we have found that two phenyl ring proton peaks of equal intensity appear both in $CDCl_3$and in acetone-$d_6$ solution which gradually collapse and eventually coalesce into a single line as temperature is raised. This observation could be interpreted in terms of the chemical exchange through direct and/or indirect interconversion between two equivalent conformations possible the complex in both solvents over the temperature range observed. And broadening of $^{133}Cs$ (I = 7/2) nmr line with increasing temperature has also been observed, indicating the exchange of $^{133}Cs$ ion between the complex and the solvent. From numerical fitting of lineshape changes for one-dimensional $^1H$ and $^{133}Cs$ spectra, the exchange rate constants and other relevant parameters for this conformational interconversion and the complex-solvent exchange were deduced.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.12 no.1
• /
• pp.73-81
• /
• 2002

This paper introduces a four-Pole Lorentz force type self-bearing motor in which a new winding configuration is proposed to enable the sing1e winding to function both as a synchronous PM motor and as a magnetic bearing. The Lorentz force type has some good points such as the linearity of control force, freedom from flux saturation, and high efficiency, unlike conventional self-bearing motors using a reluctance force. And also, compared with the previously proposed eight-pole type, this four-pole self-bearing motor is more profitable for high rotational speed. In this paper, mathematical expressions of torque and radial force in the proposed self-bearing motor are derived to show that they can be separately controlled regardless of rotational speed and time. For verification of the theory, a prototype is made, where a ring-shape outer rotor is actively controlled in two radial directions while the other motions are passively stable supposing the radial stability. Through some experiments. it is shown that the proposed scheme can provide high capability and feasibility for a small high-speed self-bearing motor.

• Proceedings of the KIEE Conference
• /
• 2008.07a
• /
• pp.1697-1698
• /
• 2008

PLS(Pohang Light Source) is 2.5 Gev synchrotron radiation source in Pohang, Korea, which is under operation since 1995. The hardware and software of the old BPM(Beam Position Monitor) data acquisition system for the PLS storage ring was completely upgraded to increase its performance and stability. The new BPM data acquisition system is based on VME-based EPICS (Experimental Physics and Instrument Control System) IOC system. We used 16-bit resolution analog-to-digital conversion board to digitize analog BPM signals. We developed a data average software to average raw BPM data using reflective memory board. We also developed device drivers for VME I/O boards used, IOC database for PV's(Process Variables). The new BPM data acquisition system is currently running for routine operation with good performance and stability. In this paper, we present the hardware and software of the new BPM data acquisition system DTL water skid cooling system and Resonant Control Cooling.

• Bulletin of the Korean Mathematical Society
• /
• v.53 no.5
• /
• pp.1341-1352
• /
• 2016

Let R be a commutative Noetherian ring, ${\Phi}$ a system of ideals of R and $I{\in}{\Phi}$. In this paper among other things we prove that if M is finitely generated and $t{\in}\mathbb{N}$ such that the R-module $H^i_{\Phi}(M)$ is $FD_{{\leq}1}$ (or weakly Laskerian) for all i < t, then $H^i_{\Phi}(M)$ is ${\Phi}$-cofinite for all i < t and for any $FD_{{\leq}0}$ (or minimax) submodule N of $H^t_{\Phi}(M)$, the R-modules $Hom_R(R/I,H^t_{\Phi}(M)/N)$ and $Ext^1_R(R/I,H^t_{\Phi}(M)/N)$ are finitely generated. Also it is shown that if cd I = 1 or $dimM/IM{\leq}1$ (e.g., $dim\;R/I{\leq}1$) for all $I{\in}{\Phi}$, then the local cohomology module $H^i_{\Phi}(M)$ is ${\Phi}$-cofinite for all $i{\geq}0$. These generalize the main results of Aghapournahr and Bahmanpour [2], Bahmanpour and Naghipour [6, 7]. Also we study cominimaxness and weakly cofiniteness of local cohomology modules with respect to a system of ideals.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2003.07a
• /
• pp.286-289
• /
• 2003

In the case of high voltage devices, junction termination plays an important role in determining the breakdown voltage of the device. The mesa junction termination has been demonstrated to yield nearly ideal breakdown voltage for 6H-SiC p-n junctions. However, such an approach may not be attractive because of the nonplanar surface, which is difficult to passivate. Moreover, In case of 4H-SiC, ideal breakdown voltage could not be achieved using mesa junction termination. For 4H-SiC planar junction termination technique is more useful one rather than mesa junction termination. In this paper, breakdown characteristics of the 4H-SiC device with planar junction termination, such as FLR(Field Limiting Ring), FP(Field Plate) and JTE(Junction Termination Extension), is presented. In the case of the FLR, breakdown voltage of 1800V is obtained. And breakdown voltage of 1000V and 1150V is also obtained for the case of FP and JTE case, respectively.

• Journal of Korean Society for Atmospheric Environment
• /
• v.20 no.3
• /
• pp.331-343
• /
• 2004

The results of individual PAH source profiles that can be applied to receptor model are as follows. The sum of 16 PAH concentrations was 391.41 ng/S㎥ in a tunnel. Phenanthrene was the most abundant compound among 16 PAH, and then pyrene, fluoranthene, anthracene, and naphthalene can be seen in elevated contents. 11,056.61 ng/S㎥ of 16 PAH concentrations in BC oil boiler was two times higher than 6,582.57 ng/S㎥) of those in LNG boiler. Naphthalene was the most abundant compound in both facilities. Phenanthrene, anthracene, and acenaphthylene were the second dominant compound group in order from both facilities. BC oil boiler had relatively high concentration of pyrene compared to LNG boiler that had high concentration of fluorene and did not detect pyrene. The sum of 16 PAH concentrations emitted from MSW incinerators after APCD (air pollution control device) was three times higher than those from MSW incinerators before APCD. However, the concentrations of more than 4-ring PAH compounds (e.g., benzo (a)anthracene) before APCD were higher than those after APCD. This fact implies that PAHs generated by combustion process are eliminated in APCD and they are continuously produced in stack or atmosphere by PAHs precursors.

• Asian Journal of Atmospheric Environment
• /
• v.5 no.1
• /
• pp.56-63
• /
• 2011

Quantifying the solute composition of a cloud droplet (or a whole droplet) is an important task for understanding formation processes and heating/cooling rates. In this study, a combination of droplet fixation and SR-XRF microprobe analysis was used to visualize and quantify elements in a micro-scale droplet. In this study, we report the preliminary outcome of this experiment. A spherical micro-scale droplet was successfully solidified through exposure to ${\alpha}$-cyano-acrylate vapor without affecting its size or shape. An X-ray microprobe system equipped at the beam line 37XU of Super Photon ring 8 GeV (SPring-8) was applied to visualize and quantify the elemental composition in an individual micro-scale droplet. It was possible to reconstruct 2D elemental maps for the K and Cl contained in a microdroplet that was dispensed from the 10-ppm KCl standard solution. Multi-elemental peaks corresponding to X-ray energy were also successfully resolved. Further experiments to determine quantitative measures of elemental mass in individual droplets and high-resolution X-ray microtomography (i.e., 3D elemental distribution) are planned for the future.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2000.11a
• /
• pp.171-176
• /
• 2000

Bioremediation of hazardous hydrophobic organic compounds, such as polycyclic aromatic hydrocarbons (PAHs), is a major environmental concern due to their toxic and carcinogenic properties. Due to their hydrophobicity, the hydrophobic organic compounds are mainly associated with the soil organic matter or nonaqueous-phase liquids. A major question concerns the relationships between biodegradation and sorption. This work develops and utilizes a non- steady state model for evaluating the interactions between sorption and biodegradation of phenanthrene, a 3-ring PAH compound, in soil-slurry systems. The model includes sorption/desorption of a target compound, its utilization by microorganisms as a primary substrate existing in the dissolved phase and/or the sorbed phase in biomass and soil, oxygen transfer, and oxygen utilization as an electron acceptor. Biodegradation tests with phenanthrene were conducted in liquid and soil-slurry systems. The soil-slurry tests were performed with very different mass transfer rate: fast mass transfer in a flask test at 150 rpm, and slow mass transfer in a roller-bottle test at 2 rpm. In the slurry tests, phenanthrene was degraded more rapidly than in liquid tests, but with a similar rate in both slurry systems. Modeling analyses with several hypotheses indicate that a model without biodegradation of compound sorbed to the soil was not able to account for the rapid degradation of phenanthrene, particularly in the roller bottle slurry test. Reduced mass-transfer resistance to bacteria attached to the soil is the most likely phenomenon accounting for rapid sorbed-phase biodegradation.

• Journal of Chest Surgery
• /
• v.30 no.4
• /
• pp.423-427
• /
• 1997

Hemoptysis occurs quite frequently as a consequence of mitral stenosis, but massive, lirE threatening pulmonary hemorrhage is distinctly unusual. We report a 30 year old female who underwent cmcrgcncy rcdo double valve replacement for intractable pulmonary hemorrhage. she underwent mitral valve replacement (lonescu Shirley 27 mm) due to rheumatic valvular heart disease in 1984 and tricuspid valve annuloplasty (Carpentier's rlng 30mm) two years later She was admitted for massive hcmoptysis and dyspnea on the 26th of December, 1995. Medical treatment including transarterial embolization was given but was not satisfactory. Emergency valve replacement (Mitral valve , 51. Judc 29mm and tricuspid valve ; 51. Jude 33mm) was performed and hemoptysis was controlled dramatically 24 hours after surgery.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.315-315
• /
• 2010

양성자 빔을 이용하여 두경부 암 치료를 South Africa의 iTHEMBA에서 시행하고 있다. 200 MeV의 양성자 빔라인으로부터 진공에서 대기로 인출하여 노즐을 통과하여 종양세포에 조사된다. 치료계획에 적합하게 빔에너지와 모양을 변환하고, 빔을 모니터링하는 기계적 장치들이 노즐에 구성된다. 빔라인에는 이온챔버, Steering Magnet, Multi-wire 이온챔버, Range trimmer plates, lead scattering plate, Double-wedge energy degrader, Multi-layer Faraday cup, Range modulator, Range monitor, occluding ring, Shielding collimators, Quadrant and monitor ionization chamber, Treatment collimator, 그리고 Wellhofer dosimetry tank로 구성되어 있다. 총길이는 6.6m이며 노즐 끝에서 환자의 isocenter 까지는 30cm 정도 아래에 위치한다. 상기의 배치를 갖는 시스템의 양성자 scattering system의 성능을 MCNPX v2.5.0 Monte Carlo simulation을 실시하였다. 또한 정확한 선량을 실시간으로 측정하는 방법인 투과형 검출기를 개발하여 치료와 빔 특성을 동시에 수행하는 기술개발연구가 보고되고 있다. 본 연구에서는 Multileaf Faraday Cup (MLPC) 검출기 설계구조와 데이터 측정방법에 관한 연구를 수행하고자 한다. 빔의 전송 방향으로 3개층의 $4{\times}4$ 배열의 구조로 48 channel의 전류값을 측정하여 입자빔의 분포를 실시간으로 관측하고, 측정된 전류는 ADC를 거쳐 치료계획에 의해 선택된 영역의 SOBP를 유지하도록 range modulation propeller를 조절하는 feed-back system을 갖춘 방사선치료빔 실시간 측정장치 개발에 관한 결과를 보고하고자 한다.