• Textile Coloration and Finishing
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• v.35 no.4
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• pp.246-255
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• 2023

In this study, we investigated for natural rubber foam to replace petrochemical-based neoprene foam. Experiments were conducted on vulcanization system and 2-step foaming process of natural rubber. The vulcanization system were EV(Efficient Vulcanization Cure), Semi-EV(Semi-Efficient Vulcanization Cure) and CV(Conventional Vulcanization Cure). In the 2-step foaming process, first molding temperature was 140℃, times were 15, 20, 25, and 30minutes, and the second molding temperature was 160℃, the times 5, 10, 15, and 20minutes. The cure and viscosity characterization were evaluated by oscillating disc rheometer (ODR) and mooney viscosmeter. Various mechanical characteristics, including hardness, tensile strength, elongation at the point of rupture, and tear strength, were quantified. Subsequently, an assessment of alterations in these mechanical attributes was conducted post-immersion in a NaCl solution. In addition degree of volume change was measured after immersing the NR foam in NaCl solution and the low-temperature permanent compression set was evaluated at 4℃. And expansion ratio and shrinkage ratio of NR foam were evaluated for 28 days. As a result the EV vulcanization system showed the least change in physical properties before and after salt water immersion, and the lowest shrinkage ratio for 28 days. In addition it was confirmed that the 2-step foaming optimum condition differed depending on the appropriate vulcanization condition.

• Polymer(Korea)
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• v.34 no.5
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• pp.464-468
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• 2010

In this study, a vinylbenzyl chloride (VBC) monomer was successfully grafted onto the several fluoropolymer films including poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP), poly(tetrafluoroethylene-co-perfluoropropylvinyl ether) (PFA), and poly(ethylene-co-tetrafluoroethylene) (ETFE) films by using a simultaneous irradiation method. The results indicated that PVBC graft polymer can be easily grafted onto the ETFE film than other fluorinated films under the same irradiation condition. The grafted films were characterized by using FTIR, TGA, and SEM-EDS instruments. The elongation at the breaking of the grafted films was found to decrease with an increase of degree of grafting (DOG). The PVBC-grafted ETFE films were found to have better mechanical properties than other PVBC-grafted fluorinated films.

• Journal of the Korean Chemical Society
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• v.21 no.5
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• pp.379-383
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• 1977

Since the organophilic bentonite disperses well in polymer matrix, a composite material of polymer and bentonite was studied for its mechanical properties. To increase the degree of dispersion and the bond in forces to the polymer matrix, bentonite, encapsulated by imidazoline, was used as a filler. Polyethylene powder of particle size of 100 mesh was used, and organophilic bentonite, so-called bentone, whose particle size was 250 mesh was also used in this experiment. V-type mixer was used for mixing and Banbury mixer was used for melt-blending. The sample specimen were made by heating the mixture in the plate press, and the specimen were formed as a sheet, exactly the same as the mold on the plate. Tensile strength, bending strength and compressive strength were studied specially. Tensile strength, elongation rate, bending strength and bending rate at constant pressure were decreased as the filler content increased. Compressive strength was increased as the filler content increased.

• Journal of Radiation Industry
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• v.6 no.3
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• pp.211-215
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• 2012

In this study, crosslinked polyethylene (PE) foam sheets were prepared through gamma-ray irradiation. PE foam sheets were prepared through a foaming process using sodium bicarbonate as a blowing and foaming agent. The prepared PE foam sheets were then crosslinked through gamma-ray irradiation. The crosslinking degree was increased to 86.0% with an increase in the absorption dose. The tensile strength of the crosslinked PE foam sheets was increased with an increase in the absorption dose. However, the elongation-at-break of the crosslinked PE foam sheets was decreased. The thermal decomposition temperature of the crosslinked PE foam sheets was increased to $421.2^{\circ}C$ with an increase in the absorption dose. The SEM analysis revealed that the morphology was not changed significantly after the crosslinking through gamma-ray irradiation.

• Korean Journal of Environmental Agriculture
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• v.15 no.1
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• pp.46-69
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• 1996

The studies were conducted to obtain the basic information of the effects of pollutants on plant species and to select the plant species showing specific responses to the pollutants. For these purposes, paraquat, ammonium, and cadmium as a source of oxidative stress, nitrogen toxicity, and heavy metal toxicity respectively were treated to the plant species. Among the tested plants, Lamiaceae, Brassicaceae, and Caryophyllaceae were tolerant to paraquat, whereas Poaceae and Asteraceae were sensitive. Especially Mosla dianthera of Lamiaceae, Hemistepta lyrata and Aster pilosus of Asteraceae, and Paspalum thunbergii of Poaceae showed higher tolerance than others. Paraquat resistance was related with life style, overwintering capacity, so perennial and biennial species showed higher tolerance than annual species. In response to ammonium, Poaceae showed higher resistance while Fabaceae and Caryophyllaceae showed sensitiveness. Weed species having tolerance to ammonium were Echinochloa crus-galli var. praticola, Panicum dichotomiflorum, Setaria glauca, Chenopodium album, and Solanum nigrum, while Mosla dianthera, Arenaria serpyllifolia and Perilla frutescens var. japonica showed sensitiveness. In the response of plant species to cadmium, Digitaria sanguinalis, Amaranthus lividus showed higher resistance, whereas Galinsoga parviflora, Plantago asiatica, Ambrosia trifida, and Paspalum thunbergii showed sensitiveness. The injured degree on germination stage by pollutants did not related with injured degree on matured stage. During germination, the root elongation was more sensitive than shoot elongation by pollutants, paraquat, ammonium, and cadmium.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.39 no.1 s.119
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• pp.48-55
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• 2007

The aim of this article is to review the general property of the famous traditional Korean paper, "rice straw paper"(Bast-Fiber mixed with straw pulp), and to compare the paper qualities varying with the composition ratio of straw pulp, in order to revive the traditional paper in modem Korea. The experiment was carried out by making first the two different mixture papers, i. e., one is the paper of 50% bast fiber mixed with 50% straw pulp, and the other is the paper of 75% bast fiber with 25% oats straw pulp, and finally the 100% bast fiber paper was made for the purpose of comparison. The qualitative properties of these three kinds of paper with the different mixing ratio of the straw pulp were evaluated, and the findings of the experiment can be summarized as follow: 1. As to the quality aspects of the paper strength like tensile strength, breaking length, elongation, and tear strength, the test proved the 100% bast fiber paper as best, and the 50% mixed paper as the next good one. 2. In aspect of the printing adaptability such as density, opacity, brightness, whiteness, lab colors, air permeability, and roughness, the 50% mixed paper proved to be the best, due to the short cells in the straw pulp. 3. As to the air permeability, the larger ratio of straw pulp was found to be the lesser, and 75% bast fiber with 25% straw pulp mixture paper and the 100% bast fiber one were found 1/5 degree efficient. 4. In terms of the water absorption degree, 100% bast fiber paper was the fastest, but in case of mixture paper, 50% mixed one was a little faster up to the point of 1cm, while the two kinds of mixed ones appear to be almost similar to each other beyond the point. 5. The straw pulp mixed paper, especially the 50% mixed one was evaluated as the highest by the calligraphers who had experienced using the papers in terms of movement and feeling of the caligraphy and painting. In addition, although the 25% mixed paper is judged to be good for book printing because of the strength, the 50% mixed paper can be thought to be more desirable for painting and calligraphy. In conclusion, we will be able to make the quality paper with durability, by mixing the straw pulp with the bast fiber in proper ratio, following the tradition of Korean paper making.

• Journal of Sericultural and Entomological Science
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• v.27 no.1
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• pp.47-50
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• 1985

The physical properties of graft polymerized silk fibre were investigated with various vinyl monomers. 1. The graft polymerization of styrene and methyl methacrylate onto raw silk reduced the tenacity and elongation of raw silk due to fixation of sericin covering silk fibre in, but the styrene grafting was more effective for sericin fixation of raw silk than the methyl methacrylate one. 2. The water absorbability of glycidyl methacrylate grafted silk increased 14.6% greater than that of methyl methacrylate grafted silk at the same degree of grafting polymerization. 3. The degree of grafting polymerization was increased mostly with ethylene glycol methacrylate. The water absorbability of ethylene glycol methacrylate grafted silk was higher than that of glycidyl methacrylate or ethyl acrylate grafted silk. But the grafted silk fabric increased the fabric flexural rigidity which was negatively related with the favorability of fabric hand-touch, as compared with that of nongrafted silk fabric. 4. The evenness of graft polymerization could be improved by agitating the polymerization bath at the fixed interval by reducing the inter size deviation of grafted silk skein and the thickness deviation of grafted silk fabric.

• Journal of Korea Foresty Energy
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• v.25 no.2
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• pp.9-15
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• 2006

The quality of wood is largely depend on the characteristics of xylem tissue and their variation. They may include tracheid length, microfibril angle, distribution and amount of resin canal, as well as specific gravity as indicator of material properties. In this study, variation of these elements between and within 30 superior families of Pinus densifloa in progeny test forest were examined and the results are as follows; In terms of elongation ratio of tracheid length which is less than 1%, the sample tree showed a transition to matured wood after 13 years particularly in Kangwon 25, 30, 90, 56 and Chungnam 4 families. The average specific gravity were from 0.35 to 0.49, and differences between the families were significant. Number of transverse resin canal per unit area were also found to be significant between the families. The microfibril angles measured at 15th ring number ranged from 0.9 degree to 28.6 degree. More studies are necessary to tell whether these variation is inherited by genetic or individual characteristic. However it would be desirable that these elements be considered as key elements in the early stage of selection process of superior tree to ensure good quality of wood production in future.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.10a
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• pp.46-49
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• 2003

Cu have been widely used as signal transmission materials for electrical electronic components owing to its high electrical conductivity. However, it's size have been limited to small ones due to its poor mechanical properties, Until now, strengthening of the copper at toy was obtained either by the solid solution and precipitation hardening by adding alloy elements or the work hardening by deformation process. Adding the at toy elements lead to reduction of electrical conductivity. In this aspect, if carbon nanofiber is used as reinforcement which have outstanding mechanical strength and electric conductivity, it is possible to develope Cu matrix nanocomposite having almost no loss of electric conductivity. It is expected to be innovative in electric conduct ing material market. The unidirectional alignment of carbon nanofiber is the most challenging task developing the copper matrix composites of high strength and electric conductivity In this study, the unidirectional alignment of carbon nanofibers which is used reinforced material are controlled by drawing process in order to manufacture the intermediary materials for the carbon nanofiber reinforced Cu matrix nanocomposite and align mechanism as well as optimized drawing process parameters are verified via experiments and numerical analysis. The materials used in this study were pure copper and the nanofibers of 150nm in diameter and of $10~20\mu\textrm{m}$ In length. The materials have been tested and the tensile strength was 75MPa with the elongation of 44% for the copper it is assumed that carbon nanofiber behave like porous elasto-plastic materials. Compaction test was conducted to obtain constitutive properties of carbon nanofiber. Optimal parameter for drawing process was obtained by experiments and numerical analysis considering the various drawing angles, reduction areas, friction coefficient, etc Lower reduction areas provides the less rupture of cu tube is not iced during the drawing process. Optimal die angle was between 5 degree and 12 degree. Relative density of carbon nanofiber embedded in the copper tube is higher as drawing diameter decrease and compressive residual stress is occurred in the copper tube. Carbon nanofibers are moved to the reverse drawing direct ion via shear force caused by deformation of the copper tube and alined to the drawing direction.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.5 no.1
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• pp.47-55
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• 1999

Applications of chitosan are related to molecular weight and degree of deacetylation(DOD) of chitosan completely. The molecular weight and DOD were greatly affected by the concentration of solution time and temperature. The degree of demineralization was not significantly different at $50^{\circ}C\;and\;70^{\circ}C$ after 30 minutes. Deproteinization decreased as process time increased. The nitrogen content was reached to 6.92% after 90 minute at $80^{\circ}C$, which is similar to theoretical nitrogen content of chitin. The DOD was 82.84% after 2 hours reaction and increased as the reaction time increased in the process. Viscosity and molecular weight are increased as recycling number of concentrated NaOH solution increased. Chemical, biological and physical properties of chitosan depend on the DOD and molecular size of the molecule. Tensile strength of the films from acetic acid solutions was between $28.9{\sim}33.6$ MPa and was generally higher than that of the films from lactic acid. Elongation of the films from lactic acid was between $97.0{\sim}109.7%$ and was generally higher than that of the films from the acetic acid. Water vapor permeability of the films prepared from lcetic acid solutions was between $1.9{\sim}2.3ng{\cdot}m/m^2{\cdot}s{\cdot}Pa$ and was generally higher than that of the films from the acetic acid.