• Title/Summary/Keyword: critical temperature ($T_c$)

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Fabrication and Characterization of BSCCO System High-Temperature Superconductor Tube Using Centrifigal Forming Process (원심성형법을 이용한 BSCCO계 고온초전도튜브 제조 및 특성 분석)

  • 박용민;장건익
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.9
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    • pp.801-804
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    • 2000
  • High-temperature superconductor of Bi-2212 system was fabricated by CFP(Centrifugal Forming Process). To make a uniform specimen slurry was prepared in the ratio of 7:3(powder : binder) and ball milled for 24 hours. Milled slurry was charged into a rotating mold with 450 rpm and dried at room temperature. Then the specimen was performed binder burn-out at 35$0^{\circ}C$ and heated for partial melting to 86$0^{\circ}C$. XRD analysis of most specimens were shown 2212 phase and observed a local plate shped microstructure with a well aligned c-axis direction from SEM images. Measured T$_{c}$(Critical temperature) was about 64 K.K.

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Warping Analysis of Unsymmetric Laminated Composites (비대칭 복합적층판 의 Warping 해석)

  • 전완주;홍창선
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.4
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    • pp.404-409
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    • 1983
  • The warping of unsymmetric laminated composites is induced by residual curing stress at the room temperature. Classical lamination theory (C.L.T.) predicts the room temperature shapes of all unsymmetric laminates to be a saddle. Experimental observations, however, indicate some unsymmetric laminated composites have cylindrical room temperature shapes. This anomalous behavior is explained by the extention of C.L.T. which involves Von Karman's large deflection theory. It is shown that, depending on the thickness, width, length, curing temperature and room temperature of the laminate, critical boundaries of the shape change are determined. Theoretical predictions are compared with experimental results of Toray Graphite/Epoxy {O$_{n}$/90$_{n}$}$_{T}$./....

Local transport properties of coated conductors by laser-scan imaging methods

  • Kim, Gracia;Jo, William;Nam, Dahyun;Cheong, Hyeonsik;Moon, Seoung Hyun
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.2
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    • pp.1-4
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    • 2016
  • To observe the superconducting current and structural properties of high critical temperature ($T_c$) superconductors (HTS), we suggest the following imaging methods: Room temperature imaging (RTI) through thermal heating, low-temperature bolometric microscopy (LTBM) and Raman scattering imaging. RTI and LTBM images visualize thermal-electric voltages as different thermal gradients at room temperature (RT) and superconducting current dissipation at near-$T_c$, respectively. Using RTI, we can obtain structural information about the surface uniformity and positions of impurities. LTBM images show the flux flow in two dimensions as a function of the local critical currents. Raman imaging is transformed from Raman survey spectra in particular areas, and the Raman vibration modes can be combined. Raman imaging can quantify the vibration modes of the areas. Therefore, we demonstrate the spatial transport properties of superconducting materials by combining the results. In addition, this enables visualization of the effect of current flow on the distribution of impurities in a uniform superconducting crystalline material. These imaging methods facilitate direct examination of the local properties of superconducting materials and wires.

A Statistical-Mechanical Model for Solutions of Monodisperse Micelles (단분산 마이셀 용액의 통계 역학적 모델)

  • Kang, Kye-Hong;Lim, Kyung-Hee
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.824-832
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    • 2008
  • micellar solution which is comprised of surfactant monomers, monodisperse micelles, and solvent(water) is studied from a statistical-mechanical point of view. The model examined in this article is for the ideal mixture of monomers, micelles, and solvent with the dielectric constant identical to that of solvent, which is an assumption common to continuum models. The model also reflects interactions between monomer and solvent molecule, and also between micelle and solvent molecule. The statistical-mechanical model under consideration yields ln $X_{CMC}=A+BT+C/T+D{\ln}T$ with $X_{CMC}$ being critical mcielle concentration (in mole fraction), being temperature, and A, B, C, D being constants which depend on the properties of the surfactant molecules. The statistical-mechanical model discussed in this article provides a theoretical basis on the thermal dependence of critical micelle concentration

Evolution of surface morphology and roughness in Si and $_{0.7}$Ge$_{0.3}$ thin fimls (Si 및Si$_{0.7}$Ge$_{0.3}$ 박막의 표현형태 및 조도의 전개)

  • 이내웅
    • Journal of Surface Science and Engineering
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    • v.31 no.6
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    • pp.345-358
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    • 1998
  • The evolution of surface roughness and morphology in epitaxial Si and $Si_{0.7}Ge{0.3}$ alloys grown by UHV opm-beam sputter deposition onto nominally-singular, [100]-, and [110]-mi-scut Si(001) was investigated by stomic force microscopy and trasmission electron microscopy. The evolution of surface roughness of epitaxial Si films grown at $300^{\circ}C$ is inconsistent with conventional scaling and hyperscaling laws for kineti roughening. Unstable growth leading to the formation of mounds separated by a well-defined length scale is observed on all substrates. Contraty to previous high-temperature growth results, the presence of steps during deposition at $300^{\circ}C$ increases the tendency toward unstable growth resulting in a much earlier development of mound structures and larger surface roughnesses on vicival substrates. Strain-induced surface roughening was found to dominate in $Si_{0.7}Ge{0.3}$ alloys grown on singular Si(001) substrates at $T_S\ge450^{\circ}C$ where the coherent islands are prererentially bounded along <100> directions and eshibt {105} facetting. Increasing the film thickness above critical values for strain relaxation leads to island coalescence and surface smoothening. At very low growth temperatures ($T_s\le 250^{\circ}C$), film surfaces roughen kinetically, due to limited adatom diffusiviry, but at far lower rates than in the higher-temperature strain-induced regime. There is an intermediate growth temperature range, however, over which alloy film surfaces remain extremely smooth even at thicknesses near critical values for strain relaxation.

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Magnetic properties of polycrystalline Tl-1223 superconductor (Tl-1223 다결정 초전도체의 자기적 특성)

  • Baek R;Lee J. H;Kim Y. C;Jeong D. Y
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.41-45
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    • 2004
  • Polycrystalline Tl-1223 superconductors with a chemical composition of (Tl, Pb, Bi)TEX>$ (Sr, Ba)<_2$$Ca_2$$Cu_3$$O_{x}$ were synthesized by the solid state reaction method. The optimum chemical composition was $Tl_{0.8}$ $Pb_{0.2}$ $Bi_{0.2}$ $Sr_{1.8}$ $Ba_{0.2}$ $Ca_{2.2}$ $Cu_3$$O_{x}$ And the optimum sintering temperature and time were $905^{\circ}C$ and 7.5h, respectively. The sample was evaluated for their superconducting properties by magnetization measurement. The critical temperature $T_{c}$ is 120 K and the critical current density $J_{c}$ (T=5K, 0T) is estimated to be ∼ $10^{5}$ A/$\textrm{cm}^2$ for $Tl_{0.8}$ $Pb_{0.2}$ $Bi_{0.2}$ $Sr_{1.8}$ $Ba_{0.2}$ $Ca_{2.2}$$Cu_3$$O_{x}$ .

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Investigation on the phonon behavior of MgB2 films via polarized Raman spectra

  • R. P. Putra;J. Y. Oh;G. H. An;H. S. Lee;B. Kang
    • Progress in Superconductivity and Cryogenics
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    • v.26 no.1
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    • pp.14-19
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    • 2024
  • In this study, we explore the anisotropy of electron-phonon coupling (EPC) constant in epitaxially grown MgB2 films on c-axis oriented Al2O3, examining its correlation with the critical temperature (Tc) and local structural disorder assessed through polarized Raman scattering. Analysis of the polarized Raman spectra reveals angle-dependent variations in the intensity of the phonon spectra. The Raman active mode originating from the boron plane, along with two additional phonon modes from the phonon density of states (PDOS) induced by lattice distortion, was distinctly observed. Persistent impurity scattering, likely attributed to oxygen diffusion, was noted at consistent frequencies across all measurement angles. The EPC values derived from the primary Raman active phonon do not significantly vary with changing observation angles, followed by that the Tc values calculated using the Allen and Dynes formula remain relatively constant across all polarization angles. Although the E2g phonon mode plays a crucial role in the EPC mechanism, the determination of Tc values in MgB2 involves not only electron-E2g coupling but also contributions from other phonon modes.

A Study on Frequency Response of GaAs MESFET with different Temperatures (온도변화에 따른 GaAs MESFET의 주파수 특성에 관한 연구)

  • 정태오;박지홍;안형근;한득영
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.550-553
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    • 2001
  • In this study, unity current gain frequency f$\_$T/ of GaAs MESFET is predicted with different temperatures up to 400 $^{\circ}C$. Temperature dependence parameters of the device including intrinsic carrier concentration n$\_$i/ effective mass, depletion width are considered to be temperature dependent. Small signal parameters such as gate-source, gate dran capacitances C$\_$gs/ C$\_$gd/ are correlated with transconductance g$\_$m/ to predict the unity current gain frequency. The extrinsic capacitance which plays an important roles in high frequency region has been taken into consideration in evaluating total capacitance by using elliptic integral through the substrate. From the results, f$\_$T/ decreases as the temperature increases due to the increase of small signal capacitances and the mobility degradation. Finally the extrinsic elements of capacitances have been proved to be critical in deciding f$\_$T/ which are originated from the design rule of the device.

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Existence of a vortex-glass phase transition in an optimally doped BaFe1.8Co0.2As2 single crystal

  • Choi, Ki-Young;Kim, Kee Hoon
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.2
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    • pp.16-19
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    • 2013
  • The magneto-resistivity and electric field-current density (E-J) curves were investigated up to a magnetic field 9 T in the optimally doped $BaFe_{1.8}Co_{0.2}As_2$ single crystal with a superconducting temperature ($T_c$) of 24.6 K. The E-J Scaling behaviors below and above vortex glass transition temperature ($T_g$) were found, confirming the existence of the vortex glass phase transition. The critical exponents for the diverging spatial and time correlations at $T_g$, were obtained as v = $1.1{\pm}0.1$ and z = $4.5{\pm}0.3$, respectively. The obtained critical exponents are in good agreement with the predicted values of v ~ 1 - 2 and z > 4 within the 3D vortex glass theory.

Synthesis and Characterization of Comb-Type Grafted Polymer Hydrogels with Low Temperature Sensitivity (저온 감열 특성을 가지는 Comb-Type Grafted Polymer Hydrogels의 합성 및 특성평가)

  • Taek Kyu Jung;Sung Soo Kim;Byung Cheol Shin
    • Journal of the Korean Chemical Society
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    • v.47 no.1
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    • pp.59-66
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    • 2003
  • The comb-type grafted polymer hydrogels, which composed of N-isopropylacrylamide monomer and oligo(N-isopropylacrylamide-co-tert-butylacrylamide) [oligo(NIPAAm-co-t-BAM)], were synthesized by redox polymerization in 5~10% methanol aqueous solution using ammonium peroxodisulfate (APS) at 4 oC for 24h. The lower critical solution temperatures (LCSTs) of the comb-type grafted hydrogels were decreased with increase of t-BAM content in the grafted copolymer. We observed the effect of crosslinker and concentration of oligo(NIPAAm-co-t-BAM) on the shrinking/swelling ratio of hydrogels. Changes of shrinking/swelling ratio were decreased with increase of concentration of crosslinker. The increase of grafted oligo(NIPAAm-co-t-BAM) in the hydrogel shows an fast changes of shrinking/ swelling rate. The comb-type grafted hydrogels are expected to be valuable for the sensing materials of time-temperature labels(TTLs).