• Carbon letters
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• 제14권1호
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• pp.34-39
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• 2013

Acrylonitrile (AN)-acrylamide (AM) copolymers were prepared by nitric acidic hydrolysis of homopolyacrylonitrile. The acrylamino group increased as a function of hydrolysis time, while crystallinity decreased. Differential scanning calorimetry and a thermal gravimetric analysis indicated that the acylamino introduced by acidic hydrolysis effectively enhanced the cyclization reaction at low temperature due to the change of the cyclization reaction mechanism. Char-yield of AN-AM copolymers also gradually increased with increasing hydrolysis time. The maximum char-yield was 49.48% when hydrolized at $23^{\circ}C$ in 65% nitric acid solution for 18 h, which was 30% higher than that of non-acidic hydrolysis of homopolyacrylonitrile. Simulation of the practical process also showed an increase of char yields, where the char yields were 55.43% and 62.60% for homopolyacrylonitrile and copolyacrylonitrile, respectively, with a hydrolysis time of 13 h.

• 임산에너지
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• 제22권1호
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• pp.37-43
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• 2003

천연셀룰로오스의 탄화과정에서 탄화수율에 영향을 미치는 인자는 탄화온도, 승온속도 및 탄화로 내의 분위기를 들 수 있다. 일반적으로 탄화수율을 높이기 위해서는 탄화목표온도를 낮추고, 승온속도를 느리게 하면 탄화로의 분위기를 불활성가스의 조건에서 탄화수율이 높아진다고 보고되어 있다. 본 연구에서는 탄화조건 중에서 가장 유동성을 가지고 있는 승온속도를 조절하고, 탈수촉매제로서 황산을 첨가함으로서 탄화수율의 향상과 탄화과정에서 천연셀룰로오스를 재료로 하여 탄화특성에 대하여 조사하였다. 그 결과 황산무처리시료에 대하여는 승온속도가 증가함에 따라 수율이 상당히 감소하였지만 황산처리 시료는 승온속도가 증가하여도 수율 감소 폭이 크지 않았다. 본 연구의 결과에서 탄화과정에 있어서 승온속도의 조절과 적당한 탈수제의 첨가는 탄화재료의 수율 향상과 탄화시간 단축에 유용한 기초자료가 될 것으로 생각된다.

• Carbon letters
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• 제1권2호
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• pp.60-63
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• 2000

In this work, the carbon fibers-reinforced carbon matrix composites made with different carbon char yields of phenolic resin matrix have been characterized by mechanical flexural tests for acoustic emission properties. The composites had been fabricated in the form of two-dimensional polyacrylonitrile based carbon fibers during the carbonization process. It was found that the composites made with the carbon char yield-rich of resin matrix result in better mechanical interfacial properties, i.e., the interlaminar shear strength (ILSS) of the composites. The data obtained from the acoustic emission monitored appeared to show that the composites made with carbon char yield-rich were also more ductile. From the acoustic emission results, the primary composite failure was largely depended on the debonding at interfaces between fibers and matrix. The interlaminar shear strengths of the composites were correlated with the acoustic emission results.

• 한국화재소방학회논문지
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• 제22권3호
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• pp.300-304
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• 2008

고분자 물질의 화재 위험성 및 화재시 인명 피해의 감소를 위한 기초자료로 제시하고자 점토질의 첨가에 의한 난연성 평가를 수행하였다. 본 연구에서는 에폭시 수지의 난연성 향상과 연기의 발생량을 감소시키기 위하여 점토질의 montmorillonite(MMT)와 같은 천연 물질을 삽입하여 연소 특성을 살펴보았다. 이 연구를 위하여 한계산소지수(limiting oxygen index, LOI), 탄화층 생성량(char yield), 연기 밀도(smoke density) 측정 둥의 난연성 실험을 실시하였다. Epoxy/MMT의 복합재료는 MMT의 농도가 증가할수록 한계산소지수 및 탄화층 생성량이 증가하여 난연성이 향상되었으나 연기 밀도는 오히려 증가하는 결과를 나타내었다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.87-90
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• 2006

The experimental study has been done for two kinds of pelletized RDFs to Investigate the carbonization effect to the chlorine concentrations, the heating value and the yield of Produced char in variable conditions of the carbonizing temperature and reaction time. One(RDF-1) is made of 100% wasted plastics and the other(RDF-2) is made of 60% wasted paper with 40% wasted plastics. The screw type carbonizer heated Indirectly by oil burner was used for the experiment and RDF feeding rate was 3kg/hr. The carbonizing temperature was 300, 350 400 and $45^{\circ}C$ and the reaction tine was 5, 10 and 15 minutes respectively. As the increase of carbonizing reaction time and temperature, the chlorine reduction rate was increased and oppositely the yield of char was decreased At the temperature of $400^{\circ}C$ and reaction time of 10 minutes the chlorine reduction rate was 60% and the char yield rate was 80% for the RDF-1 and those of RDF-2 were 80% and 75%, respectively. Additional activation experiment to the char produced from RDF-2 was done in the activation reactor by hot steam supply. As the increase of activation time the iodine number was increased. At the activation time of 20 minutes the iodine number was 552mg/g and the yield of activated carbon was 16%.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2008년도 춘계학술논문발표회 논문집
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• pp.168-172
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• 2008

The flame retardancy by the addition of clay was evaluated to present as the fundamental data to decrease the fire hazard of polymers and life losses. The flame retardancy was examined to increase flame retardancy and to decrease smoke yield of epoxy by the addition of clay such as montmorillonite. For this study, the experiments of flame retardancy were conducted as follows : the measurement of the limiting oxygen index(LOI), char yield, and smoke density. As MMT concentration increased, epoxy/MMT composite increased LOI and char yield with the decreased smoke density.

• Elastomers and Composites
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• 제57권1호
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• pp.9-12
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• 2022

Herein, a facile approach for the development of effective and low-cost carbon precursors from acrylonitrile-butadiene-styrene (ABS) rubber is reported. ABS rubber with a negligible char yield can be converted into an excellent carbon precursor with approximately 54% char yield under a nitrogen atmosphere at 800℃ by simple iodine doping and subsequent heating at 110℃ under an inert atmosphere. The enhanced char yield is attributed to the improved intermolecular interactions between the ABS chains caused by the formation of covalent bonds between the butadiene segments, along with the newly developed charge-charge interactions and other indiscriminate radical-radical couplings. The charges and radicals involved in these interactions are also generated by iodine doping. We believe that this study will be useful for the development of low-cost carbon precursors.

• 한국화재소방학회논문지
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• 제21권2호
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• pp.30-35
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• 2007

고분자 물질의 화재 위험성 및 화재시 인명 피해의 감소를 위한 기초자료로 제시하고자 난연제 및 금속분말의 첨가에 의한 난연성 평가를 수행하였다. 본 연구를 위하여 중량감소율,한계산소지수 및 탄화층 생성량 측정, 연기 중량 농도 및 일산화탄소 발생량 측정의 실험을 수행하였다. 금속분말과 난연제를 함유한 acrylonitrile butadiene styrene은 낮은 중량감소율을 나타내었고, 한계산소지수 및 탄화충 생성량은 증가하였으며, 연기 중량 농도 및 일산화탄소의 발생량도 감소하는 결과를 나타내었다. 또한 가장 효과적인 복합체는 tricresyl phosphate-Mo 복합체로 나타났다.

• 한국안전학회지
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• 제20권4호
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• pp.40-45
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• 2005

The principal actions of a flame retardant are to decrease or prevent the formation of volatile products and increase the formation of char layer. Use of flame retardant additives can decrease the overall fire hazard of the product containing them thus leading to an increase in overall fire safety. Although several flame retardants have been developed for use in polymers, many of these are known to increase the amount of smoke and toxic gases generated by them. This paper present a new flame retardant using metal addition flame retardant. For this study, the experiments of flame retardancy conducted are as follows : burning ratio, weight loss rate using TGA-DTA, the measurement of LOI and char yield. And smoke mass concentration and CO yield were measured. The metal addition flame retardant reduced burning ratio and weight loss rate, increased the LOI and yield of char formation with decreased smoke mass concentration and CO yield.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2005년도 춘계학술논문발표회 논문집
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• pp.75-80
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• 2005