• Tunnel and Underground Space
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• v.15 no.4 s.57
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• pp.316-323
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• 2005

As a result of waveform analysis, the separation of waveform found that high frequency well accomplishes but low frequency doesn't accomplish that. The data which measured less than 60 Hz and more than 60 Hz was analysed to examine the relation between cooperating charge and frequency. The measured data of more than 70 Hz was also analysed to consider the characteristics of high frequency.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.4
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• pp.451-456
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• 2024

Organic photovoltaic (OPV) devices have attracted attention due to their high efficiency and simple manufacturing process. Applying an overlayer to OPV devices is one way to improve their performance because it can improve charge extraction and suppress vertical phase separation. In addition, dichloromethane (DCM) was used as an orthogonal solvent to minimize the effect on other layers. However, an coating problems due to the use of DCM were found, which affects surface morphology as rough or peeling. Additional research efforts are needed to solve these problems, and optimal results are expected to be obtained by utilizing various buffer layers or selective organic solvents.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3473-3476
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• 2012

• Journal of the Korean Chemical Society
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• v.23 no.5
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• pp.277-285
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• 1979

CNDO/2 calculations on $XC_6H_4CH_2Cl,\;where\;X = H,\;p-CH_3,\;p-NH_2\;and\;p-NO_2$, and on benzyl radicals, cations and anions have been carried out in order to investigate nonlinear Hammett behavior. Main conclusions reached are: 1. Benzyl chloride exhibits borderline behavior due to ${\sigma}-{\pi}$ conjugation between C-Cl bond and the ring-system. 2. The extent of mutual conjugation can be judged by $\pi$-charge and bond alternation and interfrontier level separation narrowing effects. 3.The electron donating para substituent reduces the HOMO AO coefficient of the benzylic carbon, while the electron withdrawing para substituent reduces the LUMO AO coefficient of the benzylic carbon.

• Journal of the Korean Chemical Society
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• v.61 no.4
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• pp.168-178
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• 2017

$La/TiO_2$ - graphene composites were synthesized in this study, and applied to the photocatalytic degradation of Rhodamine B (RhB) under UV-visible light irradiation. X-ray diffraction (XRD), surface analysis, X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), and Transmission electron microscopy (TEM) analysis demonstrated that $La/TiO_2$ nanoparticles were well distributed on the surface of graphene, and formed the heterostructure of $La/TiO_2$-graphene. Compared to the pure $TiO_2$, $La/TiO_2$-graphene composites displayed much higher photocatalytic activities in RhB degradation under UV-visible light irradiation. The photocatalytic data of $La/TiO_2$-graphene composites exhibit extended light absorption in the visible light region, and possess better charge separation capability than that of pure $TiO_2$. The high photocatalytic activity was attributed to the composite's high adsorptivity, extended light absorption, and increased charge separation efficiency, due to the excellent electrical properties of graphene, and the large surface contact between graphene and $La/TiO_2$ nanoparticles.

• Journal of the Korean institute of surface engineering
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• v.52 no.5
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• pp.258-264
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• 2019

Assembling heterostructures by combining dissimilar oxide semiconductors is a promising approach to enhance charge separation and transfer in photoelectrochemical (PEC) water splitting. In this work, the CuO nanorods array/$Cu_2O$ thin film bilayered heterostructure was successfully fabricated by a facile method that involved a direct electrodeposition of the $Cu_2O$ thin film onto the vertically oriented CuO nanorods array to serve as the photoelectrode for the PEC water oxidation. The resulting copper-oxide-based heterostructure photoelectrode exhibited an enhanced PEC performance compared to common copper-oxide-based photoelectrodes, indicating good charge separation and transfer efficiency due to the band structure realignment at the interface. The photocurrent density and the optimal photocurrent conversion efficiency obtained on the CuO nanorods/$Cu_2O$ thin film heterostructure were $0.59mA/cm^2$ and 1.10% at 1.06 V vs. RHE, respectively. These results provide a promising route to fabricating earth-abundant copper-oxide-based photoelectrode for visible-light-driven hydrogen generation using a facile, low-cost, and scalable approach of combining electrodeposition and hydrothermal synthesis.

• Explosives and Blasting
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• v.37 no.4
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• pp.17-25
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• 2019

The method to remove the head of the cast-in-place pile using the detonating cord and horizontal separation plate was proposed in this paper. Plain concrete block was fabricated. Through the blasting test of the concrete block, the charge weight and the burden required for cutting the pile head were identified. The degree of damage of concrete blocks after cutting the head was checked using AUTODYN 2D. As a result of the experiment, it was found that the concrete block was cut using the 10 g/m detonating cord and horizontal separation plate, and the directional cutting of the block using the horizontal separation plate and the block damage caused by the detonating cord were reduced.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.47 no.6
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• pp.397-404
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• 2019

Linear Shaped Charge (LSC) that is widely used as separation system in aerospace system has to charge lots of explosives due to lack of uniformity. In addition, it is hard to optimize shape of liner and explosives because of manufacturing process. In order to overcome aforementioned drawbacks, Precision Linear Shaped Charge (PLSC) is currently under development. PLSC is made in two steps: prepare liner independently and charge explosive uniformly. In this study, PLSC is designed to have proper amount of explosives and penetration test of PLSC with different stand-off distance from liner to target is conducted to confirm penetration performance. Based on the penetration test results of PLSC, the numerical analysis method using AUTODYN is established and verified. Penetration mechanism and characteristics of PLSC is analyzed from the numerical and experimental results.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.47 no.9
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• pp.617-628
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• 2019

The currently considered pyrotechnic separation nut is separated through the complicated process, because it has many internal moving parts and two variable-volume chambers connected by the vent hole. Therefore, it has many design parameters. Some of these are the contact angles between internal moving parts, the masses of the internal moving parts, the inner diameter of the push rod protrusion, the initial volumes of the chambers, the mass of the explosive charge, and the diameter of the vent hole. To improve the pyrotechnic separation nut, it is necessary to understand how the behavior of the separation nut is changed according to design parameters. In this point of view, parametric studies are carried out using the previously proposed prediction model for pyrotechnic separation nut behaviors. In each case, the parameter of the interest is changed while the others are kept unchanged. From the results, it is investigated how each design parameter influences the separation behavior.

• Journal of the Korean Society of Propulsion Engineers
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• v.20 no.2
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• pp.67-74
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• 2016

Explosive bolt is one of separation device that uses high explosive charge, and is separated by pressure formed by an explosion and the resulting shock waves. Explosive bolt having such a mechanism would have to be designed to minimize shock and debris formation generated during separation. In this study, separation tests were carried out with distance as variable for restraining the explosive bolt (Air Gap). Bolt release and its separating shape with variation of air gap is observed, and we used accelerometer to measure the shock wave transmitted through a bound object. In addition, separation behavior of explosive bolt is analyzed using ANSYS AUOTODYN program. By comparing the results of previously performed experiments and analysis, we could confirm the effects of air gap to the release behavior of explosive bolt, and decide optimum constraining environment for specific separation bolts.