• Title/Summary/Keyword: distribution of chemical species

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A Study on the Fuel Quality Characteristics and Cold Weather Performance Test for Biodiesel Derived from Microalgae (미세조류 유래 바이오디젤 품질 특성 및 차량 저온 성능평가 연구)

  • JEON, CHEOL-HWAN;PARK, CHEON-KYU;LIM, JAE-HYUK;RYU, YOUNG-JIN;YANG, JI-HYUN;SHIM, SANG-HYEOK;CHO, YONG-HEE;KIM, KI-HYUN;PARK, HANWOOL;KIM, JUN-HO;PARK, JAEHOON;JUNG, INJAE;KANG, SUNG-MO;SHIN, DONG-WOO;LIM, SANG-MIN;LEE, CHOUL-GYUN;NA, BYUNG-KI
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.5
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    • pp.545-553
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    • 2017
  • Microalgae can offer an attractive way of generating renewable and sustainable biodiesel. Biodiesel derived from microagae can have lower impact on the environment and food supply than biodiesel produced from crops. But biodiesel derived from microagae have poor fuel properties at low temperature depending on their species. In this study, it was investigated that fuel characteristics of biodiesel derived from Tetraselmis sp. and cold weather performance of biodiesel blend (BD3, 3 vol.% biodiesel - 97 vol.% diesel). The startability and operability of the passenger car in BD3 was good at $-20^{\circ}C$.

Water Quality and Structure of Aquatic Ecosystem in Water Source, Lake Gachang (상수원 호소인 가창호의 수질과 수생태계의 계절적 변화)

  • Park, Yeon-Jeong;Lee, Hae-Jin;Seo, Jung-Kwan;Tak, Bo-Mi;Jeong, Hyun-Gi;Lee, Jae-Kwan
    • Korean Journal of Environmental Biology
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    • v.29 no.4
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    • pp.296-304
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    • 2011
  • This study was carried out to investigate the relation between water quality and structure of the aquatic ecosystem in the Lake Gachang from February to December in 2010. The annual mean COD (Chemical Oxygen Demand) in Lake Gachang was 3.5 mg $L^{-1}$, indicating, level II of environmental standards and the trophic state was mesotrophic. The seasonal succession of phytoplankton showed that Bacillariophyceae was mostly dominant species throughout the year except August. In case of zooplankton, rotifers dominate in the most seasons, but copepod (Nauplii) in August. The macrophyte plants showed diverse species composition consisted of 9 varieties, 77 species, 64 genera, 34 families and 24 orders. Surveyed species of macroinvertebrates were classified into 1 phyla, 2 classes, 4 orders, 7 families, 9 species. The macroinvertebrates showed FFG (Functional Feeding Groups) such as GC (Gathering-Collector) and SH (Shedder). A total of 42 species of fish was collected including $Zacco$ $koreanus$ and $Coreoperca$ $herzi$. In this study, we investigated environmental factors including pollutant source, load, water quality and distribution characteristics of biota such as phytoplankton, zooplankton, macrophyte plants, macroinvertebrates, fish.

Secondary Metabolites with Anti-complementary Activity from the Stem Barks of Juglans mandshurica Maxim

  • Li, Zi-Jiang;Chen, Shilin;Yang, Xiang-Hao;Wang, Rui;Min, Hee-Jeong;Wu, Lei;Si, Chuan-Ling;Bae, Young-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.2
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    • pp.118-124
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    • 2018
  • Juglans mandshurica is a fast growing hard species, which is a tree in family of Juglandaceae and has a wide distribution in China, Korea and eastern Russia. Plant materials from J. mandshurica have extensively been used in folk medicines to prevent or cure gastric, esophageal, lung and cardiac cancer. As one chain of our searching for anticomplementary agents from natural sources, two epimeric ellagitannins, [2,3-O-4,4',5,5',6,6',-hexahydroxydiphenoyl (HHDP))-(${\alpha},{\beta}$)-D-glucose] (I) and pedunculagin (II) were purified from 70% acetone extracts of the stem barks of J. mandshurica by Thin Layer Chromatography and Sephadex LH-20 column chromatography approaches. The chemical structures of the isolated compounds were characterized by MS, NMR, and a careful comparation with published literatures. The epimeric ellagitannins I and II exhibited inhibitory properties against a classical pathway of complementary system with 50 % inhibitory concentrations ($IC_{50}$) values of 65.3 and $47.7{\mu}M$, respectively, comparing with riliroside ($IC_{50}=104{\mu}M$) and rosmarinic acid ($IC_{50}=182{\mu}M$), which were used as positive controls. Thus, the work indicated both the two secondary metabolites possess excellent inhibitory activity and might be developed as potential anticomplementary chemicals.

Removal of Copper and Zinc Ions by Neutralization from the Spent Sulfate Solutions of Brass Bulb Base (황동(黃銅) 전구(電球) Base 제조과정(製造過程)에서 발생(發生)한 구리와 아연 함유(含有) 황산폐수(黃酸廢水)의 중화법(中和法)에 의한 제거(除去))

  • Lee, Man-Seung;Ahn, Jae-Woo;Lee, Chang-Hae
    • Resources Recycling
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    • v.16 no.6
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    • pp.39-45
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    • 2007
  • Optimum condition for neutralization has been studied to remove the copper and zinc ions from spent sulfate solutions which resulted from the acid washing of the base of brass bulb. Chemical distribution of copper and zinc species and the variation of solubility of the two ions with solution pH were obtained by considering the complex formation reaction and mass balance. Removal percentage of zinc was more sensitive to solution pH than that of copper. This results from the fact that the solubility of zinc is higher than that of copper. The form of coagulant affected little the removal percentage of zinc, while addition of coagulant as the phase of solution resulted in higher removal percentage of copper than as the phase of solid.

Correlation between Biotic Factor and Abiotic Factor - Focus on the Case Streams in Kyonggi District - (하천에서의 무생물적 환경인자와 생물과의 상관성 - 경기지방의 하천사례를 중심으로 -)

  • Kim, Hyea-Ju;Kim, Song-Yee;Kim, Chang-Wan
    • Korean Journal of Environment and Ecology
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    • v.20 no.4
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    • pp.374-390
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    • 2006
  • The analysis of correlation between the 9 element (used as the classification standard of stream typology out of the 25 elements pertinent to the survey of hydromorphological structure) and both emerged benthic macroinvertebrate as well as vegetation indicated that the substrate diversity, curvature, and degree of development of the transverse bar had a high correlation with the species composition. Only COD concentration was found to have the statistically significant correlation with the distribution of benthos among the 12 aquatic and chemical elements. Specifically, the analysis of the biotic and abiotic factors in this study indicated that there was a statistically significant correlation between the sand river and cobble river in the positive(+) and negative(-) aspects, suggesting that there is a distinctive difference between the two types of rivers in terms of hydromorphologlcal structure and ecological characteristics. Therefore, the findings of this study imply that the consideration of a biotop is prerequisite for the evaluation of stream status regarding stream restoration or the ecological topology of streams.

Termite monitoring and control managements for wooden building (목조건조물의 흰개미 모니터링 및 방제방법)

  • Lee, Kyu-Shik;Jeong, So-Young;Chung, Yong-Jae
    • 보존과학연구
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    • s.22
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    • pp.41-52
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    • 2001
  • The wooden building is mainly damaged by the termite which have an effect of the structure by making emptied inner part of wood. One class, Japanese termite, inhabits throughout Korea and is often detected. So the deterioration by termite attacking the wooden building needs to be controlled. Termites are over 2,800 species in the world, usually they inhabit in the tropical or subtropical region and don’t over winter in dormant condition. So their activity and distribution are chiefly restricted by temperature and humidity. The termite inhabiting in Korea is Reticulitermes speratus kyushuensis Morimoto, which known to have an optimal temperature range at $12~30^{\circ}C$ and minimum temperature at $6^{\circ}C$ for activation. These temperatures correspond to the mean temperature($5.6^{\circ}C$~$25.8^{\circ}C$) from March to November and the activity time of termitein Seoul. In addition, as a result of environmental pollution by industrial development, the climate of Korea is getting warm. The increase of mean temperature in Korea has been $1.1^{\circ}C$ for the past seventy five years, so it is expected that the damage of wooden building by termite will increase gradually. Therefore, in order to protect wooden building from damages by termite, it needs not only development of new pest control methods, but also studies on the control of environmental factors having an effect on the activity and growth of termite. For the conservation of the large cultural properties such as the wooden building in the open air, it would be effective to use the methods of fumigation, insecticidal and antiseptic chemical treatment of wood materials, soil termiticideinjection treatment, and termite colony elimination system.

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A Study on Emission Characteristics of Mercury from Coal Combustion at a Lab-scale Furnace (실험용 연소로에서 석탄 연소 시 발생하는 수은 배출특성 연구)

  • Park, Kyu-Shik;Lee, Ju-Hyoung;Kim, Jeong-Hun;Lee, Sang-Hyeob;Seo, Yong-Chil
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.2
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    • pp.238-248
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    • 2008
  • This study investigated mercury emission at various combustion conditions and analyzed mercury species in flue gas from coal combustion at a laboratory scale furnace in coal. The results of this study can be used to predict and to assess mercury emission at coal boilers and power plants. The coal used in the plants generally contains about $0.02{\sim}0.28\;mg$ of mercury per kg. Bituminous and anthracite coal used for the experiment contained 0.049 and 0.297 mg/kg of mercury, respectively. Mercury emissions during coal combustion at temperatures range of $600^{\circ}C$ to $1,400^{\circ}C$ was measured and analysed using Ontario Hydro method; the speciation changes were also observed in mercury emissions. The results showed higher fraction of elemental mercury than that of oxidised mercury at most temperatures tested in this experiment. The fraction of elemental mercury was lower in combustion of anthracite coal than in bituminous combustion. As expected, equilibrium calculations and real power plants data showed good similarity. The distribution of particle size in flue gas had the higher peak in size above $2.5\;{\mu}m$. However the peak of mercury enrichment in dust was at $0.3\;{\mu}m$, which could be easily emitted into atmosphere without filtration in combustion system. When the CEA(Chemical equilibrium and Application) code was used for combustion equilibrium calculation, Cl was found to be the important component effecting mercury oxidation, especially at the lower temperatures under $900^{\circ}C$.

Role of Features in Plasma Information Based Virtual Metrology (PI-VM) for SiO2 Etching Depth (플라즈마 정보인자를 활용한 SiO2 식각 깊이 가상 계측 모델의 특성 인자 역할 분석)

  • Jang, Yun Chang;Park, Seol Hye;Jeong, Sang Min;Ryu, Sang Won;Kim, Gon Ho
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.4
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    • pp.30-34
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    • 2019
  • We analyzed how the features in plasma information based virtual metrology (PI-VM) for SiO2 etching depth with variation of 5% contribute to the prediction accuracy, which is previously developed by Jang. As a single feature, the explanatory power to the process results is in the order of plasma information about electron energy distribution function (PIEEDF), equipment, and optical emission spectroscopy (OES) features. In the procedure of stepwise variable selection (SVS), OES features are selected after PIEEDF. Informative vector for developed PI-VM also shows relatively high correlation between OES features and etching depth. This is because the reaction rate of each chemical species that governs the etching depth can be sensitively monitored when OES features are used with PIEEDF. Securing PIEEDF is important for the development of virtual metrology (VM) for prediction of process results. The role of PIEEDF as an independent feature and the ability to monitor variation of plasma thermal state can make other features in the procedure of SVS more sensitive to the process results. It is expected that fault detection and classification (FDC) can be effectively developed by using the PI-VM.

Enzymatic Characterization and Comparison of Two Steroid Hydroxylases CYP154C3-1 and CYP154C3-2 from Streptomyces Species

  • Subedi, Pradeep;Kim, Ki-Hwa;Hong, Young-Soo;Lee, Joo-Ho;Oh, Tae-Jin
    • Journal of Microbiology and Biotechnology
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    • v.31 no.3
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    • pp.464-474
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    • 2021
  • Bacterial cytochrome P450 (CYP) enzymes are responsible for the hydroxylation of diverse endogenous substances with a heme molecule used as a cofactor. This study characterized two CYP154C3 proteins from Streptomyces sp. W2061 (CYP154C3-1) and Streptomyces sp. KCCM40643 (CYP154C3-2). The enzymatic activity assays of both CYPs conducted using heterologous redox partners' putidaredoxin and putidaredoxin reductase showed substrate flexibility with different steroids and exhibited interesting product formation patterns. The enzymatic characterization revealed good activity over a pH range of 7.0 to 7.8 and the optimal temperature range for activity was 30 to 37℃. The major product was the C16-hydroxylated product and the kinetic profiles and patterns of the generated hydroxylated products differed between the two enzymes. Both enzymes showed a higher affinity toward progesterone, with CYP154C3-1 demonstrating slightly higher activity than CYP154C3-2 for most of the substrates. Oxidizing agents (diacetoxyiodo) benzene (PIDA) and hydrogen peroxide (H2O2) were also utilized to actively support the redox reactions, with optimum conversion achieved at concentrations of 3 mM and 65 mM, respectively. The oxidizing agents affected the product distribution, influencing the type and selectivity of the CYP-catalyzed reaction. Additionally, CYP154C3s also catalyzed the C-C bond cleavage of steroids. Therefore, CYP154C3s may be a good candidate for the production of modified steroids for various biological uses.

Comparison of Model-simulated Atmospheric Carbon Dioxide with GOSAT Retrievals

  • Shim, Chang-Sub;Nassar, Ray;Kim, Jhoon
    • Asian Journal of Atmospheric Environment
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    • v.5 no.4
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    • pp.263-277
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    • 2011
  • Global atmospheric $CO_2$ distributions were simulated with a chemical transport model (GEOS-Chem) and compared with space-borne observations of $CO_2$ column density by GOSAT from April 2009 to January 2010. The GEOS-Chem model simulated 3-D global atmospheric $CO_2$ at $2^{\circ}{\times}2.5^{\circ}$ horizontal resolution using global $CO_2$ surface sources/sinks as well as 3-D emissions from aviation and the atmospheric oxidation of other carbon species. The seasonal cycle and spatial distribution of GEOS-Chem $CO_2$ columns were generally comparable with GOSAT columns over each continent with a systematic positive bias of ~1.0%. Data from the World Data Center for Greenhouse Gases (WDCGG) from twelve ground stations spanning $90^{\circ}S-82^{\circ}N$ were also compared with the modeled data for the period of 2004-2009 inclusive. The ground-based data show high correlations with the GEOS-Chem simulation ($0.66{\leq}R^2{\leq}0.99$) but the model data have a negative bias of ~1.0%, which is primarily due to the model initial conditions. Together these two comparisons can be used to infer that GOSAT $CO_2$ retrievals underestimate $CO_2$ column concentration by ~2.0%, as demonstrated in recent validation work using other methods. We further estimated individual source/sink contributions to the global atmospheric $CO_2$ budget and trends through 7 tagged $CO_2$ tracers (fossil fuels, ocean exchanges, biomass burning, biofuel burning, net terrestrial exchange, shipping, aviation, and CO oxidation) over 2004-2009. The global $CO_2$ trend over this period (2.1 ppmv/year) has been mainly driven by fossil fuel combustion and cement production (3.2 ppmv/year), reinforcing the fact that rigorous $CO_2$ reductions from human activities are necessary in order to stabilize atmospheric $CO_2$ levels.