Polymer(Korea) (폴리머)

The Polymer Society of Korea (한국고분자학회)
권호 표지

Preparation of Poly(vinylbenzyl chloride)-grafted Fluoropolymer Films by Using Radiation Grafting Method

방사선 그래프팅에 의한 염화비닐벤질 고분자가 그래프트된 불소필름의 제조

  • Fei, Geng (Radiation Research Division for Industry and Environment Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute) ;
  • Sohn, Joon-Yong (Radiation Research Division for Industry and Environment Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute) ;
  • Lee, Youn-Sik (Division of Semiconductor & Chemical Engineering, Nanomaterials Processing Research Center, Chonbuk National University) ;
  • Nho, Young-Chang (Radiation Research Division for Industry and Environment Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute) ;
  • Shin, Jun-Hwa (Radiation Research Division for Industry and Environment Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute)
  • 경비 (한국원자력연구원 정읍방사선과학연구소 방사선공업환경연구부) ;
  • 손준용 (한국원자력연구원 정읍방사선과학연구소 방사선공업환경연구부) ;
  • 이연식 (전북대학교 반도체화학공학과, 나노소재공정연구센터) ;
  • 노영창 (한국원자력연구원 정읍방사선과학연구소 방사선공업환경연구부) ;
  • 신준화 (한국원자력연구원 정읍방사선과학연구소 방사선공업환경연구부)
  • Received : 2010.06.04
  • Accepted : 2010.07.07
  • Published : 2010.09.25
Download PDF
⟨ Previous Next ⟩

Abstract

In this study, a vinylbenzyl chloride (VBC) monomer was successfully grafted onto the several fluoropolymer films including poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP), poly(tetrafluoroethylene-co-perfluoropropylvinyl ether) (PFA), and poly(ethylene-co-tetrafluoroethylene) (ETFE) films by using a simultaneous irradiation method. The results indicated that PVBC graft polymer can be easily grafted onto the ETFE film than other fluorinated films under the same irradiation condition. The grafted films were characterized by using FTIR, TGA, and SEM-EDS instruments. The elongation at the breaking of the grafted films was found to decrease with an increase of degree of grafting (DOG). The PVBC-grafted ETFE films were found to have better mechanical properties than other PVBC-grafted fluorinated films.

본 연구에서 염화비닐벤질(vinylbenzyl chloride) 단량체는 동시조사방법을 이용하여 poly(tetrafluoroethylene-co-hexafluoropropylene)(FEP), poly(tetrafluoroethylene-co-perfluoropropylvinyl ether)(PFA), poly(ethylene-co-tetrafluoroethylene)(ETFE) 불소고분자 필름에 성공적으로 그래프트되었다. 실험 결과 같은 조사조건을 적용할 경우 다른 불소고분자 필름보다 ETFE 불소필름에 PVBC 고분자가 쉽게 그래프트됨을 확인하였다. 그래프트된 필름들은 FTIR, TGA, SEM-EDS 기기들을 사용하여 분석하였다. 그래프트된 필름의 파단신장률은 그래프트률이 증가할수록 감소되는 것을 확인하였으며 ETFE에 그래프트된 필름은 다른 불소고분자에 그래프트된 필름들과 비교하여 더 좋은 기계특성을 가지고 있음을 확인하였다.

Keywords

References

  1. H. Herman, R. C. T. Slade, and J. R. Varcoe, J. Memb. Sci., 218, 147 (2003). https://doi.org/10.1016/S0376-7388(03)00167-4
  2. R. C. T. Slade and J. R. Varcoe, Solid State Ionics, 176, 585 (2005). https://doi.org/10.1016/j.ssi.2004.09.044
  3. L. Gubler, S. A. Gürsel, and G. G. Scherer, Fuel Cells, 5, 317 (2005). https://doi.org/10.1002/fuce.200400078
  4. M. M. Nasef and E.-S. A. Hegazy, Prog. Polym. Sci., 29, 499 (2004). https://doi.org/10.1016/j.progpolymsci.2004.01.003
  5. T. N. Danks, R. C. T. Slade, and J. R. Varcoe, J. Mater. Chem., 12, 3371 (2002). https://doi.org/10.1039/b208627a
  6. S. Holmberg, P. Holmlund, C. E. Wilén, T. Kallio, G. Sundholm, and F. Sundholm, J. Polym. Sci. Part A: Polym. Chem., 40, 591 (2002). https://doi.org/10.1002/pola.10146
  7. S. D. Alexandratos and X. Zhu, Macromolecules, 36, 3436 (2003). https://doi.org/10.1021/ma0215767
  8. Y. Kimura, M. Asano, J. Chen, Y. Maekawa, R. Katakai, and M. Yoshida, Radiat. Phys. Chem., 77, 864 (2008). https://doi.org/10.1016/j.radphyschem.2007.12.012
  9. G. Fei, J. Shin, S.-A. Kang, B.-S. Ko, P.-H. Kang, Y.-S. Lee, and Y. C. Nho, J. Polym. Sci. Part A: Polym. Chem., 48, 563 (2010). https://doi.org/10.1002/pola.23762
  10. J. Shin, F. Geng, S.-A. Kang, B.-S. Ko, P.-H. Kang, and Y. C. Nho, J. Appl. Polym. Sci., 113, 2858 (2009). https://doi.org/10.1002/app.30264
  11. G. Schmidt-Naake, M. $B\ddot{o}hme$, and A. Cabrera, Chem. Eng. Technol., 28, 720 (2005). https://doi.org/10.1002/ceat.200407143
  12. A. W. Trochimczuk and S. D. Alexandratos, J. Appl. Polym. Sci., 52, 1273 (1994). https://doi.org/10.1002/app.1994.070520912
  13. J. Chen, M. Asano, Y. Maekawa, and M. Yoshida, J. Memb. Sci., 277, 249 (2006). https://doi.org/10.1016/j.memsci.2005.10.036
  14. F. Cardona, G. A. George, D. J. T. Hill, F. Rasoul, and J. Maeji, Macromolecules, 35, 355 (2002). https://doi.org/10.1021/ma0022295
  15. M. M. Nasef and H. Saidi, J. Memb. Sci., 216, 27 (2003). https://doi.org/10.1016/S0376-7388(03)00027-9
  16. J. Chen, M. Asano, M. Yoshida, and Y. Maekawa, J. Appl. Polym. Sci., 101, 2661 (2006). https://doi.org/10.1002/app.23909
  17. J. Chen, M. Asano, T. Yamaki, and M. Yoshida, J. Memb. Sci., 269, 194 (2006). https://doi.org/10.1016/j.memsci.2005.06.035
  18. S. J. Blanksby and G. B. Ellison, Acc. Chem. Res., 36, 255 (2003). https://doi.org/10.1021/ar020230d
  19. K. R. Park, P. H. Kang, and Y. C. Nho, React. Funct. Polym., 65, 47 (2005). https://doi.org/10.1016/j.reactfunctpolym.2004.11.009
  20. G. Fei, S.-A. Kang, B.-S. Ko, Y.-S. Lee, Y. C. Nho, and J. Shin, J. Appl. Polym. Sci., 117, 2380 (2010). https://doi.org/10.1002/app.32078
  21. T. R. Dargaville, G. A. George, D. J. T. Hill, and A. K. Whittaker, Prog. Polym. Sci., 28, 1355 (2003). https://doi.org/10.1016/S0079-6700(03)00047-9
  22. H.-P. Brack, H. G. Bührer, L. Bonorand, and G. G. Scherer, J. Mater. Chem., 10, 1795 (2000). https://doi.org/10.1039/b001851l
  23. J. Shin, B.-S. Ko, S.-A. Kang, G. Fei, Y. C. Nho, and P.-H. Kang, Nucl. Instrum. Meth. B, 267, 791 (2009). https://doi.org/10.1016/j.nimb.2008.12.009
  24. B. Gupta, F. N. Büchi, G. G. Scherer, and A. Chapir, J. Memb. Sci., 118, 231 (1996). https://doi.org/10.1016/0376-7388(96)00093-2
  25. H. F. Mark, N. M. Bikales, C. G. Overberger, and C. Menges, Encyclopedia of Polymer Science and Engineering, Wiley, New York, Vol 5, p 614 (1988).
  26. J. Chen, M. Asano, Y. Maekawa, and M. Yoshida, J. Polym. Sci. Part A: Polym. Chem., 46, 5559 (2008). https://doi.org/10.1002/pola.22876
  27. J. Chen, U. Septiani, M. Asano, Y. Maekawa, H. Kubota, and M. Yoshida, J. Appl. Polym. Sci., 103, 1966 (2007). https://doi.org/10.1002/app.24950
  28. J. Chen, M. Asano, T. Yamaki, and M. Yoshida, J. Appl. Polym. Sci., 100, 4565 (2006). https://doi.org/10.1002/app.22567
  29. J. Chen, M. Asano, T. Yamaki, and M. Yoshida, J. Memb. Sci., 256, 38 (2005).