제어로봇시스템학회:학술대회논문집
- 1991.10b
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- Pages.1873-1878
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- 1991
Estimation of Heat and Rate Constant of Reaction by a Hight-Speed Isothermal Calorimeter
- Jung, Heung-Joe (College of Eng., Chonnam National University) ;
- Ryu, Dong-Wan (College of Eng., Chonnam National University) ;
- Park, Chan-Young (College of Eng., Chonnam National University)
- Published : 1991.10.01
Abstract
An high-speed isothermal calorimeter which can trace the progress of a liquid phase reversible reaction was constructed using analog and digital computer. By means of a set point change of the calorimeter, the thermal energy capacity and the heat of reaction in reversible reaction mixture can be measured. The heat of reaction between 2-methyl furan and maleic anhydride and the heat capacities of the adduct were 61,200 J/mol and 2.38 J/ g K, respectively. Also reaction equilibrium constant and reaction rate constants can be estimated from the response curves of the calorimeter.
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