• 제목/요약/키워드: carbon nanotube(CNT)

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Butyl 및 Hexyl기가 도입된 다중벽 탄소나노튜브의 분산성 (Dispersibility of multi-walled carbon nanotubes functionalized with butyl and hexyl group)

  • 유정현;남병욱
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2010년도 춘계학술발표논문집 2부
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    • pp.1127-1130
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    • 2010
  • 본 연구에서는 CNT의 분산성을 개선하고자 다중벽 탄소나노튜브(multi-walled carbon nanotube, MWNT)에 butyllithium solution 및 hexyllithium solution을 이용하여 표면을 화학적으로 개질하였다. 개질된 MWNT는 적외선 분광 분석 및 Raman spectrophotometer를 이용하여 MWNT에 작용기가 도입되었는지를 확인하였다. 또한, 열중량분석기(Thermogravimetric analysis, TGA)를 이용하여 작용기가 도입된 MWNT의 열적 성질을 측정하였으며, MWNT 및 개질된 MWNT를 다양한 용매에 따른 분산성을 확인하였다.

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First-Principle Study on Structural and Electronic Properties of zigzag Carbon Nanotubes

  • Lee, Yong ju;Park, Jejune
    • EDISON SW 활용 경진대회 논문집
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    • 제3회(2014년)
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    • pp.446-449
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    • 2014
  • Carbon Nanotube (CNT) have been intensively investigated since they have been considered as building blocks of nanoscience and nanotechnology. Theoretical and computational studies on CNTs have revealed their physical and chemical properties and helped researchers build various experimental devices to study them in depth. However, there have been only few systematic studies on detailed changes in electronic structures of CNTs due to geometrical structure modifications. In this regard, it is necessary to perform systematic investigations of the modifications in electronic structures of CNTs, as their geometrical configurations are altered, using the first-principles density functional theory. In other words, it is essential to determine the true equilibrium structure of CNTs. In this work, we considered the different atomic configurations by maintaining their symmetries, but changing all the inequivalent bonding types one by one. Furthermore, as for CNTs, for example, the way the graphene sheet is wrapped is represented by a pair of indices (n,m) and electronic structures of CNTs vary depending on different indices. Our results suggest all the significant couplings between electronic and geometric structures in CNTs.

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전자 패키징 Interconnect 소재로의 카본 나노튜브의 활용 (Utilization of Carbon Nanotubes for New Interconnect Materials in Electronic Packaging)

  • 이종현
    • 마이크로전자및패키징학회지
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    • 제16권3호
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    • pp.1-10
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    • 2009
  • Carbon nanotube(CNT)s have been considered as one of the most unique materials due to the their superior mechanical, thermal and electrical properties. Therefore, numerous studies have been performed for the utilization of CNTs. This review article focuses on the recent research trends on the utilization of CNTs for new interconnect materials in electronics packaging. Major contents mentioned are the direct interconnection technology using CNTs and the main properties of polymer/CNTs composite materials. This article is aimed at the reviewing of important results from the recent studies and providing the straightforward understanding of the results through the mutual analysis and a industrial viewpoint.

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유리기판 위에 성장된 탄소나노튜브를 이용한 평판 램프의 전계방출 특성 (Field Emission Properties of Flat Lamp using Carbon Nanotubes Grownon Glass Substrate)

  • 이양두;문승일;한종훈;이윤희;주병권
    • 한국전기전자재료학회논문지
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    • 제17권6호
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    • pp.647-651
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    • 2004
  • We fabricated the 1-inch diode type flat lamp using CNTs, which were grown directly on soda-lime glass substrate at 600 ∼ 650 $^{\circ}C$ by thermal chemical vapor deposition(CVD) of acetylene gas. Turn- on field was about 2.8 V/${\mu}{\textrm}{m}$. We observed that uniform and high brightness had been obtained. The brightness of CNT flat lamp was measured up to about 14 kcd/$m^2$ at 2000V in spacing of 500 ${\mu}{\textrm}{m}$. The results showed that the CNTs were very good emission source and suitable for application in the lamp.

금속유기물에 의해 합성된 나노구조물의 특성분석에 관한 연구 (The characteristic analysis of the nano-fabric synthesized by metal organic matter)

  • 류정탁;;;백양규;김연보
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.935-938
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    • 2004
  • In this work, carbon nanofibers have synthesized a low temperature using DC Ar Plasma and Fe-Phthalocyanine, and a characteristic difference of the synthesized CNF according to the location of the substrate was investigated. the density of CNFs synthesized on the position (a) were higher than that synthesized on the position (b) [See the Fig. 1]. Also, the length of CNFs was different. In the shape, CNFs with screw and straight line shape were synthesized in the position (a), but only CNFs with straight line shape were synthesized in the position (b). The difference have an important effect on the field emission characteristics.

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Thermal-magneto-mechanical stability analysis of single-walled carbon nanotube conveying pulsating viscous fluid

  • R. Selvamani;M. Mahaveer Sree Jayan;Marin Marin
    • Coupled systems mechanics
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    • 제12권1호
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    • pp.21-40
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    • 2023
  • In thisstudy, the vibration problem ofthermo elastic carbon nanotubes conveying pulsating viscous nano fluid subjected to a longitudinal magnetic field is investigated via Euler-Bernoulli beam model. The controlling partial differential equation of motion is arrived by adopting Eringen's non local theory. The instability domain and pulsation frequency of the CNT is obtained through the Galerkin's method. The numerical evaluation of thisstudy is devised by Haar wavelet method (HWM). Then, the proposed model is validated by analyzing the critical buckling load computed in presentstudy with the literature. Finally, the numerical calculation ofsystem parameters are shown as dispersion graphs and tables over non local parameter, magnetic flux, temperature difference, Knudsen number and viscous parameter.

티타늄 다공체에 담지된 Camphene과 화학기상증착법을 이용한 CNT 합성 (Synthesis of CNT on a Camphene Impregnated Titanium Porous Body by Thermal Chemical Vapor Deposition)

  • 김호규;최혜림;변종민;석명진;오승탁;김영도
    • 한국분말재료학회지
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    • 제22권2호
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    • pp.122-128
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    • 2015
  • In this study, titanium(Ti) meshes and porous bodies are employed to synthesize carbon nanotubes(CNTs) using methane($CH_4$) gas and camphene solution, respectively, by chemical vapor deposition. Camphene is impregnated into Ti porous bodies prior to heating in a furnace. Various microscopic and spectroscopic techniques are utilized to analyze CNTs. It is found that CNTs are more densely and homogeneously populated on the camphene impregnated Ti-porous bodies as compared to CNTs synthesized with methane on Ti-porous bodies. It is elucidated that, when synthesized with methane, few CNTs are formed inside of Ti porous bodies due to methane supply limited by internal structures of Ti porous bodies. Ti-meshes and porous bodies are found to be multi-walled with high degree of structural disorders. These CNTs are expected to be utilized as catalyst supports in catalytic filters and purification systems.

CNTs 합성을 통해 향상된 비표면적을 갖는 Ti 다공체의 제조 (Fabrication of Ti Porous body with Improved Specific Surface Area by Synthesis of CNTs)

  • 최혜림;변종민;석명진;오승탁;김영도
    • 한국분말재료학회지
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    • 제23권3호
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    • pp.235-239
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    • 2016
  • This study is performed to fabricate a Ti porous body by freeze drying process using titanium hydride ($TiH_2$) powder and camphene. Then, the Ti porous body is employed to synthesize carbon nanotubes (CNTs) using thermal catalytic chemical vapor deposition (CCVD) with Fe catalyst and methane ($CH_4$) gas to increase the specific surface area. The synthesized Ti porous body has $100{\mu}M$-sized macropores and $10-30{\mu}m$-sized micropores. The synthesized CNTs have random directions and are entangled with adjacent CNTs. The CNTs have a bamboo-like structure, and their average diameter is about 50 nm. The Fe nano-particles observed at the tip of the CNTs indicate that the tip growth model is applicable. The specific surface area of the CNT-coated Ti porous body is about 20 times larger than that of the raw Ti porous body. These CNT-coated Ti porous bodies are expected to be used as filters or catalyst supports.

공기 중 탄소나노튜브 시료채취 시 사용하는 카세트 종류가 벽면 손실에 미치는 영향 (Effect of Sampling Cassettes Type used in Sampling of Airborne Carbon Nanotube(CNT) to Electrostatic Loss)

  • 함승헌;김송하;이진호;이나루;윤충식
    • 한국산업보건학회지
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    • 제27권3호
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    • pp.180-186
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    • 2017
  • Objectives: The purposes of this study were to compare the surface resistance of cassettes according to the material, and to evaluate the wall deposition of carbon nanotubes(CNTs) by electrostatic loss in the inner wall of the cassette. Methods: Surface resistance was measured for three types of cassettes(25 mm polypropylene conductive cowl, 25 mm and 37 mm clear styrene cassettes) with a surface resistance meter. Also, electrostatic wall loss was measured at different weights of CNTs depending on the cassette. CNTs were laid on a weight dish with the cassette for five minutes to provide sufficient time to attach on the wall. Wipe sampling was performed to collect CNTs deposited on the wall and elemental carbon, known as a surrogate for CNTs, was analyzed. Results: The cassette with conductive materials(18% of black carbon) showed the lowest surface resistance($<1.21{\times}10^3{\Omega}$). Cassettes made from clear polystyrene showed the relatively highest surface resistance(25 mm: $10.02{\times}10^9{\Omega}$, 37 mm: $10.59{\times}10^9{\Omega}$). This means that particles are more likely to stick to the internal wall of styrene cassettes due to electrostatic electricity. This may lead to an underestimation of the airborne concentration of CNTs. The experiment showed that EC was not detected when using a 25 mm conductive cowl cassette, while EC was detected at the internal wall of 25 mm and 37 mm polystyrene cassettes. Conclusions: This study confirms that cassettes with a conductive cowl have low surface resistance and are more appropriate for CNT sampling. In addition, this finding could be applied for other types of particulate, especially regarding electrostatic charge and sampling.

Impact and Delamination Failure of Multiscale Carbon Nanotube-Fiber Reinforced Polymer Composites: A Review

  • Khan, Shafi Ullah;Kim, Jang-Kyo
    • International Journal of Aeronautical and Space Sciences
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    • 제12권2호
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    • pp.115-133
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    • 2011
  • Fiber reinforced polymer composites (FRPs) are being increasingly used for a wide range of engineering applications owing to their high specific strength and stiffness. However, their through-the-thickness performance lacks some of the most demanding physical and mechanical property requirements for structural applications, such as aerospace vehicles and military components. Carbon nanotubes (CNTs) and carbon nanofibers (CNFs), due to their excellent mechanical, thermal and electrical properties, offer great promise to improve the weak properties in the thickness direction and impart multi-functionality without substantial weight addition to FRPs. This paper reviews the progress made to date on i) the techniques developed for integration of CNTs/ CNFs into FRPs, and ii) the effects of the addition of these nanofillers on the interlaminar properties, such as such interlaminar shear strength, interlaminar fracture toughness and impact damage resistance and tolerance, of FRPs. The key challenges and future prospects in the development of multiscale CNT-FRP composites for advanced applications are also highlighted.