• 청정기술
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• 제27권2호
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• pp.115-123
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• 2021

본 연구는 무기 실리카 껍질(shell)과 유기 고분자 코어(core)로 구성된 매우 균일한 유-무기 복합체 입자 제조의 방법에 관한 것이다. 먼저, 미세유체 기술을 이용하여 균일한 크기를 지니는 유기 고분자 코어 입자를 제조하였다. 코어 입자의 제조 과정에서 코어 입자의 제조 과정에서 광 경화성 유기 물질이 포함된 분산상과 연속상의 유속을 독립적으로 제어함으로써 균일한 액적을 형성하였다. 액적이 형성됨과 동시에, 미세유체 채널의 말단에서 자외선 조사에 의해 액적이 광중합 되어 코어 입자로 형성된다. 더불어, 폴리알릴아민 하이드로클로라이드(polyallylamine hydrochloride, PAH)와 인산 이온(phosphate ion)으로 구성된 나노 복합체는 최적화된 pH 조건에서 수소결합과 정전기적 인력 같은 강력한 상호작용을 통해 코어 입자에 코팅된다. 폴리아민 나노 복합체에 존재하는 PAH 주쇄의 아민 그룹들은 규산(silicic acid)의 축합(condensation) 반응을 촉매하여, 코어 입자 표면의 실리카 나노입자 성장을 시킬 수 있었다. 따라서, 본 방법을 통해 유기 코어에 무기 실리카 나노입자로 코팅된 유-무기 복합체 입자를 제조할 수 있었다. 최종적으로, 본 연구에서 제시한 방법은 보다 온화하며 환경친화적인 조건 하에서 단시간 내에 유-무기 복합체 입자를 합성할 수 있으며, 다양한 모양과 크기를 갖는 코어 입자에 적용되어 넓게 활용될 수 있다.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2009년도 학술논문요약집
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• pp.84-85
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• 2009

New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

• Bulletin of the Korean Chemical Society
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• 제23권6호
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• pp.872-879
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• 2002

One of the improtant characteristics of core-shell type nanoparticles is the long-term storage and reuse as an aqueous injection solution when required. For this reason, reconstruction of lyophilized core-shell type nanoparticles is considered to be essential . BAB type triblock copolymers differ from AB type diblock copolymers, which contain the A block as a hydrophilic part and the B block as a hydrophobic part. by not being easily redistributed into phosphate-buffered saline (PBS, pH 7.4, 0.1 M). Therefore, lyophilized core-shell type nanoparticles of CEC triblock copolymer were reconstituted using a somication process with a bar-type sonicator in combination with a freezing-thawing process. Soncation for 30s only resuspended CEC nanoparticles in PBS; their particle size distribution showed a monomodal pattern with narrow size distribution. The bimodal size distribution pattern and the aggregates were reduced by further sonication for 120 s but these nanoparticles showed a wide size distribution. The initial burst of drug release was increased by reconstitution process. The reconstitution of CEC core-shell type nanoparticles by freezing-thawing resulted in trimodal distribution pattern and formed aggregates, although freezing-thawing process was easier than sonication . Drug release form CEC nanoparticles prepared by freezing-thawing was slower than from the original dialysis solution. Although core-shell typenanoparticles of CEC triblock copolymers were not easily performed. Cytotoxicity testing of core-shell type nanoparticles of CEC-2 triblock copolymers containing clonazepam (CNZ) was performed using L929 cells. Cytotoxicity of CNZ was decreased by incorporation into nanoparticles.

• Preventive Nutrition and Food Science
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• 제4권2호
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• pp.145-151
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• 1999

Apolipoprotein B-100 (apo B-100) is an important component in plasma low density lipoproteins (LDL). It function as the ligand for the LDL receptor in peripheral cells. The LDLs are removed from the circulation by both high-affinity receptor-mediated and receptor-independant pathways. LDLs are heterogeneous in their lipid content, size and density and certain LDL subspecies increase risk of atherosclerosis due to differences in the conformation of apo B in the particle. In the present study , surface and core peptide fraction of Apo B-100 have been characterized by comparing peptide-mapping and fluorescence spectroscopy. Surface fragments of apo B-100 were generated by digestion of LDL with either trypsin , pronase, or pancreatin elastase. Surface fractions were fractionated on a Sephadex G-50 column. The remaining core fragments were delipidated and redigested with the above enzymes, and the resulting core peptides were compared with surface peptides. Results from peptide-mapping by HPLC showed pronase-digestion was more extensive than trypsin -digestion to remove surface peptide fraction from LDL. Fluorescence spectra showed that core fractions contained higher amount of tryptophan than surface fractions, and it indicated that core fraction wa smore hydrophobic than surface fractions. A comparison of the behavior of the core and surface provided informations about the regions of apo B-100 involved in LDL metabolism and also about the structural features concerning the formation of atherosclerosis.

• 한국수소및신에너지학회논문집
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• 제25권1호
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• pp.97-104
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• 2014

In a coal gasifier for IGCC, hot syngas leaving the gasifier at about 1550oC is rapidly quenched by cold syngas recycled from the gas cleaning process. This study investigated the flow and heat transfer characteristics in the gas quench system of a commercial IGCC process plant under different operating pressures. As the operating pressure increased from 30 bar to 50 bar, the reduced gas velocity shortened the hot syngas core. The hot fly slag particles were retained within the core more effectively, and the heat transfer became more intensive around the hot gas core under higher pressures. Despite the high particle concentrations, the wall erosion by particle impaction was estimated not significant. However, large particles became more stagnant in the transfer duct due to the reduced gas velocity and drag force under higher pressures.

• Macromolecular Research
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• 제9권2호
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• pp.122-128
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• 2001

Monodisperse composite latex particles with size of ca. 300 nm, which consist ofn-butyl acrylate as a soft phase and methyl methacrylate as a hard phase with different morphology, were synthesized by seeded multi-stage emulsion polymerization. Three types of composite latex particles including random-, core/shell-, and gradient-type particles were obtained by using different monomer feeding methods during semi-batch emulsion polymerization. Effect of poly(butyl acrylate)-poly(methyl methacrylate) rubber particle morphology on the mechanical and rheological properties of rubber toughened poly(methyl methacrylate) was investigated. Among three different rubber particles, the gradient-type rubber particle showed better toughening effect than others. No significant variation of rheological property of poly(methyl methacrylate)/rubber blends was observed for the different rubber particle morphology.

• 천문학회보
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• 제35권2호
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• pp.45.1-45.1
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• 2010

Using SOHO particle and EUV detection and radio spectrograms from both ground-based and spaceborne instruments, we have studied the first phase of major solar energetic particle (SEP) events associated with wide and fast coronal mass ejections (CMEs) centered at different solar longitudes. Observations support the idea that acceleration of SEPs starts in the helium-rich plasma of the eruption's core well behind the CME leading edge, in association with coronal shocks and magnetic reconnection caused by the CME liftoff; and those "coronal" components dominate during the first ~1.5 hour of the SEP event, not yet being hidden by the CME-bow shock in solar wind. At magnetic connection to the eruption's periphery, onset of SEP emission is delayed for a time of the lateral expansion that is visualized by global coronal (EIT) wave. The first, "coronal" phase of SEP acceleration is followed by a second phase associated with CME-driven shock wave in solar wind, which accelerates high-energy ions from a helium-poor particle population until the interplanetary shock slows down to below 1000 km/s. Based on these and other SOHO observations, we discuss what findings can be expected from STEREO in the SOHO era perspective.

• Nuclear Engineering and Technology
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• 제56권2호
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• pp.575-600
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• 2024

During an earthquake on December 29th 2020, the Krško NPP automatically shutdown due to the trigger of the negative neutron flux rate signal on the power range nuclear instrumentation. From the time course of the detector signal, it can be concluded that the fluctuation in the detector signal may have been caused by the mechanical movement of the ex-core neutron detectors or the pressure vessel components rather than the actual change in reactor power. The objective of the analysis was to evaluate the sensitivity of the neutron flux at the ex-core detector position, if the detector is moved in the radial or axial direction. In addition, the effect of the core barrel movement and core inside the baffle movement in the radial direction were analysed. The analysis is complemented by the calculation of the thermal and total neutron flux gradient in radial, axial and azimuthal directions. The Monte Carlo particle transport code MCNP was used to study the changes in the response of the ex-core detector for the above-mentioned scenarios. Power and intermediate-range detectors were analysed separately, because they are designed differently, positioned at different locations, and have different response characteristics. It was found that the movement of the power range ex-core detector has a negligible effect on the value of the thermal neutron flux in the active part of the detector. However, the radial movement of the intermediate-range detector by 5 cm results in 7%-8% change in the thermal neutron flux in the active part of the intermediate-range detector. The analysis continued with an evaluation of the effects of moving the entire core barrel on the ex-core detector response. It was estimated that the 2 mm core barrel radial oscillation results in ~4% deviation in the power and intermediate-range detector signal. The movement of the reactor core inside baffle can contribute ~6% deviation in the ex-core neutron detector signal. The analysis showed that the mechanical movement of ex-core neutron detectors cannot explain the fluctuations in the ex-core detector signal. However, combined core barrel and reactor core inside baffle oscillations could be a probable reason for the observed fluctuations in the ex-core detector signal during an earthquake.

• Journal of Pharmaceutical Investigation
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• 제16권1호
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• pp.12-17
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• 1986

Etilefrine hydrochloride was microencapsulated with ethylcellulose by phase separation method to develop a sustained release dosage form. The results of dissolution test carried out with various microcapsules showed that the drug release was decreased with increasing the particle size of microcapsules at a constant core to wall ratio, and with decreasing the core to wall ratio. Also ethylcellulose 50 cps and fast stirring rate (900 rpm) was better in decreasing the drug release than ethylcellulose 22 cps and slow stirring rate (300 rpm), respectively.

• Nuclear Engineering and Technology
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• 제42권3호
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• pp.297-304
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• 2010

In the design of advanced light water reactors (ALWRs) and in the safety assessment of currently operating nuclear power plants, it is necessary to evaluate the possibility of experiencing a degraded core accident and to develop innovative safety technologies in order to assure long-term debris cooling. The objective of this experimental study is to investigate the enhancement factors of dryout heat flux in debris beds by coolant injection from below. The experimental facility consists mainly of an induction heater, a double-wall quartz-tube test section containing a steel-particle bed and coolant injection and recovery condensing loop. A fairly uniform heating of the particle bed was achieved in the radial direction and the axial variation was within 20%. This paper reports the experimental data for 3.2 mm and 4.8 mm particle beds with a 300 mm bed height. The dryout heat density data were obtained for both the top-flooding and the forced coolant injection from below with an injection mass flux of up to $1.5\;kg/m^2s$. The dryout heat density increased as the rate of coolant injection increased. At a coolant injection mass flux of $1.0\;kg/m^2s$, the dryout heat density was ${\sim}6.5\;MW/m^3$ for the 4.8 mm particle bed and ${\sim}5.6\;MW/m^3$ for the 3.2 mm particle bed. The enhancement factors of the dryout heat density were 1.6-1.8.