• Title/Summary/Keyword: contamination performance

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The Effect of Methane in Hydrogen on the Performance of Proton Exchange Membrane Fuel Cell (수소연료 중의 메탄에 의한 고분자전해질 연료전지 성능변화 연구)

  • Seo, Jung-Geun;Kwon, Jun-Taek;Kim, Jun-Bum;Chung, Jong-Tae;Kim, Woo-Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.4
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    • pp.432-438
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    • 2007
  • The reforming process for hydrogen production generates some impurities. Impurities in hydrogen such as $CO_2$, CO, $H_2S$, $NH_3$ affect fuel cell performance. It is well known that CO generated by the reforming process may negatively affect performance of cell, cause damage on catalysts resulting performance degradation. Hydrogen produced by reforming process includes about 2% methane. The presence of methane up to 10% is reported negligible degradation in cell performance. However, methane more than 10% in hydrogen stream had not been researched. The concentration of impurity supplied to the fuel cell was verified by gas chromatography(GC). In this study, the influence of $CH_4$ on performance of PEM fuel cell was investigated by means of current vs. potential experiment, long run(10 hr) test and electrochemical impedance measurement when the concentrations of impurities were 10%, 20% and 30%.

Mold Growth and Mycotoxin Contamination of Forages (조사료의 곰팡이 발생과 곰팡이독소 오염)

  • Sung, Ha-Guyn;Lee, Joung-Kyong;Seo, Sung;Lim, Dong-Cheul;Kim, Jong-Duk
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.30 no.1
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    • pp.77-88
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    • 2010
  • In order to ensure good animal health and performance, it is essential to produce forages with high feeding value and good hygienic quality. However, huge amounts of forages consumed by ruminants are contaminated with mold prior to harvest or during storage as hay, straw or silage. These mold can grow in forages only when nutrients are available, correct temperature exist, oxygen is present, and unbound water is available. Fungal 'species can be divided into two groups: field fungi and storage fungi. Field fungi invade the forages while the crop is still in the field, require high moisture conditions, and are such as species of Fusarium, Alternaria, Clodosporium, Diplodia, Gibberrella and Helminthosporium. Storage fungi invade forages during storage and need less moisture than field fungi. These such as species of Aspergillus and Penicillium usually do not occur any problem before harvest. Mold growth can spoil the nutritional aspects of the forages and also results in secondary metabolites that are highly toxic to animal, humans and plants. Moldy feeds are less palatable and may reduce dry matter intake. This, in turn, leads to a reduction of nutrition intake, reducing weight gains or milk production. Performance losses of 5 to 10 percent are typical with moldy feeds. Mycotoxins are toxic substances produced by fungi (molds) growing on crops in the field or storages. While greater than 400 mycotoxins have been chemically identified, the biological or veterinary medical impact of only several mycotoxins is known. Mycotoxins have attracted considerable attention as potential causes for poor performance and health disorders in domestic livestock. They can be carcinogenic, hepatotoxic, hematotoxic, immunosuppressive, estrogenic, or mutagenic. So, feeding moldy forages has adverse effects on animal health and milk consumers. Also, this author reported that rice straw hay was contaminated mycotoxigenic fungi such as Penicillium roqueforti and Fusarium culmorum in Korea. Therefore, it is an urgent need to develop an improved post harvest storage method to reduce nutrient loss and mycotoxin contamination of forages, which will have a positive impact on human health.

Factors Related to Sanitary Management Performance Based on HACCP System in School Foodservice - Seoul, Gyeonggi, Kangwon and Choongchung Areas in Korea - (HACCP 시스템 적용 학교급식 위생관리 수행수준에 영향을 미치는 요인 - 서울, 경기, 강원, 충청지역을 중심으로 -)

  • Kim, Gyoung-Mi;Lee, Sim-Yeol
    • Korean Journal of Community Nutrition
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    • v.14 no.6
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    • pp.817-830
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    • 2009
  • The purpose of this study was to analysis the sanitary management performance based on HACCP system for school foodservice. This study was carried out from September 2008 until December 2008 and is targeted towards schools' dietitians that work at schools with school foodservice. The regional distribution of this research is as follows; 377 schools in Seoul, 648 schools in Gyeonggido, 160 schools in Kangwondo, 438 schools in Choongchungdo equaling 1,623 schools in total. When school foodservices were put through sanitation management achievement level analysis applied by the HACCP system, results displayed that management of temperature (3.96 points), time (4.08 points), and cross-contamination (4.07 points) were all below the average achievement level. HACCP system's achievement level based on the TQM showed that areas for strategy development, leadership, information and analysis had low achievement levels. Achievement levels for CCP are quality check, delivery/distribution process, sterilization/cleansing of food's contact surface. As a result of multiple regression analysis of the factors that influenced sanitation management achievement level of school foodservice HACCP system; sanitary job standard showed 35.6% and CCP achievement levels showed 26.8% explanatory rate. In particular, Kangwondo's number of foodservice provided to per cook was small. Also, the better the processing management was assessed, the higher the sanitary job standard achievement level became resulting to a explanatory rate of 39.5%. Elementary schools showed a higher explanatory rate of 37.0% than middle and high schools. CCP achievement levels in middle and high schools with self-operated foodservice had a 28.0% variable explanatory rate, which was the highest. The better the drainage system, leadership and assessments turned out to be, the higher the CCP achievement levels became. In summary, to revitalize HACCP system that is based on the TQM, it is considered that proper database of HACCP system for school foodservice's sanitation management be constructed and more emphasis should be put on strategy development to improve customers' satisfactory level. In addition, improvements in achievement levels of time, temperature, and cross-contamination for sanitary job standard and CCP achievement level are essential.

Pretreatment of Fish for the determination of polycyclic aromatic hydrocarbons using alkali digestion (알칼리분해를 이용한 어류 중 다환방향족탄화수소의 전처리방법)

  • Hu, Soojung;Lee, Hyomin;Chae, Youngzoo;Yoo, Eun-Ah
    • Analytical Science and Technology
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    • v.18 no.5
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    • pp.403-409
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    • 2005
  • Polycyclic Aromatic Hydrocarbons(PAHs) contamination arises from several sources including processing of food(smoking, direct drying, cooking) and environmental contamination of air, water, or soil, the later being considered as the most important. In this study, to establish the analytical method for some PAHs[benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene, indeno(1,2,3-c,d)pyrene] in fish, alkali digestion time, extraction solvents, elution volume of florisil cartridge for clean-up have been optimized. The methodology involved saponification and extraction with n-hexane, clean-up on Sep-Pak florisil cartridges and determination by HPLC/FLD(High Performance Liquid Chromatography/Fluorescence Detector). Overall method recoveries for 8 PAHs spiked into these products ranged from 90 to 106%.

Physiochemical Treatment of Feed and Utilization of Feed Additives to Control Salmonella in Poultry (가금의 살모넬라 제어를 위한 사료의 이화학적 처리와 사료첨가제의 활용)

  • Kim, Ji-Hyuk;Kim, Hack-Youn;Kim, Bong-Ki;Kim, Gye-Woong
    • Korean Journal of Poultry Science
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    • v.45 no.1
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    • pp.1-15
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    • 2018
  • Salmonella infections in livestock industry cause various problems such as worsening animal welfare and productivity, damaging consumer confidence in the food safety of animal products. Chicken meat and eggs are known as major source of pathogen causing human foodborne infections. Therefore food safety concerns have prompted the poultry producers and governments to introduce the strategy and regulation to control these pathogens. Salmonella can persist for long periods of time in a wide range of spaces including feed bin, feed processing facilities, poultry farm, slaughterhouse, processing plants, etc. For the effective and constant Salmonella control, combination of pre-harvest, harvest and post-harvest measures should be considered comprehensively. The control measures would be most effective at farm level where the contamination initiates. Transmission of pathogen from feed origin to the live poultry and finally to the products was proven already. To control bacteria in the feed ingredients and formula feed, thermal processing, irradiation or chemical treatment may be applied. Chemical treatments to inhibit Salmonella in the feed involve the use of products containing organic acids, formaldehyde, or a combination of such compounds. However, recontamination which might occur during storage and transport process and/or by other various factors should always be under control and eliminated. Feed additives used to control Salmonella in birds' gastrointestinal track can be of various types, including prebiotics, probiotics, organic acids and bacteriophages. Although their mode of action varies, they ultimately inhibit the colonization of Salmonella in the gut and improve the performance of birds. This review describes the strategies that could be adapted to the management of feedstuffs and the use of feed additives in pre-harvest stage to control Salmonella contamination in poultry farming.

Characteristics of Microbial Fuel Cells Using Livestock Waste and Degradation of MEA (가축 분뇨를 이용한 미생물 연료전지의 특성 및 MEA 열화)

  • Kim, Young-Sook;Chu, Cheun-Ho;Jeong, Jae-Jin;Ahn, Myung-Won;Na, Il-Chai;Lee, Jeong-Hoon;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.175-181
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    • 2014
  • Microbial fuel cells (MFC) were operated with livestock wastes and PEMFC (Proton Exchange Membrane Fuel Cells) MEA (Membrane and Electrode Assembly). OCV of MFC with mixtures of microbial was higher than that of MFC with single microbial. MFC using pig wastes showed highest OCV (540 mV) among cow waste, chicken waste and duck waste. And the power density of MFC using pig waste was $963mW/m^2$. Contamination of MEA with $Na^{2+}$, $Ca^{2+}$, $K^+$ ion and impurities was the one cause for low performance of MFC during operation.

Analysis of Oil Species of Illegally Disposed Oil (무단 투기 유류에 대한 유종 해석)

  • Lim, Young-Kwan;Lee, Eun-Yul;Seong, Sang-Rae;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.664-668
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    • 2016
  • The contamination in soil, underground water and river environment became serious due to illegal waste dumping. In this study, our research group analyzed the oil species of illegally disposed oils from J City. After pretreating the mixture of oil, water and solid phases to obtain homogeneous phase components, the physical property analysis, atom analysis, and gas chromatography were performed. From the results showing 11.8% of oxygen content, $-6^{\circ}C$ of pour point and chromatogram pattern. the contaminated oil was identified as a vegetable one. High performance liquid chromatography (HPLC) analysis was also performed in order to know what kind of vegetable oil was, and the ratio of LLO, OOL and POL was found to be high indicating that the disposed oil is majorly the used soybean oil with some vegetable oil mixtures. This study can be used for identifying contaminators for oils from the illegal waste dumping.

The Presence of Polycyclic Aromatic Hydrocarbons (PAHs) in Grilled Beef, Chicken and Fish by Considering Dietary Exposure and Risk Assessment

  • Sahin, Seyda;Ulusoy, Halil Ibrahim;Alemdar, Suleyman;Erdogan, Selim;Agaoglu, Sema
    • Food Science of Animal Resources
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    • v.40 no.5
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    • pp.675-688
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    • 2020
  • Polycyclic aromatic hydrocarbons (PAHs) are dangerous chemical compounds that can be formed by cooking foods at high temperatures. The aim of this study is to determine the level of contamination of PAH compounds with high performance liquid chromatography (HPLC) on heat treated meat samples and the consumption of PAH compounds in meat samples, as well as the dietary exposure status and possible health risk estimation. In five different heat treated meat samples (meat doner, chicken doner, meatballs, grilled chicken, and fish), the total PAH (Σ16PAH) contamination level was 6.08, 4.42, 4.45, 4.91, and 7.26 ㎍/kg, respectively. Benzo[a]pyrene (BaP) in meatballs and grilled fish samples had a level 0.70 and 0.73 ㎍/kg. All of the samples analyzed were found to be below the EU permitted limit (5 ㎍/kg) in terms of BaP. Estimates of daily intake (EDI) for a total of 16PAH in heat treated meat doner, chicken doner, meatballs, grilled chicken and fish samples were 3.41, 3.71, 2.49, 4.12, and 1.77 ng/kg bw/day, respectively. In this study, the average margin of exposure (MOE) value calculated was found in the range of 179.487 and 425.000 for BaP and PAH4. This study is the first study to provide important information in terms of evaluating the possible health risk that PAH compounds can create in people's diets due to heat treatment of meat and meat products in Sivas, Turkey.

Development of Wireless Real-Time Gas Detector System for Chemical Protection Performance Test of Personal Protective Equipment (화생방 보호의 성능평가를 위한 무선 실시간 가스 검출기 개발)

  • Kah, Dong-Ha
    • Journal of the Korea Institute of Military Science and Technology
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    • v.23 no.3
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    • pp.294-301
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    • 2020
  • Man-In-Simulant Test(MIST) provides a test method to evaluate chemical protective equipments such as protective garments, gloves, footwear and gas mask. The MIST chamber is built to control concentration of chemical vapor that has a activity space for two persons. Non-toxic methyl-salicylate(MeS) is used to simulate chemical agent vapor. We carried out to measure inward leakage MeS vapors by using passive adsorbent dosimeter(PAD) which are placed on the skin at specific locations of the body while man is activity according to the standard procedure in MIST chamber. But more time is required for PADs and there is concern of contamination in PADs by recovering after experiment. Therefore detector for measuring in real time is necessary. In order to analyze in real time the contamination of the personal protective equipment inside the chemical environment, we have developed a wireless real-time gas detector. The detector consists of 8 gas-sensors and 1 control-board. The control-board includes a CPU for processing a signal, a power supply unit for biasing the sensor and Bluetooth-chipset for transmission of signals to external PC. All signals from gas-sensors are converted into digital signals simultaneously in the control-board. These digital signals are stored in external PC via Bluetooth wireless communication. The experiment is performed by using protective equipment worn on manikin. The detector is mounted inside protective equipment which is capable of providing a real-time monitoring inward leakage MeS vapor. Developed detector is demonstrated the feasibility as real-time detector for MIST.

Phoswich Detector for Simultaneous Measuring Alpha/beta Particles (알파/베타선 동시측정용 phoswich 검출기)

  • Kim, Gye-Hong;Park, Chan-Hee;Lee, Kune-Woo;Jung, Chong-Hun;Seo, Bum-Kyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.2
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    • pp.111-117
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    • 2008
  • The new type phoswich detector consisting of the ZnS(Ag) and plastic scintillator for alpha/beta-ray simultaneous counting was developed for monitoring radiological contamination inside pipes. The detection performance was estimated using the PSD (pulse shape discrimination) method as a function of distance between the scintillator and radioactive source. The attenuation of particles traveling through a thin film for preventing the detector from being contaminated was experimentally estimated. It is concluded from our investigation that the phoswich detector developed can provide a sufficient alpha/beta-ray discrimination. The application of a thin film for preventing the detector from being contaminated was proven to be feasible.

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