• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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• pp.165-166
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• 2002

Hydrogen free diamond like carbon (DLC) films were prepared on steel substrates by using a single ion beam in a configuration that allowed sputtering of a graphite target and at the same time allowed to impact the substrate at a grazing angle. The DLC films so prepared have improved properties with increased disorder and with modest hardness that is slightly higher than previously reported values. We have studied the effects of $N_2^+$ ions implantation on such films. It is found that the implantations of nitrogen ions into DLC films lead to chemical modifications that allowed N atoms to be incorporated into the carbon network to produce a nitrogenated DLC. Nano-indentation experiments indicated that the nitrogenated films have consistently higher hardnesses ranging from 30 to 45GPa, which represents a considerable increase in surface hardness, compared with non-nitrogenated precursor films. The investigations by XPS and Raman spectroscopy suggests that the $N_2^+$ implanted DLCs had undergone both chemical and structural modifications through the incorporation of N atoms and the increased ratio of $sp^3/sp^2$ type bonding. The observed high hardness was therefore attributable to these structural and chemical modifications. This result has implication for the preparation of super hard wear resistant films required for tribological functions in devices.

• 환경생물
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• 제27권3호
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• pp.279-284
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• 2009

In order to understand food sources-metabolism for the pacific oyster (Crassostrea gigas), the stable isotope ratios of carbon (${\delta}^{13}C$) and nitrogen (${\delta}^{15}N$) of its gut, gill, and muscle as well as potential food sources (particulate organic matter, sedimentary organic matter, benthic microalgae, seagrass detritus) were determined in Dongdae Bay. Average ${\delta}^{13}C$ and ${\delta}^{15}N$ values reflect that oysters primarily fed on sedimentary organic matter as opposed to suspended organic matter during summer and winter seasons. However, the relatively enriched $^{15}N$ values of particulate organic matter (>$250{\mu}m$) and sedimentary organic matter in the summer may be due to the photosynthetic incorporation of $^{15}N$-enriched nitrogen (DIN) or the spawning events of bivalves. Specific oyster tissues (gut, gill, and muscle) revealed different metabolic pathways, which were determined through analysis of ${\delta}^{13}C$ and ${\delta}^{15}N$ in each organ. The present results suggest the determination of carbon and nitrogen stable isotopes to be a useful approach in ecological research related to the food sources- metabolism of Crassostrea gigas.

• 폴리머
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• 제34권3호
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• pp.198-201
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• 2010

탄소나노튜브의 응집력을 완화하기 위한 표면 개질과 고분자 소재와의 상용성을 유도하기 위하여, 친수성 고분자를 도입하는 연구를 진행하였다. 산처리를 통한 표면 기능화를 시행하였으며, 카복실기 도입 탄소나노튜브를 thionyl chloride을 사용하여 acyl chloride로 치환한 후 저분자량의 아민 말단 poly(ethylene oxide)를 공유결합으로 도입하였다. TGA를 통하여 탄소나노튜브 표면에 도입된 고분자의 함량을 계산하였으며, 탄소나노튜브 표면에 도입된 고분자의 표면 형상을 SEM과 TEM을 통하여 직경이 증가하는 것을 확인할 수 있었다.

• 한국초전도ㆍ저온공학회논문지
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• 제18권1호
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• pp.1-5
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• 2016

Field and temperature dependence of the critical current density, Jc, were measured for both un-doped and carbon doped $MgB_2/Nb/Monel$ wires manufactured by Hyper Tech Research, Inc. In particular, carbon incorporation into the $MgB_2$ structure using malic acid additive and a chemical solution method can be advantageous because of the highly uniform mixing between the carbon and boron powders. At 4.2 K and 10 T, Jc was estimated to be $25,000-25,300Acm^{-2}$ for the wire sintered at $600^{\circ}C$ for 4 hours. The irreversibility field, $B_{irr}$, of the malic acid doped wire was approximately 21.0 - 21.8 T, as obtained from a linear extrapolation of the J-B characteristic. Interestingly enough, the Jc of the malic acid doped sample exceeds $10^5Acm^{-2}$ at 6 T and 4.2 K, which is comparable to that of commercial Nb-Ti wires.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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• pp.114-115
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• 2019

When concrete is exposed to fire, the decomposition of Portland cement paste results in critical damage to the concrete structure of a building. Although the behavior of cement pastes after heating provides crucial information with respect to the reuse of the building exposed to fire, the recovery process of the damaged concrete structure has not yet been fully elucidated. In addition, research on appropriate additives such as carbon nanotube (CNT) has been increasing recently, however, investigation of CNT incorporated cement paste after decomposition of CNT by high temperature is not fully investigated. In this study, we investigated the physicochemical properties of CNT incorporated cement paste under different temperatures (200℃, 500℃ and 800℃). Also, the effects of different rehydration conditions (20℃ 60% RH and in water for different curing times) on the recovery of the paste were studied. The changes in tensile and compressive strength, surface observation of the specimens were characterized. In addition, the decomposition and formation of hydrates in the paste due to the heating process were studied using X-ray diffraction.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2019년도 학술발표회
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• pp.148-148
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• 2019

The 2006 Millennium Ecosystem Assessment (MA) defines ecosystem services (ES) as "the benefits people obtain from ecosystems". Identifying where ES originates, whom it benefits and how it is changing over a period of time is critical in rapidly developing country like Nepal, where the risk of ES loss is high. In the context of various ecosystem services provided by watershed, this study, particularly deals with water yield, Soil loss and Carbon sequestration computation and evaluation in Bagmati Basin of Nepal. As Bagmati Basin incorporates capital city Kathmandu of nepal, land use change is significant over decades and mapping of ES is crucial for sustainable development of Basin in future. In this regard, the objectives of this study are 1) To compute the total and sub-watershed scale water yield of the basin, 2) Computation of soil loss and sediment retention in the basin, and 3) Computation of carbon sequestration in the basin. Integrated Valuation of Environmental Services and Tradeoffs (InVEST), a popular model for ecosystem service assessment based on Budyko hydrological method is used to compute Ecosystem services. The scenario of ES in two periods of time can be referenced for various approaches of prioritization and incorporation of their value into local and regional decision making for management of basin.

• Journal of Electrochemical Science and Technology
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• 제14권3호
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• pp.222-230
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• 2023

Capacitive deionization of saline water is one of the most promising water purification technologies due to its high energy efficiency and cost-effectiveness. This study synthesizes porous carbon composites composed of reduced graphene oxide (rGO) and activated carbon (AC) with various rGO/AC ratios using a facile chemical method. Surface characterization of the rGO/AC composites shows a successful chemical reduction of GO to rGO and incorporation of AC into rGO. The optimized rGO/AC composite electrode exhibits a specific capacitance of ~243 F g^-1 in a 1 M NaCl solution. The galvanostatic charging-discharging test shows excellent reversible cycles, with a slight shortening in the cycle time from the ~260^th to the 530^th cycle. Various monovalent sodium salts (NaF, NaCl, NaBr, and NaI) and chloride salts (LiCl, NaCl, KCl, and CsCl) are deionized with the rGO/AC electrode pairs at a cell voltage of 1.3 V. Among them, NaI shows the highest specific adsorption capacity of ~22.2 mg g^-1. Detailed surface characterization and electrochemical analyses are conducted.

• 한국건설순환자원학회논문집
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• 제11권4호
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• pp.425-432
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• 2023

본 연구에서는 바이오차를 혼입한 탄소 저감형 콘크리트 기술을 개발하고자 한다. 주요 인프라 분야인 건축과 터널에 단열성능과 탄소 포집이 가능한 바이오차를 혼입시킨 콘크리트의 성능 평가 실험을 수행하였다. 콘크리트 배합은 바이오차 혼입률 0, 5, 10, 15 및 20 %와 물-바인더 비를 0.25, 0.30, 0.35 및 0.40으로 선정하여 배합조건을 구성하였다. 각 배합별 물리적 특성을 평가하기 위해 단위중량, 총 공극률 및 투수계수를 측정하였고, 역학적 특성을 파악하기 위해 콘크리트 압축강도, 휨강도를 측정하였다. 바이오차를 혼입한 탄소 저감형 콘크리트의 단열 효과를 향상 시키기 위한 주요 인자는 회귀분석을 통해 바이오차 혼입률, 단위중량, 콘크리트 강도 및 열전도율은 서로 밀접한 상관관계를 갖는 것으로 나타났다. 향후 혹한기후 특성을 갖는 북방지역에 단열성능을 높이기 위한 단열재료로 활용될 것으로 판단된다.

• Applied Biological Chemistry
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• 제21권1호
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• pp.63-67
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• 1978

균일(均一)하게 표식(漂識)된 $C^{14}$-포도당을 산란계(産卵鷄)에 주사후(注射後) 혈장(血漿) 지질(脂質)로 방사능(放射能)이 병합(倂合)되는 상태(狀態)를 조사(調査)하였다. 혈장(血漿)에서 전지질(全脂質)을 추출(抽出)하는 방법(方法)은 Folch등(等)의 방법(方法)을 조금 변형(變型)하여 적용(適用)하였으며 방사능(放射能)의 측정(測定)은 액체(液體)신치레숀카운터에 의(依)하여 실시(實施)하였다. 공시(供試)한 산란계(産卵鷄)의 혈장(血漿) 지질(脂質)의 농도(濃度)는 추적자량(追跡子豊)의 $C^{14}$-포도당을 정맥(靜脈)에 주사(注射)한 후(後) 5분(分)에 채취(採取)한 시료(試料)에서 100m1당(當) 3.07g을 나타내었다. 포도당의 비방사능(比放射能)은 대수적(對數的)으로 급속(急速)하게 감소(減少)하는 반면(反面) kg체중당(體重當), 주사단위량당(注射單位量當), 그리고 혈장(血漿) 지질(脂質)의 그람 탄소원자량(炭素原子當) 비방사능(比放射能)은 주사후(注射後) 120분(分)까지 시간(時間)에 따라서 매우 서서(徐徐)히 증가(增加)하였다. 포도당의 방사능(放射能)으로부터 혈장(血漿) 지질(脂質)의 방사능(放射能)으로 병합(倂合)되는 율(率)은 주사후(注射後) 120분(分)까지 0.73%이었다.

• Composites Research
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• 제34권5호
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• pp.290-295
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• 2021

지구 온난화 억제를 위한 전 세계적인 연비규제에 발맞춘 해결책으로 자동차에 경량구조복합재료를 적용하는 것이 메가트렌드로 인식되고 있다. 본 연구에서는 수리, 폐기 및 재활용 측면에서 유리한 열가소성 탄소섬유강화플라스틱의 적용을 극대화하기 위해 전도특성이 요구되는 부품 대체 이슈에 대응할 수 있는 기술적 접근을 제공하는 것을 목표로 수행되었다. 저점도 중합 가능한 기지재의 특성을 활용하여 전도성 필러를 파우더 믹싱 방법으로 균일하게 혼입하면서도 우수한 함침 특성을 나타내는 열가소성 탄소섬유강화플라스틱 제조방법에 기초하여 카본블랙, 탄소나노튜브, 그래핀 나노플레이틀렛, 흑연, 피치계 탄소섬유 등 다양한 탄소기반 전도성 필러를 최대 함량까지 혼입하여 전기저항 및 열전도도를 비교하여 고찰하였다. 전도성 탄소 필러의 종류나 형태보다는 최대 혼입량이 시편의 전도 특성을 제어하기 위해 가장 중요한 인자임을 확인하였고, 전기전도 특성을 향상시키기 위해서는 1차원 형태의 전도성 탄소필러를 적용하는 것이 유리할 수 있는 반면 열전도 특성을 향상시키기 위해서는 2차원 형태의 전도성 탄소필러를 적용하는 것이 유리 할 수 있다는 실험 결과를 확인하였다. 본 연구의 결과들은 열가소성 탄소섬유강화플라스틱의 전도 특성을 제어하기 위한 최적 구조 설계에 잠재적인 통찰력을 제공할 수 있다.