• 한국전기전자재료학회논문지
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• 제17권12호
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• pp.1356-1361
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• 2004

High temperature superconducting coated conductor has a structure of ///. The buffer layer consists of multi-layer, this study reports the deposition method and optimal deposition conditions of YSZ(Yttria-stabilized zirconia) layer which plays a important part in preventing the elements of substrate from diffusing into the superconducting layer. YSZ layer was deposited by DC reactive sputtering technique using water vapor for oxidizing deposited elements on substrate. To investigate optimal thickness of YSZ film, four YSZ/CeO$_2$/Ni samples with different YSZ thickness(130 nm, 260 nm, 390 nm, and 650 nm) were prepared. The SEM image showed that the surface of YSZ layer was getting to be rougher as YSZ layer was getting thicker and the growth mode of YSZ layer was columnar grain growth. After CeO$_2$ layer was deposited with the same thickness of 18.3 nm on each four samples, YBCO layer was deposited by PLD method with the thickness of 300 nm. The critical currents of four samples were 0, 6 A, 7.5 A, and 5 A respectively. This shows that as YSZ layer is getting thicker, YSZ layer plays a good role as a diffusion barrier but the surface of YSZ layer is getting rougher.

• 대한전자공학회논문지
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• 제21권6호
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• pp.34-41
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• 1984

RMOS(refractors metal oxide semiconductor)의 게이트 금속으로 사용되는 Mo2N/Mo 이중층을 N2와 Ar을 혼합하여 저온의 반응성 스펏터링법으로 제조하였다. Ar : N2=95 : 5로 혼합된 가스 분위기에서 반응성 스펏터링을 할 때 Mo2N이 잘 형성되었다. 이렇게 제조한 Mo2N 박막은 면저항이 약 1.20∼1.28Ω/□로서 다결정 실리콘의 1/10정도가 되어 반도체 소자의 동작속도를 크게 향상시킬 것으로 기대된다. 1100℃의 N2분위기에서 PSC(phosphorus silicate glass)를 불순물 확산원으로 하여 소오스와 드레인의 불순물 확산을 할때 Mo2N 박막이 Mo으로 환원되어 확산전의 면저항보다 훨씬 작은 약 0.38Ω/□정도의 면저항을 나타내었다. 본 실험에서 제작한 자기정렬된 RMOSFET의 문턱전압은 약 -1.5V이고 결핍과 증가의 두 가지 동작특성을 나타내었다.

• 대한인간공학회지
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• 제17권3호
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• pp.41-59
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• 1998

Thermal comfort aspect of a locally-cooled target space in warm and humid environments(typically in the rainy summer season) was studied in view of PPD index. First. theoretical analyses were conducted to examine the effect of the governing parameters(such as air temperature, relative humidity and air velocity, etc.) using a computer model. Secondly, experimental investigations were also performed in a climatic room designed to simulate corresponding thermal conditions of outdoor environments. During the tests, temporal variation of PPD was recorded as functions of climatic variables(outdoor and indoor temperatures, relative humidity and air velocity) for the given human factors(metabolic heat generation and clothing). From both theoretical and experimental investigations, air temperature and air velocity were found to be the most dominant parameters affecting PPD of the target space. Results were summarized as: 1. Relative humidity of the locally-cooled target space tends to approach that of outdoor's as the space is subjected to an ON-OFF mode of cooling, since moisture potential of the two rooms reaches an equalized state as a result of moisture diffusion. 2. It was recognized that changes in relative humidity did not show any significance in view of thermal comfort as was reported in the previous studies, while variations of both temperature and air velocity caused relatively large changes in the degree of thermal comfort. 3. In-door environment should be evaluated in terms of PPD instead of relative humidity commonly recognized as an important climatic variable particularly in warm and humid environments.

• Journal of Electrochemical Science and Technology
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• 제7권1호
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• pp.68-75
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• 2016

In this study a new, simple, precise, accurate and economic electrochemical method was developed and validated for the voltammetric determination of zolpidem (ZP) using disposable pencil graphite (PG) electrode. The anodic oxidation of ZP on the surface of the PG electrode was examined in a britton robinson (BR) buffer. Square wave and cyclic voltammetry were used as electrochemical techniques in the potential range of 0-1.2 V in the pH 8 BR buffer. In cyclic voltammetry studies, the diffusion coefficient of ZP oxidation was found to be 3.6×10^-6 cm² s^-1. On the other hand, the ZP has shown a well-defined irreversible anodic peak at 0.98 V in the square wave voltammetry mode. The PG electrode, primarily being graphite which has a large active surface area gives rise to increasing peak current with respect to ZP electrooxidation. PG electrode showed an electrocatalytic effect in anodic oxidation of ZP. A linear relationship between catalytic current response and ZP concentration was obtained over a concentration range of 10-30 μM with R.S.D. values ranging from 0.29-3.89. Limits of detection and quantitation were found to be 1 and 3 μM, respectively. Finally, the PG electrode was successfully used to determine ZP in standard and tablet dosage forms with a mean recovery of 100.69 %.

• 공업화학
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• 제27권3호
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• pp.335-341
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• 2016

본 연구에서는 지상 및 미소중력환경하에서 물리적 승화법 공정에서의 확산-대류유동에 미치는 불순물의 영향을 이론적으로 $Hg_2Cl_2-I_2$ 시스템에 적용하여 규명하는 것이다. 이론적 해석은 증기상에서 확산-대류 흐름, 열 및 물질전달을 속도 벡터 흐름, 유선, 온도, 농도 분포를 통하여 제시된다. 결정 영역에서의 전체 몰플럭스는 중력가속도와 성분 $I_2$, 불순물에 상당히 민감하게 반응한다. 성분 $I_2$을 증가시켰을 때, 농도 대류효과는 확산-대류 유동흐름을 안정화시키는 경향이 있다. 지상중력가속도의 0.001환경에서는 유동흐름은 1차원포물선의 흐름 구조를 나타내며, 확산지배형태를 보여주고 있다. $10^{-3}$지상중력가속도 이하에서는 대류 영향은 무시할 수 있다.

• Journal of Electrochemical Science and Technology
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• 제9권3호
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• pp.202-211
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• 2018

In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing $[Pd(NH_3)_4]^{2+}$ (0.02 M) and $[Fe-Citrate]^{2+}$ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dispersive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates - brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) - Fe content of the electrodeposited alloys increases by increasing the overpotential. Also the cathodic current efficiency is low due to high rate of $H_2$ co-reduction. Regarding the chronoamperometry current-time transients, it has been demonstrated that the nucleation mechanism is instantaneous with a typical three dimensional (3D) diffusion-controlled growth in the case of brass and copper substrates; while for FTO, the growth mode changes to 3D progressive. At a constant overpotential, the calculated number of active nucleation sites for metallic substrates is much higher than that of FTO/glass; however by increasing the overpotential, the number of active nucleation sites increases. The SEM micrographs as well as the XRD patterns reveal the formation of Fe-Pd alloy thin films with nanostructure arrangement and ultra-fine grains.

• 공업화학
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• 제10권3호
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• pp.331-335
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• 1999

진이급속 산화물은 전기화학적 산소 발생/환원에 대한 bifunctional 촉매효과가 있어 금속-공기 이차전지와 같은 에너지 저장기술 개발에 연구대상이 되어왔다. Amorphous citrate precursor법을 이용하여 perovskite 구조를 갖는 La-Ca-Co 산화물과 pyrochlore 구조를 갖는 Pb-Ru 산화물을 제조하고, 이후 열처리법으로 표면적이 큰 전이금속 산화물 촉매분말을 제조하였다. PTFE 결합 기체확산형 전극의 충방전 실험을 통하여 전기화학적 산소발생/환원에 대한 좋은 촉매능을 가짐을 확인하였고, ${\pm}25mA/cm^2$의 전류밀도를 가하고 공기를 공급하면서 충방전 실험한 결과 100시간 이내에서 두촉매분말 모두 안정하였다. ACP법으로 제조한 perovskite 구조의 La0.6Ca0.4CoO3과 pyrochlore 구조의 Pb2Ru2O6가 이차전지용 공기전극 재료로 사용할 수 있음을 확인하였다.

• 공업화학
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• 제10권2호
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• pp.212-217
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• 1999

기체투과 특성을 관찰하기 위해 양극산화에 의해 세공직경의 크기가 서로 다른 상부층과 하부층으로 이루어진 이중기하구조의 다공성 알루미나막을 제조하였다. 양극산화는 황산 전해질 하에서 직류에 의한 정전류법으로 행하였으며, 양질의 막을 얻기 위해 열산화, 화학연마, 전해연마 등의 전처리를 한 후 양극산화를 행하였다. 양극산화에 의한 알루미나 막의 제조에서 세공직경은 전해질의 종류 및 농도, 전해 온도, 전류밀도 등에 의존하는데, 전류밀도를 극도로 낮추어 세공직경이 20 nm 이하인 상부층을 제조하고 전류밀도를 높여서 세공직경이 36 nm인 하부층을 제조하였다. 막의 두께는 전기량에 의해 조절되어 상부층의 두께는 약 $6{\mu}m$이었으며 하부층을 포함하는 막의 총 두께는 약 $80{\sim}90{\mu}m$로 제조되었다. 제조된 막은 가압법에 의한 기체투과 실험을 행하였다. 제조된 막의 기체투과 기구는 Knudsen 흐름을 따르는 것을 확인하였다.

• Journal of Microbiology and Biotechnology
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• 제23권2호
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• pp.167-176
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• 2013

A novel bioactive molecule produced by Bacillus thuringiensis subsp. kurstaki Bn1 (Bt-Bn1), isolated from a common pest of hazelnut, Balaninus nucum L. (Coleoptera: Curculionidae), was determined, purified, and characterized in this study. The Bt-Bn1 strain was investigated for antibacterial activity with an agar spot assay and well diffusion assay against B. cereus, B. weinhenstephenensis, L. monocytogenes, P. savastanoi, P. syringae, P. lemoignei, and many other B. thuringiensis strains. The production of bioactive molecule was determined at the early logarithmic phase in the growth cycle of strain Bt-Bn1 and its production continued until the beginning of the stationary phase. The mode of action of this molecule displayed bacteriocidal or bacteriolytic effect depending on the concentration. The bioactive molecule was purified 78-fold from the bacteria supernatant with ammonium sulfate precipitation, dialysis, ultrafiltration, gel filtration chromatography, and HPLC, respectively. The molecular mass of this molecule was estimated via SDS-PAGE and confirmed by the ESI-TOFMS as 3,139 Da. The bioactive molecule was also determined to be a heat-stable, pH-stable (range 6-8), and proteinase K sensitive antibacterial peptide, similar to bacteriocins. Based on all characteristics determined in this study, the purified bacteriocin was named as thuricin Bn1 because of the similarities to the previously identified thuricin-like bacteriocin produced by the various B. thuringiensis strains. Plasmid elution studies showed that gene responsible for the production of thuricin Bn1 is located on the chromosome of Bt-Bn1. Therefore, it is a novel bacteriocin and the first recorded one produced by an insect originated bacterium. It has potential usage for the control of many different pathogenic and spoilage bacteria in the food industry, agriculture, and various other areas.

• 지구물리
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• 제2권2호
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• pp.123-134
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• 1999

상부맨틀이나 하부지각의 고전도층(HCL)에서 나타나는 고이방성은 MT 탐사에 큰 영향을 미칠 수 있다. 본 연구에서는 고이방성 매질이 MT 반응에 미치는 영향을 고찰하기 위한 모델연구를 수행하였다. 각각의 균질한 암체의 전기적 성질은 대칭적인 전기전도도 텐서로 주어지며 모델링을 위한 기본방정식은 전기장과 자기장 성분이 결합되어진 주파수 영역 분산 방정식으로 주어진다. 이방성 매질에서는 전기장의 왜곡에 의해 항상 4성분의 임피던스가 존재하며, 2차원 구조에서는 대각선 성분, 특히 YY성분의 임피던스가 증가한다. 어떤 경우에는 서로 이방성 주향이 다른 매질의 상호작용에 의해 TM 모드의 위상이 90° 이상으로 증가하고 겉보기비저항이 낮아지는 현상이 발생한다. GB 분리법은 광역적인 반응을 추출하는데 이용될 수 있으나, 심부의 이방성의 영향을 크게 받는다. 이상의 모델연구의 결과를 BC87자료에 적용하여 현장자료에서의 이방성 효과를 고찰하였다.