• 대한기계학회논문집
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• 제17권10호
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• pp.2611-2623
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• 1993

To construct the design back data for a lean-burn gas engine, we investigated the combustion characteristics in the main chamber using a constant volume combustion chamber with subchamber. The combustion characteristics with configuration change of the critical passageholes have been studied by taking pressure data, schlieren photograph, ion current and light emission signal of flame. Heat release rate with various critical passageholes also have been analysed by using the combustion model of a prechamber diesel engine. It was found that combustion characteristics in the main combustion chamber were greatly influenced by the geometric configurations of critical passagehole.

• Bulletin of the Korean Chemical Society
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• 제32권6호
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• pp.1939-1944
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• 2011

The nucleophilic substitution reactions of bis(Y-aryl) chlorophosphates (1) with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at 35.0 $^{\circ}C$. The kinetic results of 1 are compared with those of Y-aryl phenyl chlorophosphates (2). The substrate 1 has one more identical substituent Y compared to substrate 2. The cross-interaction between Y and Y, due to additional substituent Y, is significant enough to result in the change of the sign of cross-interaction constant (CIC) from negative ${\rho}_{XY}$ = -1.31 (2) to positive ${\rho}_{XY}$ = +1.91 (1), indicating the change of reaction mechanism from a concerted $S_N2$ (2) to a stepwise mechanism with a rate-limiting leaving group departure from the intermediate (1). The deuterium kinetic isotope effects (DKIEs) involving deuterated anilines ($XC_6H_4ND_2$) show secondary inverse, $k_H/k_D$ = 0.61-0.87. The DKIEs invariably increase as substituent X changes from electron-donating to electron-withdrawing, while invariably decrease as substituent Y changes from electron-donating to electron-withdrawing. A stepwise mechanism with a rate-limiting bond breaking involving a predominant backside attack is proposed on the basis of positive sign of ${\rho}_{XY}$ and secondary inverse DKIEs.

• International Journal of Fluid Machinery and Systems
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• 제6권3호
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• pp.137-143
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• 2013

To improve annular jet pump (AJP) performance, new ways named constant rate of velocity/pressure change method (CRVC/CRPC) were adopted to design its diffuser. The design formulas were derived according to the assumption of linear velocity/pressure variation in the diffuser. Based on the two-dimensional numerical simulations, the effect of the diffuser profile and the included angle on the pump performance and the internal flow details has been analyzed. The predicted results of the RNG k-epsilon turbulence model show a better agreement with the experiment data than that of the standard and the realizable k-epsilon turbulence models. The AJP with the CRPC diffuser produces a linear pressure increase in the CRPC diffuser as expected. The AJP with CRPC/CRVC diffuser has better performance when the diffuser included angle is greater or the diffuser length is shorter. Therefore, the AJP with CRPC/CRVC diffuser is suitable for applications requiring space limitation and weight restriction.

• 대한화학회지
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• 제30권1호
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• pp.3-8
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• 1986

물-글리세롤, 물-에틸렌 글리콜, 물-이소프로필 알코올 및 물-t-부틸 알코올의 2성분 혼합용매 중에서 cis-$[Co(en)_2ClNO_2]^+$착이온의 가용매 분해반응을 분광광도법으로 연구하였다. 용매의 극성이 커짐에 따라 반응속도도 커지는 경향이 있었으며 반응속도의 대수값과 $\frac{D-1}{2D+1}$값을 도시한 결과 비직선적인 관계를 나타내는 것으로 보아서 용매의 수소결합이나 분산력등의 비정전기적인 상호작용이 지배적으로 작용함을 알 수 있었다. log k와 Grundwald-Winstein의 Y값을 도시한 직선의 기울기와 Kivinen식에서 구한 전이상태에 관여하는 물분자의 수 n값으로부터 실험에 사용한 착물의 가용매 분해반응은 Id메카니즘으로 진행됨을 알았다. 한편 자유에너지 사이클의 결과는 초기상태에서 보다 전이상태에서 용매구조의 효과가 더 큼을 알 수 있었다.

• 대한기계학회논문집B
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• 제24권11호
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• pp.1486-1496
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• 2000

The initial flame kernel development and flame propagation in a constant volume combustion chamber is analyzed by the heat release rate and the mass fraction burnt. The combustion pressure is measured with a piezoelectric type pressure sensor. In order to evaluate the effects of ignition system and ignition energy on the flame propagation, four different ignition systems are designed and tested, and the ignition energy is varied by the dwell time. Several different spark plugs are also tested and examined to analysis the effects of electrodes on flame kernel development. The results show that the when the dwell time is increased, and when the spark plug gap is extended, heat release rate and the mass burnt fraction are increased. The materials and shapes of electrodes affect the flame development, because they change the energy transfer efficiency from electrical energy to chemical energy. The diameter of electrodes influences not only the heat release rate but also the mass burnt fraction as well.

• 유체기계공업학회:학술대회논문집
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• 유체기계공업학회 1999년도 유체기계 연구개발 발표회 논문집
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• pp.46-51
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• 1999

This paper describes the control charcteristics of thermal/flow systems. In thermal/flow systems, the transport lag plays as a dead time causing a deterioration of the controllability. Besides this, such many parameters including the temperature, pressure, and flow rate affect the system response that a control scheme which can deal with multi-input is required. Particularly in a refrigerant compressor test facility, the evaporator and condenser interact each other so that the change in the evaporator pressure cause the condenser pressure to change or vice versa. Therefore, to control the evaporator pressure, not only the cooling water flow rate in the evaporator but also the coolant flow rate in the condenser is considered. Meanwhile, the conventional PID controllers, which is suitable for a single input system, shows a large overshoot for a disturbance input. In this work, the predictive control scheme is introduced and its applicability is discussed for thermal/flow systems.

• Environmental Analysis Health and Toxicology
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• 제23권3호
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• pp.213-220
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• 2008

The characteristics of PAHs accumulated on pine needles which were used as passive samplers of atmospheric POPs were studied. Atmospheric PAHs were accumulated on pine needles. The absorbed rate of PAHs was higher in gaseous state than in particulate and is not constant. The accumulation rate did not change too much among different classes of pine trees. Therefore young pine needles is better as a passive sampler of atmospheric PAHs for short monitoring period.

• 한국환경보건학회지
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• 제35권1호
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• pp.64-70
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• 2009

The aims of this study is to examine the effects of the changes in HRT(Hydraulic Retention Time) and media charge in a water-mill, among other operation factors, on the nitrogen and phosphorus removal in order to use up-flow anaerobic reactors, anoxic reactors and water-mill aerobic reactors for sewage treatment. The extension of HRT improved the nitrogen removal efficiency, however the removal pattern was constant regardless of HRT. The removal of phosphorus was constant (80%-90%) regardless of the change in HRT. The removal rate with change in influx load varied such that at the OLR (Organic Load Rate) of 1-3 kg/d, the T-N removal efficiency was 80.7%-88.9% and the T-P removal efficiency was 82.9%-89.3% while at the NLR (Nitrogen Loading Rate) of 0.108-0.156 kg/d the removal efficiencies were 80.7-88.9% (T-N) and 82.9-89.3% (T-P). The analyses of the nitrogen and phosphorous removal characteristics with the C/N and C/P ratio showed that the mean T-N removal rate was 88% at the C/N ratio of 1.2-2.6, and that the mean T-P removal rate was 86% at the C/P ratio of 7.2-14.1. Also, the analysis of nitrogen and phosphorous removal characteristics were analyzed in relation to media charge. The comparison between with and without media charge in the water-mill showed that while the nitrogen removal efficiencies were 86-94% and 85-89% respectively, the difference of phosphorous removal efficiencies were between the two conditions was not significant, thus it suggested that the media charge has less effect on the removal efficiency of phosphorous compared to that of nitrogen.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1991년도 한국자동제어학술회의논문집(국제학술편); KOEX, Seoul; 22-24 Oct. 1991
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• pp.1873-1878
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• 1991

An high-speed isothermal calorimeter which can trace the progress of a liquid phase reversible reaction was constructed using analog and digital computer. By means of a set point change of the calorimeter, the thermal energy capacity and the heat of reaction in reversible reaction mixture can be measured. The heat of reaction between 2-methyl furan and maleic anhydride and the heat capacities of the adduct were 61,200 J/mol and 2.38 J/ g K, respectively. Also reaction equilibrium constant and reaction rate constants can be estimated from the response curves of the calorimeter.

• 한국추진공학회지
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• 제22권5호
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• pp.22-31
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• 2018

본 연구에서는 연소실 경계조건 변화에 따른 핀틀 노즐의 동특성을 파악하기 위해 수치해석을 수행하였다. 핀틀의 움직임을 모사하기 위해 노즐과 핀틀의 영역을 분리하여 격자를 생성하고 중첩격자기법을 사용하였다. 연소실의 경계조건은 일정질량유량과 추진제 연소속도 조건을 적용하여 결과를 비교하였다. 일정질량유량조건은 입구에 유입되는 질량유량을 정량적으로 변화시켜 연소실의 압력과 추력 특성을 파악하였다. 추진제 연소속도 조건은 연소실 압력에 의한 연소속도 식을 고려하였다. 추진제 연소속도 조건은 일정질량유량조건과는 다른 비선형적 유량변화를 나타내며, 작은 유량으로도 큰 연소실 압력변화를 가져온다.