• Title/Summary/Keyword: cell decomposition

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Foaming Characteristics and Physical Properties of Ethylene Vinyl Acetate Copolymer Foams (Ethylene Vinyl Acetate Copolymer 발포체의 발포특성 및 물리적 특성)

  • Kim, Jin-Tae;Son, Woo-Jung;Ahn, Byung-Hyun;Kim, Won-Ho
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.52-60
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    • 2001
  • Physical properties of foams depend on the density of foams, Physical properties of base polymers, open ceil contents, and cell structures including the size, size distribution, shape of ceil and the thickness of membrane and strut. The density of foam is affected by raw materials, concentration oi crosslinking agent and blowing agent and process parameters such as processing technique and condition. Ethylene vinyl acetate copolymer(EVA) foam is a crosslinked cellular material. The foaming characteristics and physical properties of EVA foam are affected by decomposition rate of blowing agent. In this study, the decomposition rate of blowing agent and crosslinking rate, foaming characteristics and physical properties of foams were evaluated. The slow decomposition rate of blowing agent results in low density foam, good shock absorption property and uniform cell size distribution compared to the high decomposition rate of blowing agent.

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Triphenyl phosphate as an Efficient Electrolyte Additive for Ni-rich NCM Cathode Materials

  • Jung, Kwangeun;Oh, Si Hyoung;Yim, Taeeun
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.67-73
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    • 2021
  • Nickel-rich lithium nickel-cobalt-manganese oxides (NCM) are viewed as promising cathode materials for lithium-ion batteries (LIBs); however, their poor cycling performance at high temperature is a critical hurdle preventing expansion of their applications. We propose the use of a functional electrolyte additive, triphenyl phosphate (TPPa), which can form an effective cathode-electrolyte interphase (CEI) layer on the surface of Ni-rich NCM cathode material by electrochemical reactions. Linear sweep voltammetry confirms that the TPPa additive is electrochemically oxidized at around 4.83 V (vs. Li/Li+) and it participates in the formation of a CEI layer on the surface of NCM811 cathode material. During high temperature cycling, TPPa greatly improves the cycling performance of NCM811 cathode material, as a cell cycled with TPPa-containing electrolyte exhibits a retention (133.7 mA h g-1) of 63.5%, while a cell cycled with standard electrolyte shows poor cycling retention (51.3%, 108.3 mA h g-1). Further systematic analyses on recovered NCM811 cathodes demonstrate the effectiveness of the TPPa-based CEI layer in the cell, as electrolyte decomposition is suppressed in the cell cycled with TPPa-containing electrolyte. This confirms that TPPa is effective at increasing the surface stability of NCM811 cathode material because the TPPa-initiated POx-based CEI layer prevents electrolyte decomposition in the cell even at high temperatures.

Simplification of Boundary Representation Models Based on Stepwise Volume Decomposition (단계적 볼륨분해에 기반한 경계표현 모델의 단순화)

  • Kim, Byung Chul;Mun, Duhwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.10
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    • pp.1305-1313
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    • 2013
  • In this study, a method to apply feature-based simplification to boundary representation models is proposed. For feature-based simplification, a volume decomposition tree is created from a boundary representation model. The volume decomposition tree is represented by regularized Boolean operations of additive volumes, subtractive volumes, and fillet/round/chamfer volumes, and it is generated by stepwise volume decomposition, which consists of fillet/round/chamfer decomposition, wrap-around decomposition, volume split decomposition, and cell-based decomposition. After the volume decomposition tree is transformed to an infix expression, the CAD model can be simplified by reordering the volumes. To verify the proposed method, a prototype system was implemented, and experiments on test cases were conducted. From the results of the experiments, it is verified that the proposed method is useful for simplifying CAD models based on boundary representation.

Experimental and Simulation Study of PEMFC based on Ammonia Decomposition Gas as Fuel

  • Zhao, Jian Feng;Liang, Yi Fan;Liang, Qian Chaos;Li, Meng Jie;Hu, Jin Yi
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.63-70
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    • 2022
  • Compared with hydrogen, ammonia has the advantages of high gravimetric hydrogen densities (17.8 wt.%), ease of storage and transportation as a chemical hydrogen storage medium, while its application in small-scale on-site hydrogen production scenarios is limited by the need for complex separation equipment during high purity hydrogen production. Therefore, the study of PEMFC, which can directly utilize ammonia decomposition gas, can greatly expand the application of fuel cells. In this paper, the output characteristics, fuel efficiency and the variation trend of hydrogen concentration and local current density in the anode channel of fuel cell with the output voltage of PEMFC fueled by ammonia decomposition gas were studied by experiment and simulation. The results indicate that the maximum output power of the hybrid fuel decreases by 9.6% compared with that of the pure hydrogen fuel at the same inlet hydrogen equivalent. When the molar concentration of hydrogen in the anode channel is less than 0.12, the output characteristics of PEMFC will be seriously affected. Employing ammonia decomposition gas as fuel, the efficiency corresponding to the maximum output power of PEMFC is approximately 47%, which is 10% lower than the maximum efficiency of pure hydrogen.

Electrochemical oxidation of sodium dodecylbenzenesulfonate in Pt anodes with Y2O3 particles

  • Jung-Hoon Choi;Byeonggwan Lee;Ki-Rak Lee;Hyun Woo Kang;Hyeon Jin Eom;Seong-Sik Shin;Ga-Yeong Kim;Geun-Il Park;Hwan-Seo Park
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4441-4448
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    • 2022
  • The electrochemical oxidation process has been widely studied in the field of wastewater treatment for the decomposition of organic materials through oxidation using ·OH generated on the anode. Pt anode electrodes with high durability and long-term operability have a low oxygen evolution potential, making them unsuitable for electrochemical oxidation processes. Therefore, to apply Pt electrodes that are suitable for long-term operation and large-scale processes, it is necessary to develop a new method for improving the decomposition rate of organic materials. This study introduces a method to improve the decomposition rate of organic materials when using a Pt anode electrode in the electrochemical oxidation process for the treatment of organic decontamination liquid waste. Electrochemical decomposition tests were performed using sodium dodecylbenzenesulfonate (SDBS) as a representative organic material and a Pt mesh as the anode electrode. Y2O3 particles were introduced into the electrolytic cell to improve the decomposition rate. The decomposition rate significantly improved from 21% to 99%, and the current efficiency also improved. These results can be applied to the electrochemical oxidation process without additional system modification to enhance the decomposition rate and current efficiency.

A Mobile Robot Path Planning based on the Terrain with Varing Degrees of Traversability (연속적으로 변화하는 Traversability를 고려한 Mobile 로봇의 경로계획)

  • Lee, S.C.;Choo, H.J.
    • Proceedings of the KIEE Conference
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    • 1998.07g
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    • pp.2315-2317
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    • 1998
  • There has been extensive efforts about robot path planning. Some major approaches are the roadmap approach, potential field approach and the cell decomposition approach. However, most of the path planning methods proposed so far based on above approaches consider the terrains filled with binary obstacles, i.e., if there exists an obstacle, robot simply cannot pass the location. In this paper, A mobile robot path planning method based on the cell decomposition technique for mobile robot that takes account of the terrain with varing degrees of travers-ability is discussed.

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Single S-a-E fault tolerance of the triangular cellular permutation networks (삼각형 셀룰러 순열 네트워크에서의 단일 s-a-E 결함 허용)

  • 김우한;전대성;윤영우
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.33B no.9
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    • pp.37-48
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    • 1996
  • In this paper, for the single s-a-E fault detected in a triangular cellular permutation network (TCPN), we propose a method which can tolerate a fault by reconfiguring the netowrk and analyze the possibilities of the reconfiguration. The network is set up through iterative decomposition of a permutation into the right or left coset. For the s-a-E fault of a cell which is to be transpositioned for an increasing order mapping, we cna reconfigure it merely by switching te decomposition scheme from right coset to left coset or vice versa. Also for a decreasing order mapping, we make a detour around the faulty cell. Reconfiguring with the redundant connectivity of a TCPN, we could realize form 17% to 90% of the permutation for the number of inputs from 4 to 40. REconfiguration of the network by exchanging the first input with the last input and the first output with the last output resulted in more than 99% realization of the permutation. Also with the exchange of all inputs and outputs with neighboring cells, we could have 100% realization of the permutation.

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A Study on Effect of Thermal Decomposition Products of Coal on Anodic Reactions in Direct Carbon Fuel Cell (석탄 열분해 생성물이 직접탄소연료전지에서 애노드 반응에 미치는 영향에 대한 연구)

  • Rhie, Young Hoon;Eom, Seong Yong;Ahn, Seong Yool;Choi, Gyung Min;Kim, Duck Jool
    • Journal of Hydrogen and New Energy
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    • v.24 no.5
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    • pp.413-420
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    • 2013
  • Effect of inherent volatile matters in fuels on electrochemical reactions of anode was investigated for a single direct carbon fuel cell (DCFC). Raw coals used as power source in the DCFC release light gases into the atmosphere under the operating temperature of DCFC ($700^{\circ}C$) by thermal decomposition and only char remained. These exhausted gases change the gas composition around anode and affect the electrochemical oxidation reaction of system. To investigate the effect of produced gases, comparative study was conducted between Indonesian sub-bituminous coal and its char obtained through thermal treatment, carbonizing. Maximum power density of raw coal ($52mW/cm^2$) was appeared higher than that of char ($37mW/cm^2$) because the gases produced from the raw coal during thermal decomposition gave additional positive results to electrochemical reaction of the system. The produced gases from coals were analyzed using TGA and FT-IR. The influence of volatile matters on anodic electrolyteelectrode interface was observed by the equivalent circuit induced from fitting of impedance spectroscopy data.

UAV Path Planning based on Deep Reinforcement Learning using Cell Decomposition Algorithm (셀 분해 알고리즘을 활용한 심층 강화학습 기반 무인 항공기 경로 계획)

  • Kyoung-Hun Kim;Byungsun Hwang;Joonho Seon;Soo-Hyun Kim;Jin-Young Kim
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.3
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    • pp.15-20
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    • 2024
  • Path planning for unmanned aerial vehicles (UAV) is crucial in avoiding collisions with obstacles in complex environments that include both static and dynamic obstacles. Path planning algorithms like RRT and A* are effectively handle static obstacle avoidance but have limitations with increasing computational complexity in high-dimensional environments. Reinforcement learning-based algorithms can accommodate complex environments, but like traditional path planning algorithms, they struggle with training complexity and convergence in higher-dimensional environment. In this paper, we proposed a reinforcement learning model utilizing a cell decomposition algorithm. The proposed model reduces the complexity of the environment by decomposing the learning environment in detail, and improves the obstacle avoidance performance by establishing the valid action of the agent. This solves the exploration problem of reinforcement learning and improves the convergence of learning. Simulation results show that the proposed model improves learning speed and efficient path planning compared to reinforcement learning models in general environments.

The performance analysis of photovoltaic module accounting for solar cell degradation and series resistance (태양전지 셀의 열화와 직렬저항의 변화에 따른 태양전지 모듈의 특성 해석)

  • Park, Chi-Hong;Kang, Gi-Hwan;Waithiru, L.;Ahn, Hyung-Keun;Yu, Gwon-Jong;Han, Deuk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.28-29
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    • 2006
  • When photovoltaic module is used for a long time, its performance decreases due to several reasons. In this paper, we focus on the possibilities mainly contributing to the degraded efficiency of the polycrystalline silicon photovoltaic modules. The analysis is based on the modules that have been used for 15 years. These are two main reasons that cause the efficiency degradation, the corrosion and thermal decomposition. The former phenomenon of electrode is mainly due to the moisture from damaged back sheet in some module. However the other reason of the degraded efficiency comes from the thermal decomposition, which can not be observed from the outside but only by experiment. In this study, the comparison between the efficiency of normal modules and degradation modules is presented. Module having degraded cell was seen to cause increase of series resistance by about 80%, in comparison to normal samples efficiency which reduce by about 20%. This study shows that the effects of series resistances on module performance are critical. These effects must be understood and taken into consideration when analyzing performance degradation.

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