• Title/Summary/Keyword: dispersions

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The influence of graphene platelet with different dispersions on the vibrational behavior of nanocomposite truncated conical shells

  • Khayat, Majid;Baghlani, Abdolhossein;Dehghan, Seyed Mehdi;Najafgholipour, Mohammad Amir
    • Steel and Composite Structures
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    • v.38 no.1
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    • pp.47-66
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    • 2021
  • This work addresses the free vibration analysis of Functionally Graded Porous (FGP) nanocomposite truncated conical shells with Graphene PLatelet (GPL) reinforcement. In this study, three different distributions for porosity and three different dispersions for graphene platelets have been considered in the direction of the shell thickness. The Halpin-Tsai equations are used to find the effective material properties of the graphene platelet reinforced materials. The equations of motion are derived based on the higher-order shear deformation theory and Sanders's theory. The Fourier Differential Quadrature (FDQ) technique is implemented to solve the governing equations of the problem and to obtain the natural frequencies of the truncated conical shell. The combination of FDQ with higher-order shear deformation theory allows a very accurate prediction of the natural frequencies. The precision and reliability of the proposed method are verified by the results of literature. Moreover, a wide parametric study concerning the effect of some influential parameters, such as the geometrical parameters, porosity distribution, circumferential wave numbers, GPLs dispersion as well as boundary restraint conditions on free vibration response of FGP-GPL truncated conical shell is also carried out and investigated in detail.

High-power SESAM Mode-locked Yb:KGW Laser with Different Group-velocity Dispersions

  • Park, Byeong-Jun;Song, Ji-Yeon;Lee, Seong-Yeon;Yee, Ki-Ju
    • Current Optics and Photonics
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    • v.6 no.4
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    • pp.407-412
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    • 2022
  • We report on a diode-laser-pumped mode-locked Yb:KGW laser system, which delivers ultrashort pulses down to 89 fs at a repetition rate of 63 MHz, with an average power of up to 5.6 W. A fiber-coupled diode laser at 981 nm, operated with a compact driver, is used to optically pump the gain crystal via an off-axis parabolic mirror. A semiconductor saturable-absorber mirror is used to initiate the pulsed operation. Laser characteristics such as the pulse duration, spectrum bandwidth, and output power are investigated by varying the intracavity dispersions via changing the number of bounces between negative-dispersive mirrors within the cavity. Short pulses with a duration of 89 fs, a center wavelength of 1,027 nm, and 3.6 W of output power are produced at a group-velocity dispersion (GVD) of -3,300 fs2. As the negative GVD increases, the pulse duration lengthens but the output power at the single-pulse condition can be enhanced, reaching 5.6 W at a GVD of -6,600 fs2. Because of pulse broadening at high negative GVDs, the highest peak intensity is achievable at a moderate GVD with our system.

Effect of Multi-functional Group of Acrylate Crosslinker on Properties of Waterborne Polyurethane-acrylate

  • Moon, Seok Kyu;Kim, Eun-jin;Kwon, Yong Rok;Kim, Jung Soo;Kim, Hae Chan;Park, Han Soo;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.57 no.3
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    • pp.100-106
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    • 2022
  • Waterborne polyurethane-acrylate(WPUA) dispersions were prepared by surfactant-free emulsion polymerization in a two-step process. In the first step, polytetrahydrofuran, isophorone diisocyanate, dimethylol proponic acid, and 2-hydroxyethyl methacrylate were used to synthesize a vinyl-terminated polyurethane prepolymer. In the second step, styrene, methyl methacrylate, butyl acrylate, and different multi-functional crosslinkers were copolymerized. 1,6-hexanediol diacrylate, trimethylolpropane triacrylate, and pentaerythritol tetraacrylate were used as the crosslinkers, and their effect on the mechanical and thermal properties of WPUA was investigated. Overall, as the number of functional groups of the cross-linker increased, the gel fraction improved to 79.26%, the particle size increased from 75.9 nm to 148.7 nm, and the tensile strength was improved from 5.86 MPa to 12.40 MPa. In thermal properties, the glass transition temperature and decomposition temperature increased by 9.9℃ and 18℃, respectively. The chemical structures of the WPUA dispersions were characterized by Fourier-transform infrared spectroscopy. The synthesized WPUA has high potential for applications such as coatings, leather coatings, adhesives, and wood finishing.

Impact of target spectra variance of selected ground motions on seismic response of structures

  • Xu, Liuyun;Zhou, Zhiguang
    • Earthquakes and Structures
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    • v.23 no.2
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    • pp.115-128
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    • 2022
  • One common method to select input ground motions to predict dynamic behavior of structures subjected to seismic excitation requires spectral acceleration (Sa) match target mean response spectrum. However, dispersion of ground motions, which explicitly affects the structural response, is rarely discussed in this method. Generally, selecting ground motions matching target mean and variance has been utilized as an appropriate method to predict reliable seismic response. The goal of this paper is to investigate the impact of target spectra variance of ground motions on structural seismic response. Two sets of ground motions with different target variances (zero variance and minimum variance larger than inherent variance of the target spectrum) are selected as input to two different structures. Structural responses at different heights are compared, in terms of peak, mean and dispersion. Results show that increase of target spectra variance tends to increase peak floor acceleration, peak deformation and dispersions of response of interest remarkably. To short-period structures, dispersion increase ratios of seismic response are close to that of Sa of input ground motions at the first period. To long-period structures, dispersions of floor acceleration and floor response spectra increase more significantly at the bottom, while dispersion increase ratios of IDR and deformation are close to that of Sa of input ground motions at the first period. This study could further provide useful information on selecting appropriate ground motion to predict seismic behavior of different types of structures.

Velocity Dispersion Bias of Galaxy Groups classified by Machine Learning Algorithm

  • Lee, Youngdae;Jeong, Hyunjin;Ko, Jongwan;Lee, Joon Hyeop;Lee, Jong Chul;Lee, Hye-Ran;Yang, Yujin;Rey, Soo-Chang
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.74.2-74.2
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    • 2019
  • We present a possible bias in the estimation of velocity dispersions for galaxy groups due to the contribution of subgroups which are infalling into the groups. We execute a systematic search for flux-limited galaxy groups and subgroups based on the spectroscopic galaxies with r < 17.77 mag of SDSS data release 12, by using DBSCAN (Density-Based Spatial Clustering of Application with Noise) and Hierarchical Clustering Method which are well known unsupervised machine learning algorithm. A total of 2042 groups with at least 10 members are found and ~20% of groups have subgroups. We found that the estimation of velocity dispersions of groups using total galaxies including those in subgroups are underestimated by ~10% compared to the case of using only galaxies in main groups. This result suggests that the subgroups should be properly considered for mass measurement of galaxy groups based on the velocity dispersion.

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Drop formation of Carbopol dispersions displaying yield stress, shear thinning and elastic properties in a flow-focusing microfluidic channel

  • Hong, Joung-Sook;Cooper-White, Justin
    • Korea-Australia Rheology Journal
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    • v.21 no.4
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    • pp.269-280
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    • 2009
  • The drop formation dynamics of a shear thinning, elastic, yield stress ($\tau_o$) fluid (Carbopol 980 (poly(acrylic acid)) dispersions) in silicone oil has been investigated in a flow-focusing microfluidic channel. The rheological character of each solution investigated varied from Netwonian-like through to highly non-Newtonian and was varied by changing the degree of neutralization along the poly (acrylic acid) backbone. We have observed that the drop size of these non-Newtonian fluids (regardless of the degree of neutralisation) showed bimodal behaviour. At first we observed increases in drop size with increasing viscosity ratio (viscosity ratio=viscosity of dispersed phase (DP)/viscosity of continuous phase (CP)) at low flowrates of the continuous phases, and thereafter, decreasing drop sizes as the flow rate of the CP increases past a critical value. Only at the onset of pinching and during the high extensional deformation during pinch-off of a drop are any differences in the non-Newtonian characteristics of these fluids, that is extents of shear thinning, elasticity and yield stress ($\tau_o$), apparent. Changes in these break-off dynamics resulted in the observed differences in the number and size distribution of secondary drops during pinch-off for both fluid classes, Newtonian-like and non-Newtonian fluids. In the case of the Newtonian-like drops, a secondary drop was generated by the onset of necking and breakup at both ends of the filament, akin to end-pinching behavior. This pinch-off behavior was observed to be unaffected by changes in viscosity ratio, over the range explored. Meanwhile, in the case of the non-Newtonian solutions, discrete differences in behaviour were observed, believed to be attributable to each of the non-Newtonian properties of shear thinning, elasticity and yield stress. The presence of a yield stress ($\tau_o$), when coupled with slow flow rates or low viscosities of the CP, reduced the drop size compared to the Newtonian-like Carbopol dispersions of much lower viscosity. The presence of shear thinning resulted in a rapid necking event post onset, a decrease in primary droplet size and, in some cases, an increase in the rate of drop production. The presence of elasticity during the extensional flow imposed by the necking event allowed for the extended maintenance of the filament, as observed previously for dilute solutions of linear polymers during drop break-up.

Enhanced Dissolution and Duodenal Permeation of Atorvastatin Calcium Using Bile Salt and 2-Hydroxypropyl-${\beta}$-Cyclodextrin (담즙산염과 2-히드록시프로필-${\beta}$-시클로덱스트린을 이용한 아토르바스타틴칼슘의 용출 및 십이지장 점막 투과 증진)

  • Choi, Ji-Won;Chun, In-Koo
    • YAKHAK HOEJI
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    • v.56 no.3
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    • pp.164-172
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    • 2012
  • This study was aimed to increase the solubility, dissolution and permeation rates of atorvastatin calcium (ATC) using bile salt and/or 2-hydroxypropyl-${\beta}$-cyclodextrin ($HP{\beta}CD$). From solubility studies, sodium deoxycholate (SDC) among bile salts studied was found to have the highest solubilizing effect on ATC ($4.4{\pm}0.4$ mg/ml), and the order of increasing solubility was SDC>sod. cholate>sod. glycocholate>sod. taurodeoxycholate>sod. taurocholate>conjugated bile acid. ATC solid dispersions were prepared at various ratios of drug to SDC and/or $HP{\beta}CD$, and evaluated by differential scanning calorimetry (DSC), dissolution studies and dissolution-permeation studies. DSC curves showed amorphous state of ATC in the physical mixture and solid dispersion. Dissolution rates of ATC-SDC solid dispersions and physical mixture were markedly increased at pH 6.8, but decreased at pH 1.2 with greater proportions of SDC due to the precipitation of SDC, compared with that of drug alone. On the other hand, dissolution rates of ATC-$HP{\beta}CD$ solid dispersion and physical mixture at pH 1.2 were varied with the ratio of drug to carriers. From duodenal permeation studies, it was found that fluxes of ATC (donor dose: 0.5 mg/3.5 ml) in the presence of 25 mM sodium glycocholate, SDC, sod. cholate and sod. taurocholate $(5.7{\pm}0.9$, $5.6{\pm}0.9$, $4.8{\pm}0.7$ and $4.6{\pm}0.9\;{\mu}g/cm^2/hr$, respectively) were enhanced, compared with drug alone ($3.4{\pm}0.9\;{\mu}g/cm^2/hr$). In the dissolution-permeation studies, 1 : 9 : 10 (w/w) ATC-SDC-$HP{\beta}CD$ solid dispersion increased the flux 2.2 times, compared with 1 : 5 : 4 (w/w) ATC-lactose-corn starch mixture as control. In conclusion, solid dispersions with bile salt and $HP{\beta}CD$ were found to be an effective means for increasing the dissolution and permeation rates of ATC.

Rheological Properties of Exopolysaccharide EPS-R Produced by Marine Bacterium Hahella chejuensis KCTC 2395

  • Ahn, Se-Hun;Yim, Joung-Han;Kim, Sung-Jin;Lee, Hong-Kum
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.808-811
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    • 2001
  • The rheological properties of exopolysaccharide(EPS-R) produced by marine bacteria Hahella chjuensis KCTC 2395 was investigated. EPS-R solution showed a characteristic non-Newtonian behavior fluid properties. In aqueose dispersions of EPS-R 1%, consistency index(K) and flow behavior index(n) were 1,410 cp and 0.73. EPS-R solution was pseudoplastic fluid by power-low model. Rheological propertie of EPS-R was found to be influenced by the concentration of salt, pH, temperature and ionic compounds.

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The Production of Microcapsules containing Cinnamon and Aromatic, Antimicrobial Finishing(Part I) (계피정유를 함유한 마이크로캡슐의 제조 및 방향.항균가공(제1보))

  • 김혜림;송화순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.3
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    • pp.569-576
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    • 2001
  • The purpose of this study is to develop multifunctional fibers by sticking cinnamon microcapsules on cotton knit. The prepolymer was made from urea-formaldehyde for usage of wall materials of microcapsules. The parameters for adoptable condition are 5000rpm of agitation speed, 1% of dispersions concentration according to the observation with SEM and particle analyzer. The Antimicrobial activity of cotton knit treated with capsule was increased greatly and maintained on the laundering cycle.

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An Adaptive Test for Ordered Interqartile Ranges among Several Distributions

  • Park, Chul-Gyu
    • Journal of the Korean Statistical Society
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    • v.30 no.1
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    • pp.63-76
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    • 2001
  • An adaptive estimation and testing method is proposed for comparing dispersions among several ordered groups. Based upon the large sampling theory for nonparametric quartile estimators, we derive the order restricted estimators and construct a simple test statistic. This test statistic has a mixture of several chi-square distributions as its asymptotic null distribution. The proposed test is illustratively applied to survival time data for the patients with carcinoma of the oropharynx.

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